Trapping model for the non-Arrhenius ionic conductivity in fast ion-conducting glasses

Journal of Physics Condensed Matter

Volumn 15, Issue 16, 2003, Pages

  Martin, S W ^a   Martin, D M ^a   Schrooten, J ^a   Meyer, B M ^a  

^a Iowa State University of Science and Technology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARRIER CONCENTRATION; ELECTRIC CONDUCTIVITY; ELECTRON TRAPS; ELECTROSTATICS; GLASS; POSITIVE IONS; TEMPERATURE;

ACTIVATED CARRIER CONCENTRATION; FAST ION CONDUCTING GLASSES; NON-ARRHENIUS IONIC CONDUCTIVITY; TRAPPING MODEL;

IONIC CONDUCTION IN SOLIDS;

EID: 0038188765     PISSN: 09538984     EISSN: None     Source Type: Journal    
DOI: 10.1088/0953-8984/15/16/312     Document Type: Article

References (31)

1. Funke K, Cramer C and Roling B 2000 Dynamics of mobile ions in glass-what do conductivity spectra tell us? Glass Sci. Technol. 73 244
2. Angell C A 1992 Mobile ions in amorphous solids Annu. Rev. Phys. Chem. 43 693
3. Fusco F A, Tuller H L and Button D P 1992 Lithium, sodium and potassium transport in fast ion conducting glasses: trends and models Mater. Sci. Eng. B 13 157
4. Pradel A and Ribes M 1992 Ionically conductive chalcogenide glasses J. Solid State Chem. 96 247
5. Martin S W 1991 Ionic conduction in phosphate glasses J. Am. Ceram. Soc. 74 1767
6. Ingram M D 1989 Ionic conductivity and glass structure Phil Mag. B 60 729-40
7. Ingram M D 1987 Ionic conductivity in glass Phys. Chem. Glasses 28 215
8. Levasseur A et al 1981 Synthesis and electrical properties of new sulfide glasses with high ionic conductivity C. R. Seances Acad. Sci. II 293 563-5
9. Robert G, Malugani J P and Saida A 1981 Fast ionic silver and lithium conduction in glasses Solid State Ion. 3/4 311
10. Ravaine D 1980 Glasses as solid electrolytes J. Non-Cryst. Solids 38/39 353
11. 3 glasses containing lithium or sodium Phys. Chem. Glasses 4 29
12. Kincs J and Martin S W 1996 Non-Arrhenius conductivity in glass: mobility and conductivity saturation effects Phys. Rev. Lett. 76 70
13. Schrooten J A 2001 Investigation into the non-Arrhenius behavior of fast ion conducting glasses PhD Thesis Iowa State University of Science and Technology
14. 4) system J. Non-Cryst. Solids 53 73
15. Maass P, Meyer M, Bunde A and Dieterich W 1996 Microscopic explanation of the non-Arrhenius conductivity in glassy fast ionic conductors Phys. Rev. Lett. 77 1528
16. Ngai K L and Rizos A K 1996 Parameterless explanation of the non-Arrhenius conductivity in glassy fast ionic conductors Phys. Rev. Lett. 76 1296
17. Martin S W 1991 Ionic conduction in phosphate glasses J. Am. Ceram. Soc. 74 1767
18. 2 Solid State Ion. 91 7
19. Barrow G M 1979 Physical Chemistry (New York: McGraw-Hill)
20. Matic A, Swenson J, Borjesson L, Longeville S, Lechner R E, Howells W S, Akai T and Martin S W 1999 Ionic motion of silver in super-ionic glasses Physica B 266 69
21. Svare I, Martin S W and Borsa F 2000 Stretched exponentials with T-dependent exponents from fixed distributions of energy barriers for relaxation times in fast-ion conductors Phys. Rev. B 61 228
22. Almond D P, Vainas B and Uvarov N F 1998 A new analysis of the bulk ac electrical response of ionic conductors Solid State Ion. 111 253
23. Isard J O 1996 High field conduction in ionic glasses-Effect of a distribution of activation energies J. Non-Cryst. Solids 202 137
24. Macdonald J R 1993 Distributed relaxation response for two classes of material temperature behavior Phys Status Solidi b 176 275
25. Schirrmeister F, Kahnt H and Feltz A 1987 Frequency-dependent conductivity and the time distribution function of hopping events J. Non-Cryst. Solids 97/98 523
26. Martin S W, Borsa F and Svare I 1901 Distribution of activation energies treatment of fast ion motions in glass Proc. Electrochem. Soc. 2000-32 66
27. 3) J. Am. Ceram. Soc. 73 3481
28. Swenson J, Matic A, Karlsson C, Borjesson L and Howells W S 2000 Free volume and dissociation effects in fast ion conducting glasses J. Non-Cryst. Solids 263/264 73
29. Fusco F A, Tuller H L and Button D P 1992 Lithium, sodium and potassium transport in fast ion conducting glasses: trends and models Mater. Sci. Eng. B B13 157
30. McElfresh D K and Howitt D G 1986 Activation enthalpy for diffusion in glass Comm. Am. Ceram. Soc. 69 C-237-8
31. Ryan M J and Smedley S I 1984 The effect of pressure on fast ion conductivity in glasses J. Non-Cryst. Solids 65 29