Hexagonal Pore Organization in Mesostructured Metal Tin Sulfides Built with [Sn2S6]4- Cluster

Nano Letters

Volumn 2, Issue 5, 2002, Pages 513-517

  Rangan, Krishnaswamy K ^a   Trikalitis, Pantelis N ^a   Canlas, Christian ^a   Bakas, Thomas ^b   Weliky, David P ^a   Kanatzidis, Mercouri G ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

^b UNIVERSITY OF IOANNINA   (Greece)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0038130814     PISSN: 15306984     EISSN: None     Source Type: Journal    
DOI: 10.1021/nl025502k     Document Type: Article

References (34)

1. Ozin, G. A. Materials Chemistry, An Emerging Subdiscipline, Adv. Chem. Ser.; Interrante, L., Ed. 1995, 245, 335-372. Barton, T. J.; Bull, L. M.; Klemperer, W. G.; Loy, D. A.; McEnaney, B.; Misono, M.; Monson, P. A.; Pez, G.; Scherer, G. W.; Vartuli, J. C.; Yaghi, O. M. Chem. Mater. 1999, 11, 2633-2656. Axtell, A. E.; Liao, J. H.; Pikramenou, Z.; Park, Y.; Kanatzidis, M. G. J. Am. Chem. Soc. 1993, 115, 12 191.
2. Ozin, G. A. Materials Chemistry, An Emerging Subdiscipline, Adv. Chem. Ser.; Interrante, L., Ed. 1995, 245, 335-372. Barton, T. J.; Bull, L. M.; Klemperer, W. G.; Loy, D. A.; McEnaney, B.; Misono, M.; Monson, P. A.; Pez, G.; Scherer, G. W.; Vartuli, J. C.; Yaghi, O. M. Chem. Mater. 1999, 11, 2633-2656. Axtell, A. E.; Liao, J. H.; Pikramenou, Z.; Park, Y.; Kanatzidis, M. G. J. Am. Chem. Soc. 1993, 115, 12 191.
3. Ozin, G. A. Materials Chemistry, An Emerging Subdiscipline, Adv. Chem. Ser.; Interrante, L., Ed. 1995, 245, 335-372. Barton, T. J.; Bull, L. M.; Klemperer, W. G.; Loy, D. A.; McEnaney, B.; Misono, M.; Monson, P. A.; Pez, G.; Scherer, G. W.; Vartuli, J. C.; Yaghi, O. M. Chem. Mater. 1999, 11, 2633-2656. Axtell, A. E.; Liao, J. H.; Pikramenou, Z.; Park, Y.; Kanatzidis, M. G. J. Am. Chem. Soc. 1993, 115, 12 191.
4. Weiss, D.; Roukes, M. L.; Menschig, A.; Grambow, P. Nanostructures and Mesoscopic Systems; Kirk, W. P., Reed, M. A., Eds.; Academic Press: Boston; 1992, pp 299-309. Turton, R. The Quantum Dot; Oxford University Press: New York, 1995. Bowes, C. L.; Ozin, G. A. Mater. Res. Soc. Symp. Proc. 1993, 286, 93-98.
5. Weiss, D.; Roukes, M. L.; Menschig, A.; Grambow, P. Nanostructures and Mesoscopic Systems; Kirk, W. P., Reed, M. A., Eds.; Academic Press: Boston; 1992, pp 299-309. Turton, R. The Quantum Dot; Oxford University Press: New York, 1995. Bowes, C. L.; Ozin, G. A. Mater. Res. Soc. Symp. Proc. 1993, 286, 93-98.
6. Weiss, D.; Roukes, M. L.; Menschig, A.; Grambow, P. Nanostructures and Mesoscopic Systems; Kirk, W. P., Reed, M. A., Eds.; Academic Press: Boston; 1992, pp 299-309. Turton, R. The Quantum Dot; Oxford University Press: New York, 1995. Bowes, C. L.; Ozin, G. A. Mater. Res. Soc. Symp. Proc. 1993, 286, 93-98.
