Operational control of stereoselectivity during the enzymatic hydrolysis of racemic organophosphorus compounds

Journal of the American Chemical Society

Volumn 125, Issue 25, 2003, Pages 7526-7527

  Li, Yingchun ^a   Aubert, Sarah D ^a   Raushel, Frank M ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOPHOSPHORUS COMPOUND; PHENOL; PHOSPHOTRIESTERASE;

ARTICLE; CATALYST; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; ENANTIOMER; HYDROLYSIS; PKA; RACEMIC MIXTURE; SPECTROPHOTOMETRY; STEREOCHEMISTRY;

ARYLDIALKYLPHOSPHATASE; ESTERASES; HYDROLYSIS; KINETICS; ORGANOPHOSPHORUS COMPOUNDS; STEREOISOMERISM;

EID: 0038208150     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja035625m     Document Type: Article

References (16)

1. (a) Raushel, F. M. Curr. Opin. Microbiol. 2002, 5, 288-295.
2. (b) Raushel, F. M.; Holden, H. M. Adv. Enzymol. Relat. Areas Mol. Biol. 2000, 74, 51-93.
3. Omburo, G. A.; Kuo, J. M.; Mullins, L. S.; Raushel, F. M. J. Biol. Chem. 1992, 267, 13278-13283.
4. (a) Vanhooke, J. L.; Benning, M. M.; Raushel, F. M.; Holden, H. M. Biochemistry 1996, 35, 6020-6025.
5. (b) Benning, M. M.; Shim; Raushel, F. M.; Holden, H. M. Biochemistry 2001, 40, 2712-2722.
6. (a) Lewis, V. E.; Donarski, W. J.; Raushel, F. M. Biochemistry, 1988, 27, 1591-1597.
7. (b) Hong, S.-B.; Raushel, F. M. Biochemistry 1999, 38, 1159-1165.
8. (a) Chen-Goodspeed, M.; Sogorb, M. A.; Wu, F.; Hong, S. B.; Raushel, F. M. Biochemistry 2001, 40, 1325-1331.
9. Chen-Goodspeed, M.; Sogorb, M. A.; Wu, F.; Raushel, F. M. Biochemistry 2001, 40, 1332-1339.
10. (a) Wu, F.; Li, W.-S.; Chen-Goodspeed, M.; Sogorgb, M. A.; Raushel, F. R. J. Am. Chem. Soc. 2000, 122, 10206-10207.
11. (b) Li, W.; Li, Y.; Hill, C. M.; Lum, K. T.; Raushel, F. M. J. Am. Chem. Soc. 2002, 124, 3498-3499.
12. Hong, S.-B.; Raushel, F. M. Biochemistry 1996, 35, 10904.
13. Donarski, W. J.; Dumas, D. P.; Heitmeyer, D. P.; Lewis, V. E.; Raushel, F. M. Biochemistry 1989, 28, 4650-4655.
14. (a) Zhu, W.; Wu, F.; Raushel, F. M.; Vigh, G. J. Chromatogr. 2000, 895, 247.
15. (b) Zhu, Wu.; Li, W.-S.; Raushel, F. M.; Vigh, G. Electrophoresis 2000, 21, 3249.
16. Steurbaut, W.; Dekimpe, N.; Schreyen, L.; Dejonckheere, W. Bull. Soc. Chim. Belg. 1975, 84, 791.