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Volumn 221, Issue 1-3, 2003, Pages 119-129

Effects of metal-counterion interactions on the percolation in microemulsions composed of bis(N-octylethylenediamine)metal(II) complexes in water/benzene and water/chloroform systems

Author keywords

Metal complex surfactant; Microemulsion; Percolation; Reverse micelle; Self diffusion

Indexed keywords

BENZENE; DIFFUSION; ELECTRIC CONDUCTIVITY; SOLUTIONS; SOLVENTS;

EID: 0038013810     PISSN: 09277757     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0927-7757(03)00129-8     Document Type: Article
Times cited : (11)

References (35)
  • 5
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    • X. Lu, Z. Zhang, Y. Liang, J. Chem. Soc. Chem. Commun. (1994) 2731; Langmuir 12 (1996) 5501; Langmuir 13 (1997) 533.
    • (1996) Langmuir , vol.12 , pp. 5501
  • 6
    • 0000577497 scopus 로고    scopus 로고
    • X. Lu, Z. Zhang, Y. Liang, J. Chem. Soc. Chem. Commun. (1994) 2731; Langmuir 12 (1996) 5501; Langmuir 13 (1997) 533.
    • (1997) Langmuir , vol.13 , pp. 533
  • 14
    • 85020659121 scopus 로고    scopus 로고
    • note
    • The differences in the diffusion coefficients between the methyl protons and the methylene protons in the zinc(II) complexes were checked for many systems and were within 5%. There was no significant trend concerning the differences. The diffusion coefficients in the methanol and chloroform solutions are not shown here. Some of the results were described in [4,6].
  • 17
    • 85020646161 scopus 로고    scopus 로고
    • note
    • 0=5 than that of the dichloro-zinc(II) complex would be due to the twice larger concentrations of the former complex in benzene.
  • 24
    • 0001862196 scopus 로고
    • K.L. Mittal, B. Lindman (Eds.), Plenum, New York and London
    • (a) T.F. Tadros, in: K.L. Mittal, B. Lindman (Eds.), Surfactants in Solution, vol. 3, Plenum, New York and London, 1984, pp. 1501.
    • (1984) Surfactants in Solution , vol.3 , pp. 1501
    • Tadros, T.F.1
  • 32
    • 85020662742 scopus 로고    scopus 로고
    • note
    • 2 concentration condition is twice larger than the other dichloro complex systems, the difference in the conductivities between the nitrato and chloro systems is too large for the difference in the concentrations.
  • 35
    • 85020678195 scopus 로고    scopus 로고
    • note
    • When the Stokes radius is estimated from modified Eq. (1) by using the viscosity and the diffusion coefficient in concentrated solutions, the apparent estimated radius tends to decrease in highly aggregation systems with an increase of the solute concentrations on the contrary to the actual increase in the aggregate size [17,18].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.