Deoxygenation of Polynuclear Metal-Oxo Anions: Synthesis, Structure, and Reactivity of the Condensed Polyoxoanion [C4H9]4(NbW5O18) 2O

Inorganic Chemistry

Volumn 35, Issue 9, 1996, Pages 2524-2529

  Lu, Ying Jie ^a   Lalancette, Roger ^b   Beer, Robert H ^a  

^a Och Spine at New York Presbyterian Hospitals   (United States)

^b RUTGERS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0038061833     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic951197c     Document Type: Article

References (63)

1. (a) Pope, M. T. Heteropoly and Isopoly Oxometalates; Springer Verlag: New York, 1983.
2. (b) Day, V. W.; Klemperer, W. G. Science 1985, 228, 533.
3. (c) Pope, M. T ; Müller, A. Angew. Chem., Int. Ed. Engl. 1991, 30, 34.
4. (d) Pope, M. T., Müller, A. Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity; Kluwer Academic Publishers: Dordrecht, Netherlands, 1994.
5. (e) Jansen, R. J. J.; van Veldhuizen, H. M.; Schwegler, M. A.; van Bekkum, H. Recl. Trav. Chim. Pays-Bas 1994, 113, 115.
6. (a) Kim, G.; Hagen, K.; Hill, C. L. Inorg. Chem. 1992, 31, 5316 and references therein,
7. (b) Hou, Y.; Hill, C. L. J. Am. Chem. Soc. 1993, 115, 11823.
8. (c) Zubieta, J. A. In Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity; Pope, M. T., Muller, A., Eds.; Kluwer Academic Publishers: Dordrecht, Netherlands, 1994; p 129.
9. (d) Strong, J. B.; Ostrander, R.; Rheingold, A. L.; Maata, E. A. J Am. Chem. Soc. 1994, 116, 3601.
10. (a) Schwartz, C.; Klemperer, W. G. Inorg. Chem. 1985, 24, 4459.
11. (b) Besecker, C. J.; Klemperer, W. G.: Maltbie, D. J.; Wright, D. A. Inorg. Chem. 1985, 24, 1027.
12. (c) Day, V. W.; Klemperer, W. G.; Maltbie, D. J. Organometallics 1985, 4, 104.
13. (a) Finke, R. G.; Droege, M. W. J. Am. Chem. Soc. 1984, 106, 7274.
14. (b) Day, V. W.; Klemperer, W. G.; Schwartz, C. J. Am. Chem. Soc. 1987, 109, 6030.
15. (c) Edlund, D. J.; Saxton, R. J.; Lyon, D. K.; Finke, R. G. Organometallics 1988, 7, 1692.
16. (d) Finke, R. G.; Nomiya, K.; Green, C. A.; Droege, M. W. Inorg. Synth. 1992, 29, 239.
17. (a) Trovarelli, A.; Finke, R. G. Inorg. Chem. 1993, 32, 6034.
18. (b) Nomiya, K.; Kaneko, M.; Kasuga, N. C.; Finke, R. G.; Pohl, M. Inorg. Chem. 1994, 33, 1469.
19. Other condensed polyoxoanions recently characterized by X-ray crystallography: (i) Wassermann, K.; Palm, R.; Lunk, H.-J.; Fuchs, J.; Steinfeld, N; Stoesser, R. Inorg. Chem. 1995, 34, 5029 and references therein, (ii) Galán-Mascarós, J. R.; Giménez-Saiz, C.; Triki, S.; Smail, T.; Gómez-Garcia, C. J.; Coronado, E.; Ouahab, L. Angew. Chem., Int. Ed. Engl. 1995, 34, 1460.
20. Other condensed polyoxoanions recently characterized by X-ray crystallography: (i) Wassermann, K.; Palm, R.; Lunk, H.-J.; Fuchs, J.; Steinfeld, N; Stoesser, R. Inorg. Chem. 1995, 34, 5029 and references therein, (ii) Galán-Mascarós, J. R.; Giménez-Saiz, C.; Triki, S.; Smail, T.; Gómez-Garcia, C. J.; Coronado, E.; Ouahab, L. Angew. Chem., Int. Ed. Engl. 1995, 34, 1460.
21. (a) Shriver, D. F. The Manipulation of Air-Sensitive Compounds; J. Wiley and Sons: New York, 1986.
22. (b) McNally, J. P.; Leong, V. S.; Cooper, N. J. ACS Symp. Ser. 1987, 357, 6-23.
23. Che, T. M.; Day, V. W.; Francesconi, L. C.; Fredrich, M. F.; Klemperer, W. G. Inorg. Chem. 1985, 24, 4055.
24. (a) Bradley, D. C.; Chakravarti, B. N.; Wardlaw, W. J. Chem. Soc. 1956, 2381.
