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note
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For the calix[6] dianionic structures, the NMR spectra are consistent with a 1,2,3-alternate conformation in solution, leading to a pattern of one pair of doublets and one singlet in the methylene region. The coalescence temperature of the pair of doublets was used for ΔG calculations.
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0038812851
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note
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Although the satisfactory elemental analysis cannot distinguish between the pure mixed-cation species versus a 1:1 ratio of the two single-cation species, NMR spectra are consistent with a single mixed-cation species in solution.
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0037798381
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note
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13C NMR spectra were recorded on a Varian XL-300 spectrometer at 300 and 75 MHz, respectively. Analytical samples were dried in a drying pistol under vacuum for at least 24 h. Microanalyses were performed by Desert Laboratories, Tucson, AZ. IR spectra were obtained with an Infinity GoldTM FTIR spectrometer. Vacuum filtrations used Fisherbrand grade Q8 filter paper.
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