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note
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3 (prepared as described in ref 6) were treated in situ with 3 equiv of MeMgI at - 40 °C. The change of the solution color to yellow and the precipitation of inorganic salts were observed over the course of 20 min. Heating the solutions to 0 °C immediately led to their darkening and then to the appearance of a metallic mirror on the inside surface of the reaction flask.
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0038151910
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note
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The total content of fluorene and bifluorene in the samples is ea. 1%, which does not interfere with the observation of the resonances from the main products at 20 °C.
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Some data dealing with catalytic behavior of 1 have been reported in: Knjazhanski, S. Va.; Cadenas, G.; Moreno G.; Zamora, M. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1999, 40(2), 831.
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0038490418
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note
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3 with 2-propanol. Our approach allows preparing both compounds easily in analytically pure form.
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31
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0038490417
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Chinese Pat. Appl. 1269367
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Wu, Q.; Lin, S.; Zhu, F. Chinese Pat. Appl. 1269367.
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Wu, Q.1
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