Addition of metal cyanides to tosylhydrazones of aldehydes in aprotic solvents: A new method for one-carbon homologation of aldehydes and for the synthesis of α-(N2-tosylhydrazino)nitriles

Synthesis

Volumn , Issue 7, 2003, Pages 1049-1054

  Marczak, Stanisław ^a   Wicha, Jerzy ^a  

^a POLISH ACADEMY OF SCIENCES   (Poland)

Author keywords

Aldehyde arylsulfonylhydrazones; Diethylaluminum cyanide; Scandium triflate; Trimethylsilyl cyanide; Trimethylsilyl triflate; Trimethyltin cyanide

Indexed keywords

CARBON; CATALYSTS; SCANDIUM; SYNTHESIS (CHEMICAL);

HOMOLOGATION;

CYANIDES;

ALDEHYDE; ALPHA (N 2 TOSYLHYDRAZINO)NITRILE DERIVATIVE; ALUMINUM DERIVATIVE; CARBON; CYANIDE; DIETHYLALUMINUM CYANIDE; LEWIS ACID; NITRILE; SCANDIUM; SCANDIUM TRIFLATE; SOLVENT; TOLUENESULFONIC ACID DERIVATIVE; TOSYLHYDRAZONE DERIVATIVE; TRIMETHYLSILYL CYANIDE; TRIMETHYLSILYL DERIVATIVE; TRIMETHYLSILYL TRIFLATE; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; CHEMICAL MODIFICATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; ROOM TEMPERATURE; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 0038018726     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-39161     Document Type: Article

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