25. (b) Bradley, D. C.; Wardlaw, W.; Whitley, A. J. Chem. Soc. 1955, 726.
26. (a) Filowitz, M.; Ho, R. C. K.; Klemperer, W. G. Inorg. Chem. 1979, 18, 93.
27. (b) Flynn, C. M., Jr.; Stucky, G. D. Inorg. Chem. 1969, 8, 178.
28. 25b
29. Sanchez, C.; Livage, J.; Launay, J. P.; Fournier, M. J. Am. Chem. Soc. 1983, 105, 6817.
30. Sheldrick, G. SHELXTL/PC, Siemens Analytical X-Ray Instrument. Inc.: Madison, WI, 1990.
31. 3b
32. (a) Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds: J. Wiley and Sons: New York, 1988; p 232.
33. (b) Housmekerides, C. E.; Ramage, D. L.; Kretz, C. M.; Shontz, J. T.; Pilato, R. S.; Geoffroy, G. L.; Rheingold, A. L.; Haggerty, B. S. Inorg. Chem. 1992, 31, 4453.
34. (c) Jones, E. L.; Reynolds, J. G.; Huffman, J. C.; Christou, G. Polyhedron 1991, 10, 1817.
35. (a) Rehder, D. In Transition Metal Nuclear Magnetic Resonance; Presogin, P. S., Ed.; Elsevier: Amsterdam, The Netherlands, 1991; p 45.
36. (b) Kidd, G. R. In NMR of Newly Accessible Nuclei; Laszlo, P., Ed.; Academic Press: New York, 1983; pp 103-130.
37. 15b
38. Sola, J.; Do, Y.; Berg, J. M.; Holm, R. H. Inorg. Chem. 1985, 24, 1706.
39. 3c
40. (a) Prout, K.; Cameron, T. S.; Forder, R. A.; Critchley, S. R.; Denton, B.; Rees, G. V. Acta Crystallogr. 1974, B30, 2290.
41. (b) Bottomley, F.; Keizer, P. N.; White, P. S.; Preston, K. F. Organometallics 1990, 9, 1916.
42. (a) Dunitz, J. D.; Orgel, L. E. J. Chem. Soc. 1953, 2594.
43. (b) Cotton, F. A.; Najjar, R. C. Inorg. Chem. 1981, 20, 1866.
44. (a) Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; J. Wiley and Sons: New York, 1988; p 156.
45. (b) Pope, M. T. Heteropoly and Isopoly Oxometalates; Springer Verlag: New York, 1983; pp 18-21.
46. (a) Lindqvist, I. Ark. Kemi 1953, 5, 247.
47. (b) Bradley, D. C.; Hursthouse, M. B.; Rodesiler, P. F. J. Chem. Soc., Chem. Commun. 1968, 1112.
48. (c) Flynn, C. M.; Stuckey, G. D. Inorg. Chem. 1969, 8, 335.
49. (d) Greaeber E. J.; Morosin, B. Acta Crystallogr. 1977, B33, 2137.
50. Fuchs, J. V.; Freiwald, W.; Hartl, H. Acta Crystallogr. B34, 1764.
51. Mayer, J. Inorg. Chem. 1988, 27, 3899.
52. (a) Besecker, C. J.; Day, V. W.; Klemperer, W. G.; Thompson, M. R. J. Am. Chem. Soc. 1982, 104, 6158.
53. (b) Besecker, C. J.; Day, V. W.; Klemperer, W. G.; Thompson, M. R. J. Am. Chem. Soc. 1984, 106, 4125.
54. (c) Besecker, C. J.; Day, V. W.; Klemperer, W. G.; Thompson, M. R. Inorg. Chem. 1985, 24, 44.
55. (d) Day, V. W.; Klemperer, W. G.; Main, D. J. Inorg. Chem., 1990 29, 2345.
56. Allcock, H. R.; Bissell, E. T.; Shawl, E. T. Inorg. Chem. 1973, 12, 2963.
57. Mohs, T. R.; Yapp, G. P. A.; Rheingold, A. L.; Maata, E. A. Inorg. Chem. 1995, 34, 9.
58. Iball, J.; Low, J. N.; Weakley, T. J. R. J. Chem. Soc., Dalton Trans. 1974, 2021.
59. Pretsch, P. D.; Seibel, J.; Simon, W.; Clerc, T. Tables of Spectral Data for Structural Determination of Organic Compounds; Springer-Verlag: Berlin, 1989.
60. Knoth, W. H.; Harlow, R. L. J. Am. Chem. Soc. 1981, 103, 4265.
61. (a) Kung, H. H. Transition Metal Oxides: Surface Chemistry and Catalysis; Elsevier: Amsterdam, The Netherlands, 1989; Chapter 6.
62. (b) Barteau, M. A. J. Vac. Sci. Technol. A 1993, 11, 2162.
63. Clegg, W.; Elsegood, M. R. J.; Errington, R. J., Havelock, J. J. Chem. Soc., Dalton Trans. 1996, 681.