Zinc saccharate: A robust, 3D coordination network with two types of isolated, parallel channels, one hydrophilic and the other hydrophobic

Angewandte Chemie - International Edition

Volumn 42, Issue 16, 2003, Pages 1848-1851

  Abrahams, Brendan F ^a   Moylan, Michael ^a   Orchard, Simon D ^a   Robson, Richard ^a  

^a UNIVERSITY OF MELBOURNE   (Australia)

Author keywords

Carbohydrates; Coordination polymer; Structure elucidation; Zinc

Indexed keywords

CATALYST ACTIVITY; CRYSTAL STRUCTURE; HYDROPHILICITY; HYDROPHOBICITY;

COORDINATION NETWORKS;

ZINC COMPOUNDS;

UNCLASSIFIED DRUG; ZINC DERIVATIVE; ZINC SACCHARATE;

ARTICLE; CHELATION; CHEMICAL BINDING; CHEMICAL STRUCTURE; HYDROPHILICITY; HYDROPHOBICITY; MOLECULAR DYNAMICS; STRUCTURE ANALYSIS; THERMOGRAVIMETRY;

EID: 0038031636     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200250633     Document Type: Article

References (13)

1. "Chemicals and Materials from Renewable Resources: "D. E. Kiely, ACS Symp. Ser. 2001, 784, 64-80.
2. F. Ferrier, A. Avezou, G. Terzian, D. Benlian, J. Mol. Struct. 1998, 442, 281.
3. T. Taga, Y. Kuroda, K. Osaki, Bull. Chem. Soc. Jpn. 1977, 50, 3079.
4. T. Taga, T. Shimada, N. Mimura, Acta Crystallogr. Sect. C 1994, 50, 1076.
5. B. Sheldrick, W. Mackie, Acta Crystallogr. Sect. C 1989, 45, 1072.
6. B. Sheldrick, W. Mackie, D. Akrigg, Acta Crystallogr. Sect. C 1989, 45, 191.
7. [12]). CCDC-197968-1949971 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+ 44) 1223-336-033; or deposit@ccdc.cam.ac.uk).
8. 1.
9. A. L. Spek, PLATON, A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, The Netherlands, 1998.
10. This hydrogen-bonding of water to pendant hydroxy groups of the network is reminiscent of the behavior of a coordination polymer of 1,2-dipyridylglycol recently reported by R. Kitaura, K. Fujimoto, S. Noro, M. Kondo, S. Kitagawa, Angew. Chem. 2002, 114, 141; Angew. Chem. Int. Ed. 2002, 41, 133.
11. This hydrogen-bonding of water to pendant hydroxy groups of the network is reminiscent of the behavior of a coordination polymer of 1,2-dipyridylglycol recently reported by R. Kitaura, K. Fujimoto, S. Noro, M. Kondo, S. Kitagawa, Angew. Chem. 2002, 114, 141; Angew. Chem. Int. Ed. 2002, 41, 133.
12. G. M. Sheldrick, SHELXTL V5.1 Software Reference Manual, Bruker AXS, Inc., Madison, Wisconsin, USA, 1997.
13. G. M. Sheldrick, SHELX-97, Program for Crystal Structure Analysis, University of Göttingen, Göttingen (Germany), 1997.