1,4-Addition of Grignard reagents to 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene

Angewandte Chemie - International Edition

Volumn 42, Issue 16, 2003, Pages 1863-1866

  Renner, Jens ^a   Bergsträßer, Uwe ^a   Binger, Paul ^a   Regitz, Manfred ^a  

^a Rheinland Pfälzische Technische Universität Kaiserslautern Landau   (Germany)

Author keywords

1,4 Addition; Grignard reaction; Magnesium; Phosphorus; Phosphorus heterocycles

Indexed keywords

ADDITION REACTIONS; BENZENE; HYDROLYSIS; SALTS;

GRIGNARD REAGENTS;

MAGNESIUM COMPOUNDS;

2,4,6 TRI TERT BUTYL 1,3,5 TRIPHOSPHABENZENE; BENZENE DERIVATIVE; REAGENT; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BINDING; CONFORMATIONAL TRANSITION; CRYSTAL STRUCTURE; CYCLOADDITION; GRIGNARD REACTION; REACTION ANALYSIS; STEREOCHEMISTRY; SYNTHESIS;

EID: 0038031624     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200250182     Document Type: Article

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26. -3; symmetry operations to generate equivalent positions -x, -y, -z. Note: One of the THF molecules coordinated to magnesium displays a disorder that is considered in the refinement by means of two split positions for C29 (occupancy factor 0.7) and C29′ (occupancy factor 0.3). Besides the THF molecules coordinated to magnesium, two further free THF molecules were localized and refined anisotropically. One of these molecules also showed a pronounced disorder, which is included in the refinement with two positions (occupancy factor 0.5 each) with limitation of the anisotropic temperature factors. This and the decomposition of the crystal observed in spite of a measurement temperature of 240 K resulted in relatively high R values for the structure model.
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28. -3; symmetry operations to generate equivalent positions -x + 3/2,y,z.
29. -3. CCDC-205753 (3d), 205754 (4a), and 205755 (5) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ ccdc.cam.ac.uk).