7. Ciesla, U.; Schüth, F. Microporous Mesoporous Mater. 1999, 27, 131.
8. Schüth, F. Chem. Mater. 2001, 13, 3184.
9. MacLachlan, M. J.; Coombs, N.; Ozin, G. A. Nature 1999, 397, 681-684. MacLachlan, M. J.; Coombs, N.; Bedard, R. L.; White, S.; Thompson, L. K.; Ozin, G. A. J. Am. Chem. Soc. 1999, 121, 12 005-12 017.
10. MacLachlan, M. J.; Coombs, N.; Ozin, G. A. Nature 1999, 397, 681-684. MacLachlan, M. J.; Coombs, N.; Bedard, R. L.; White, S.; Thompson, L. K.; Ozin, G. A. J. Am. Chem. Soc. 1999, 121, 12 005-12 017.
11. Rangan, K. K.; Billinge, S. J. L.; Petkov, V.; Heising, J.; Kanatzidis, M. G. Chem. Mater. 1999, 11, 2629-2632. Wachhold, M.; Rangan, K. K.; Lei, M.; Thorpe, M. F.; Billinge, S. J. L.; Petkov, V.; Heising, J.; Kanatzidis, M. G. J. Solid State Chem. 2000, 152, 21-36.
12. Rangan, K. K.; Billinge, S. J. L.; Petkov, V.; Heising, J.; Kanatzidis, M. G. Chem. Mater. 1999, 11, 2629-2632. Wachhold, M.; Rangan, K. K.; Lei, M.; Thorpe, M. F.; Billinge, S. J. L.; Petkov, V.; Heising, J.; Kanatzidis, M. G. J. Solid State Chem. 2000, 152, 21-36.
13. Li, J. Q.; Kessler, H.; Delmotte, L. J. Chem. Soc.-Faraday Trans. 1997, 93, 665-668. Li, J. Q.; Kessler, H. Microporous Mater. 1997, 9, 141-147. Li, J. Q.; Delmotte, L.; Kessler, H. Chem. Commun. 1996, 1023-1024. Jiang, T.; Ozin, G. A. J. Mater. Chem. 1997, 7, 2213-2222. Li, J. Q.; Marler, B.; Kessler, H.; Soulard, M.; Kallus, S. Inorg. Chem. 1997, 36, 4697-4701.
14. Li, J. Q.; Kessler, H.; Delmotte, L. J. Chem. Soc.-Faraday Trans. 1997, 93, 665-668. Li, J. Q.; Kessler, H. Microporous Mater. 1997, 9, 141-147. Li, J. Q.; Delmotte, L.; Kessler, H. Chem. Commun. 1996, 1023-1024. Jiang, T.; Ozin, G. A. J. Mater. Chem. 1997, 7, 2213-2222. Li, J. Q.; Marler, B.; Kessler, H.; Soulard, M.; Kallus, S. Inorg. Chem. 1997, 36, 4697-4701.
15. Li, J. Q.; Kessler, H.; Delmotte, L. J. Chem. Soc.-Faraday Trans. 1997, 93, 665-668. Li, J. Q.; Kessler, H. Microporous Mater. 1997, 9, 141-147. Li, J. Q.; Delmotte, L.; Kessler, H. Chem. Commun. 1996, 1023-1024. Jiang, T.; Ozin, G. A. J. Mater. Chem. 1997, 7, 2213-2222. Li, J. Q.; Marler, B.; Kessler, H.; Soulard, M.; Kallus, S. Inorg. Chem. 1997, 36, 4697-4701.
16. Li, J. Q.; Kessler, H.; Delmotte, L. J. Chem. Soc.-Faraday Trans. 1997, 93, 665-668. Li, J. Q.; Kessler, H. Microporous Mater. 1997, 9, 141-147. Li, J. Q.; Delmotte, L.; Kessler, H. Chem. Commun. 1996, 1023-1024. Jiang, T.; Ozin, G. A. J. Mater. Chem. 1997, 7, 2213-2222. Li, J. Q.; Marler, B.; Kessler, H.; Soulard, M.; Kallus, S. Inorg. Chem. 1997, 36, 4697-4701.
