Diastereoselective addition of α-metalated sulfoxides to imines revisited: Mechanism, computational studies, and the effect of external chiral ligands

Collection of Czechoslovak Chemical Communications

Volumn 68, Issue 5, 2003, Pages 885-898

  Pedersen, Brian ^a   Rein, Tobias ^a   Søtofte, Inger ^a   Norrby, Per Ola ^a   Tanner, David ^a  

^a TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

Author keywords

Asymmetric additions; Carbanions; Chiral sulfoxides; Diastereoselectivity; Imines; N ligands; Organolithium reagents; Quantum mechanical calculations

Indexed keywords

2 (ANILINO) 2 PHENYLETHYL 4 TOLYLSULFOXIDE; 2 TERT BUTYL 2 (2 METHOXYANILINO)ETHYL 4 TOLYLSULFOXIDE; LIGAND; SULFOXIDE; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CHIRALITY; DIASTEREOISOMER; QUANTUM MECHANICS; REACTION TIME; STEREOCHEMISTRY; X RAY CRYSTALLOGRAPHY;

EID: 0038044641     PISSN: 00100765     EISSN: None     Source Type: Journal    
DOI: 10.1135/cccc20030885     Document Type: Article

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