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Volumn 36, Issue 12, 2003, Pages 4646-4658

Length of subchains and chain ends in cross-linked polymer networks

Author keywords

[No Author keywords available]

Indexed keywords

CROSSLINKED POLYMER NETWORKS; INTRAMOLECULAR LOOPS;

EID: 0037934708     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma034044e     Document Type: Article
Times cited : (35)

References (43)
  • 9
    • 0038321140 scopus 로고    scopus 로고
    • note
    • 5), but we will show that this is just an approximation valid far beyond the gel point.
  • 25
    • 0004051232 scopus 로고
    • Computer simulation of polymer network formation
    • Colbourn, E. A., Ed.; Longman: Harlow, England; Chapter 8
    • Eichinger, B. E.; Akgiray, O. In Computer simulation of polymer network formation; in: Computer Simulation of Polymers; Colbourn, E. A., Ed.; Longman: Harlow, England, 1994; Chapter 8.
    • (1994) Computer Simulation of Polymers
    • Eichinger, B.E.1    Akgiray, O.2
  • 29
    • 0037645616 scopus 로고    scopus 로고
    • note
    • The handling of reactions connecting chains directly follows as a simplification.
  • 30
    • 0038659808 scopus 로고    scopus 로고
    • note
    • This extent of reaction is clearly different from the fraction of reactions which involve cross-linking agents.
  • 31
    • 0037983515 scopus 로고    scopus 로고
    • note
    • According to Dusek et al., we call structures as on the right side of Figure 1 cycles. The term intramolecular loops is also used in the literature.
  • 32
    • 0037983514 scopus 로고    scopus 로고
    • note
    • There exists no proof for this but within the scope of accuracy of the algorithms used, the results were identical.
  • 33
    • 0038659807 scopus 로고    scopus 로고
    • note
    • The details of the simulations are discussed in section 3.2.1.
  • 34
    • 0037983513 scopus 로고    scopus 로고
    • note
    • C) to show that the second reaction of the cycle forming cross-links obeys another rule disturbing the binomial distribution.
  • 36
    • 0038321142 scopus 로고    scopus 로고
    • note
    • With the simplifying assumption that the link between cross-link and chain is comparable to the links along the chain; otherwise, the distance N has to be adapted accordingly.
  • 37
    • 0037983511 scopus 로고    scopus 로고
    • note
    • Depending on the length of the bridge between the chains this term has to be modified.
  • 41
    • 0037983510 scopus 로고    scopus 로고
    • note
    • We neglect the effect of the finite length of the chains as a good approximation.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.