Phase separation during radiation crosslinking of unsaturated polyester resin

Radiation Physics and Chemistry

Volumn 67, Issue 3-4, 2003, Pages 415-419

  Pucić, Irina ^a   Ranogajec, Franjo ^a  

^a RUDER BO KOVI INSTITUTE   (Croatia)

Author keywords

DSC; FTIR; Phase separation; Radiation initiated crosslinking; Thickness; Unsaturated polyester resin

Indexed keywords

COPOLYMERIZATION; CROSSLINKING; DIFFERENTIAL SCANNING CALORIMETRY; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GELS; PHASE SEPARATION; RADIATION EFFECTS; RESINS; UNSATURATED POLYMERS;

EXOTHERMIC REACTIONS;

POLYESTERS;

POLYESTER; RESIN;

CONFERENCE PAPER; CROSS LINKING; GEL; HEAT TREATMENT; HIGH TEMPERATURE; LOW TEMPERATURE; PHASE SEPARATION; POLYMERIZATION;

EID: 0038019633     PISSN: 0969806X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0969-806X(03)00077-X     Document Type: Conference Paper

References (17)

1. Avella M., Martuscelli E., Mazzola M. Kinetic study of the cure reaction of unsaturated polyester resins. J. Therm. Anal. 30:1985;1359-1366.
2. Bergmark P., Flodin P. Structure of the carbon chain polymer in unsaturated polyesters. Polymer. 28:1987;1662-1666.
3. Day D.R. Cure characterization of thick SMC parts using dielectric and finite difference analysis. J. Reinf. Plast. Compos. 13(10):1994;918-926.
4. Delahaye N., Marais S., Saiter J.M., Metayer M. Characterization of unsaturated polyester resin cured with styrene. J. Appl. Polym. Sci. 67(4):1998;695-703.
5. Dobo J. Some features of radiation processing in the plastics industry. Radiat. Phys. Chem. 26(5):1985;555-558.
6. Hsu C.P., Lee L.J. Free-radical crosslinking copolymerization of styrene unsaturated polyester resins.1. Phase Separation Microgel Formation Polymer. 34(21):1993;4496-4505.
7. Hsu C.P., Lee L.J. Free-radical crosslinking copolymerization of styrene unsaturated polyester resins.3. Kinet. Gelation Mech. Polymer. 34(21):1993;4516-4523.
8. Huang Y.J., Chen C.J. Curing of unsaturated polyester resins-effects of comonomer composition. III. Medium temperature reactions. J. Appl. Polym. Sci. 48:1993;151-165.
9. Kubota H. Curing of highly reactive polyester resin under pressure. kinetic studies by differential scanning calorimetry J. Appl. Polym. Sci. 19:1975;2279-2297.
10. Lu M.G., Kim S.W. Unsaturated polyester resin based on recycled pet. preparation and curing behavior J. Appl. Polym. Sci. 80(7):2001;1052-1057.
11. Lu M.G., Shim M.J., Kim S.W. Curing behavior of an unsaturated polyester system analysed by avrami equation. Thermochim. Acta. 323:1998;37-42.
12. Martin J.L. Kinetic analysis of an asymmetrical DSC peak in the curing of an unsaturated polyester resin catalysed with MEKP and cobalt octoate. Polymer. 40(12):1999;3451-3462.
13. Paauw M., Pizzi A. A FTIR analysis method for simple unsaturated polyesters. J. Appl. Polym. Sci. 42:1991;1377-1384.
14. Paauw M., Pizzi A. Completion of unsaturated polyesters analysis by FTIR. J. Appl. Polym. Sci. 48:1993;931-934.
15. Pucić I., Ranogajec F. DC-electrical conductivity as a method for monitoring radiation curing of unsaturated polyester resins, 1. Measurement conditions and comparison with extraction analysis data. Radiat. Phys. Chem. 46(3):1995;365-370.
16. Urban M.W., Gaboury S.R., Provder T. Spectroscopic evidence for styrene homopolymerization during polyester/styrene crosslinking. Polym. Commun. 32(6):1991;171-175.
17. Yang H., Lee L.J. Effects on resin chemistry on redox polymerization of unsaturated polyester resins. J. Appl. Polym. Sci. 84(1):2002;211-227.