Electrochemical dissolution of simulated "white inclusions" in nitric acid. Linear voltammetry study with Mo, Re, Ru metals and their alloys electrodes

Radiochimica Acta

Volumn 91, Issue 7, 2003, Pages 419-425

  Maslennikov, A ^a   Fourest, B ^b   David, F ^b   Masson, M ^c  

^a RUSSIAN ACADEMY OF SCIENCES   (Russian Federation)

^b Institute of Molecular Physics   (France)

^c NONE

Author keywords

Electrochemical dissolution; Mo; Re; Ru alloys

Indexed keywords

ALLOY; MOLYBDENUM; NITRIC ACID; RHENIUM; RUTHENIUM;

ARTICLE; DISSOLUTION; ELECTROCHEMICAL ANALYSIS; ELECTRODE; PHYSICAL CHEMISTRY; POTENTIOMETRY; SIMULATION;

EID: 0038037535     PISSN: 00338230     EISSN: None     Source Type: Journal    
DOI: 10.1524/ract.91.7.419.20014     Document Type: Article

References (27)

1. Schmid, M.: Analyse des résidus de dissolution primaires et secondaires. Thèse de l'Universite technique de Munich (1986) p. 235 (in French).
2. Boudry, J., Miquel, P.: Adaptation of the PUREX process to the reprocessing of fast reactor fuel. ANS Topical meeting on the "Back end of the fuel cycle", Savannah, Georgia, March 9-22 (1978).
3. Kleykamp, H.: Zusammensetzung der Rückstände bei der Auflösung bestrahlter LWR Brennstoffe in Salpetersäure. Kfk 4476 Oct. (1988) p. 145.
4. Gonda, K., Oka, K., Nemoto, T.: Characteristics behavior of emulsion at nuclear fuel reprocessing. Nucl. Technol. 57, 192 (1982).
5. Octavio, J., Paschoal, A., Kleykamp, H., Thummler, F.: Phase equilibria in Quaternary molybdenum-ruthenium-rhodium-palladium system. Z. Metallkde. 4(10), 652 (1983).
6. Jeskins, I. L., Brown, P. E.: Characterization of dissolution residues - fuel element cladding and fission product insolubles. Radiochim. Acta 36, 25 (1984).
7. O'Boyle, D. R., Brown, F. L., Sanecki, J. E.: Solid fission product behavior in uranium-plutonium oxide fuel irradiated in a fast neutron flux. J. Nucl. Mater. 29, 27 (1969).
8. 2 systems. J. Nucl. Mater. 130, 426 (1985).
9. Ginzburg, S. I., Yezerskaya, N. A., Prokof'eva, I. V., Fedorenko, N. V., Shlenskaya, V. I., Bel'sky, N. K.: Analytical Chemistry of the Platinum Group Metals. In: Analytical chemistry of the elements Series. Nauka Publ. Moscow (1972) pp. 21-22 (in Russian).
10. Bolshakov, K. A., Sinitsyn, N. M., Borbat, B. F., Borisov, V. V.: About the behavior of Ru in the solutions of sulfuric acid. Sov. Radiochem. 11, 107 (1969) (in Russian).
11. Lobanov, E. M., Husnutdinov, R. I.: Preparation of the Ir and Rh standard solutions for radioactivation analysis, using the electrolytic dissolution with alterating current. Sov. Anal. Chem. 21, 743 (1966).
12. Goryunov, A. A., Ryabov, A. N.: A novel method for ruthenium dissolution. Russ. J. Inorg. Chem. 10, 2596 (1965).
13. Rard, J. A., Rand, M. H., Anderegg, G., Wanner, H.: Chemical thermodynamic of technetium. (Sandino Amalia, M. C., Osthols, E., eds.) NEA Elsevier Publ., Amsterdam (1999) pp. 233-263.
14. Heumann, T., Stolica, N.: Molybdenium. In: Encyclopedia of the electrochemistry of the elements. (Bard, A., ed.) Marcel Dekker, New-York - Basel (1973) Vol. 5, pp. 138-225 (and references there).
15. Cheshko, T. M., Davydov, A. D., Koudryavtsev, V. N.: Anodic behavior of molybdenum in the solutions of metansulfonic acid. Russ. Electrochem. 34, 1332 (1998).
16. Pozdeeva, A. A., Antonovskaya, A. I., Sukhotin, A. M.: Molybdenum passivity. Metal Inhibition (Zatshita metallov) 1, 20 (1965).
17. Wang, K., Li, Y.-S., Xe, P.: In situ identification of surface species of Mo in different media. Electrochim. Acta 43, 2459 (1998).
18. Badawy, W. A., Al-Khafari, F. M.: Corrosion and passivation behavior of molybdenum in aqueous solutions at different pH. Electrochim. Acta 44, 693 (1998).
19. Cardwell, T. J., Magree, R. J.: Technetium. In: Encyclopedia of Electrochemistry of the Elements. (Bard, A. J., ed.) A. Dekker Publ., New York (1974) Vol. 2, p. 125.
20. Spitsyn, V. I., Kuzina, A. F.: Technetium. Nauka Publ., Moscow (1981) p. 256.
21. Borisova, L., Ermakov, A.: Rhenium analytical chemistry. In: Analytical chemistry of the elements Series. Nauka Publ., Moscow (1974) pp. 16-18.
22. Llopis, J. F., Tordesillas, I. M.: Ruthenium. In: Encyclopedia of the electrochemistry of the elements. (Bard, A., ed.) Marcel Dekker, New-York - Basel (1973) Vol. 5, pp. 277-298.
23. Kotz, R., Stucki, S.: Oxygen evolution and corrosion of rutheniumiridium alloys. J. Electrochem. Sci. Technol. 132, 103 (1985).
24. Bard, A. Parsons, R., Jordan, J. (eds.): Standard potentials in aqueous solutions. Marcel Dekker Publ., New-York - Basel (1986).
25. Bard, A., Faulkner, R.: Electrochimie. Principes, méthodes et applications. Masson Publ. (1983) pp. 101-102.
26. Niemiec, J.: X-ray analysis of technetium-molybdenum alloys. Bull. Acad. Pol. Sci., Ser. Sci. Chim. XI, 305 (1963).
27. Kleykamp, H.: Thermodynamics of the Mo-Ru system. J. Less-Comm. Met. 144, 79 (1988).