17. Li, J. Q.; Kessler, H.; Delmotte, L. J. Chem. Soc.-Faraday Trans. 1997, 93, 665-668. Li, J. Q.; Kessler, H. Microporous Mater. 1997, 9, 141-147. Li, J. Q.; Delmotte, L.; Kessler, H. Chem. Commun. 1996, 1023-1024. Jiang, T.; Ozin, G. A. J. Mater. Chem. 1997, 7, 2213-2222. Li, J. Q.; Marler, B.; Kessler, H.; Soulard, M.; Kallus, S. Inorg. Chem. 1997, 36, 4697-4701.
18. Trikalitis, P. N.; Rangan, K. K.; Bakas, T.; Kanatzidis, M. G. Nature 2001, 401, 671.
19. Krebs, B. Angew. Chem., Int. Ed. Engl. 1983, 22, 113.
20. 4-Sn), whereas in water they are different, showing a single line at 69 ppm and 55 ppm, respectively.
21. 119Sn solution NMR data) and precipitation of the mesophases is immediate upon addition of the linking metal cations, we expect that they become part of the inorganic framework.
22. + fragment indicating the abstraction of sulfur atoms from the inorganic framework leading to its collapse.
23. Pophal, C.; Fuess, H. Microporous Mesoporous Mater. 1999, 33, 241.
24. 0 are the local and average atomic number densities, respectively, Q is the magnitude of the wave vector and S(Q) is the corrected and properly normalized total powder diffraction pattern of the material [For details see: Proffen, T.; Billinge, S. J. L. J. Appl. Crystallogr. 1999, 32, 572. Billinge, S. J. L.; Egami, T. Phys. Rev. B. 1993, 47, 14 386].
25. 0 are the local and average atomic number densities, respectively, Q is the magnitude of the wave vector and S(Q) is the corrected and properly normalized total powder diffraction pattern of the material [For details see: Proffen, T.; Billinge, S. J. L. J. Appl. Crystallogr. 1999, 32, 572. Billinge, S. J. L.; Egami, T. Phys. Rev. B. 1993, 47, 14 386].
26. Kennedy, J. D.; McFarlane, W. Multinuclear NMR; Mason, J., Ed.; Plenum Press: New York, 1987, pp 305-334. Jiang, T.; Ozin, G. A.; Bedard, R. L. Adv. Mater. 1994, 6, 860.
27. Kennedy, J. D.; McFarlane, W. Multinuclear NMR; Mason, J., Ed.; Plenum Press: New York, 1987, pp 305-334. Jiang, T.; Ozin, G. A.; Bedard, R. L. Adv. Mater. 1994, 6, 860.
28. 4Sn (see ref 15).
29. 4Sn with the spinning sidebands extending over ∼800 ppm.
30. Lippens, P. E. Phys. Rev. 1999, B60, 4576.
31. Rangan, K. K.; Trikalitis, P. N.; Kanatzidis, M. G.; J. Am. Chem. Soc. 2000, 722, 10 230. Rangan, K. K.; Trikalitis, P. N.; Bakas, T.; Kanatzidis, M. G. Chem. Commun. 2001, 809.
32. Rangan, K. K.; Trikalitis, P. N.; Kanatzidis, M. G.; J. Am. Chem. Soc. 2000, 722, 10 230. Rangan, K. K.; Trikalitis, P. N.; Bakas, T.; Kanatzidis, M. G. Chem. Commun. 2001, 809.
33. 3Br possesses no chromophore and shows no PL.
34. + was detected (m/z = 257) indicating S atom extraction from the framework. This chemical transformation ultimately results in framework collapse.