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5544231648
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According to the structure information, the Sm-A-Hex-B transition should belong to the XY universality class. To date, all the experimental results fails to show the expected criticality in both bulk samples and extremely thin films
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According to the structure information, the Sm-A-Hex-B transition should belong to the XY universality class. To date, all the experimental results fails to show the expected criticality in both bulk samples and extremely thin films.
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An error was found in previously calculating the units of the measured heat-capacity data [39]. For some unknown reasons, the measured heat capacity of this perfluorinated compound is about twice that of the ordinary liquid-crystal compounds
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An error was found in previously calculating the units of the measured heat-capacity data [39]. For some unknown reasons, the measured heat capacity of this perfluorinated compound is about twice that of the ordinary liquid-crystal compounds.
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33
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Even though the anomaly from a two-layer film cannot presently be detected, the surface-enhanced ordering transition presumably due to only the two outermost layers of thicker films can still be resolved because of our calorimeter's film thickness dependent signal-to-noise (S/N) ratio. Films of moderate thickness (≈ 20 layers) generally provide the highest quality data. We have determined that S/N must be improved by at least a factor of five before the heat-capacity anomaly associated with the Sm-A-Sm-C transition of two-layer H10F5MOPP films can be convincingly resolved. Several possible approaches are currently being evaluated.
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Surface ordering has been identified in various other systems, e.g., M. B. Feller, W. Chen, and Y. R. Shen, Phys. Rev. A 43, 6778 (1991); X. Z. Wu, B. M. Ocko, E. B. Sirota, S. K. Sinha, M. Deutsch, B. H. Cao, and M. W. Kim, Science 261, 1018 (1993); M. N. G. de Mul and J. A. Mann, Jr., Langmuir 10, 2311 (1994), and references found therein.
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Surface ordering has been identified in various other systems, e.g., M. B. Feller, W. Chen, and Y. R. Shen, Phys. Rev. A 43, 6778 (1991); X. Z. Wu, B. M. Ocko, E. B. Sirota, S. K. Sinha, M. Deutsch, B. H. Cao, and M. W. Kim, Science 261, 1018 (1993); M. N. G. de Mul and J. A. Mann, Jr., Langmuir 10, 2311 (1994), and references found therein.
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47
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and references found therein
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Surface ordering has been identified in various other systems, e.g., M. B. Feller, W. Chen, and Y. R. Shen, Phys. Rev. A 43, 6778 (1991); X. Z. Wu, B. M. Ocko, E. B. Sirota, S. K. Sinha, M. Deutsch, B. H. Cao, and M. W. Kim, Science 261, 1018 (1993); M. N. G. de Mul and J. A. Mann, Jr., Langmuir 10, 2311 (1994), and references found therein.
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p/(N-n) versus N. For n>2, an up turn in such a plot is identified for thinner films. Thus we conclude that only two outermost surface layers contribute to the small heat-capacity humps
-
p/(N-n) versus N. For n>2, an up turn in such a plot is identified for thinner films. Thus we conclude that only two outermost surface layers contribute to the small heat-capacity humps.
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