Unusual oxidation of dichalcogenido complexes of platinum

Chemistry Letters

Volumn 32, Issue 2, 2003, Pages 170-171

  Nagata, Kazuto ^a   Takeda, Nobuhiro ^a   Tokitoh, Norihiro ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; PLATINUM COMPLEX; SELENIUM DERIVATIVE; SILICONE DERIVATIVE; SULFUR DERIVATIVE; SULFUR OXIDE;

ARTICLE; OXIDATION; SYNTHESIS;

EID: 0037883536     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2003.170     Document Type: Article

References (24)

1. For reviews on transition metal oxopolychalcogenido complexes, see: W. Weigand and R. Wünsch, Chem. Ber., 129, 1409 (1996); W. A. Scenk, Angew. Chem., Int. Ed. Engl., 26, 98 (1987).
2. For reviews on transition metal oxopolychalcogenido complexes, see: W. Weigand and R. Wünsch, Chem. Ber., 129, 1409 (1996); W. A. Scenk, Angew. Chem., Int. Ed. Engl., 26, 98 (1987).
3. M. E. Raseta, S. A. Cawood, M. E. Welker, and A. L. Rheingold. J. Am. Chem. Soc., 111. 8268 (1989); G. A. Urove and M. E. Welker, Organometallics, 7, 1013 (1988).
4. M. E. Raseta, S. A. Cawood, M. E. Welker, and A. L. Rheingold. J. Am. Chem. Soc., 111. 8268 (1989); G. A. Urove and M. E. Welker, Organometallics, 7, 1013 (1988).
5. A. Z. Rys, A.-M. Lehuis, A. Shaver, and D. N. Harpp, Organometallics, 18, 1113 (1999); M. A. Halcrow, J. C. Huffman, and G. Christou, Inorg. Chem., 33, 3639 (1994); M. Herberhold, B. Schmidkonz, M. L. Ziegler, and T. Zahn, Angew. Chem., Int. Ed. Engl., 24, 515 (1985); J. E. Hoots, D. A. Lesch, and T. B. Rauchfuss, Inorg. Chem., 23, 3130 (1984); J. E. Hoots, T. B. Rauchfuss, and S. R. Wilson, J. Chem. Soc., Chem. Commun., 1983, 1226; A. P. Ginsberg, W. E. Lindsell, C. R. Sprinkle, K. W. West, and R. L. Cohen, Inorg. Chem., 21, 3666 (1982); G. Schmid and G. Ritter, Angew. Chem., Int. Ed. Engl., 14, 645 (1975).
6. A. Z. Rys, A.-M. Lehuis, A. Shaver, and D. N. Harpp, Organometallics, 18, 1113 (1999); M. A. Halcrow, J. C. Huffman, and G. Christou, Inorg. Chem., 33, 3639 (1994); M. Herberhold, B. Schmidkonz, M. L. Ziegler, and T. Zahn, Angew. Chem., Int. Ed. Engl., 24, 515 (1985); J. E. Hoots, D. A. Lesch, and T. B. Rauchfuss, Inorg. Chem., 23, 3130 (1984); J. E. Hoots, T. B. Rauchfuss, and S. R. Wilson, J. Chem. Soc., Chem. Commun., 1983, 1226; A. P. Ginsberg, W. E. Lindsell, C. R. Sprinkle, K. W. West, and R. L. Cohen, Inorg. Chem., 21, 3666 (1982); G. Schmid and G. Ritter, Angew. Chem., Int. Ed. Engl., 14, 645 (1975).
7. A. Z. Rys, A.-M. Lehuis, A. Shaver, and D. N. Harpp, Organometallics, 18, 1113 (1999); M. A. Halcrow, J. C. Huffman, and G. Christou, Inorg. Chem., 33, 3639 (1994); M. Herberhold, B. Schmidkonz, M. L. Ziegler, and T. Zahn, Angew. Chem., Int. Ed. Engl., 24, 515 (1985); J. E. Hoots, D. A. Lesch, and T. B. Rauchfuss, Inorg. Chem., 23, 3130 (1984); J. E. Hoots, T. B. Rauchfuss, and S. R. Wilson, J. Chem. Soc., Chem. Commun., 1983, 1226; A. P. Ginsberg, W. E. Lindsell, C. R. Sprinkle, K. W. West, and R. L. Cohen, Inorg. Chem., 21, 3666 (1982); G. Schmid and G. Ritter, Angew. Chem., Int. Ed. Engl., 14, 645 (1975).
8. A. Z. Rys, A.-M. Lehuis, A. Shaver, and D. N. Harpp, Organometallics, 18, 1113 (1999); M. A. Halcrow, J. C. Huffman, and G. Christou, Inorg. Chem., 33, 3639 (1994); M. Herberhold, B. Schmidkonz, M. L. Ziegler, and T. Zahn, Angew. Chem., Int. Ed. Engl., 24, 515 (1985); J. E. Hoots, D. A. Lesch, and T. B. Rauchfuss, Inorg. Chem., 23, 3130 (1984); J. E. Hoots, T. B. Rauchfuss, and S. R. Wilson, J. Chem. Soc., Chem. Commun., 1983, 1226; A. P. Ginsberg, W. E. Lindsell, C. R. Sprinkle, K. W. West, and R. L. Cohen, Inorg. Chem., 21, 3666 (1982); G. Schmid and G. Ritter, Angew. Chem., Int. Ed. Engl., 14, 645 (1975).
9. A. Z. Rys, A.-M. Lehuis, A. Shaver, and D. N. Harpp, Organometallics, 18, 1113 (1999); M. A. Halcrow, J. C. Huffman, and G. Christou, Inorg. Chem., 33, 3639 (1994); M. Herberhold, B. Schmidkonz, M. L. Ziegler, and T. Zahn, Angew. Chem., Int. Ed. Engl., 24, 515 (1985); J. E. Hoots, D. A. Lesch, and T. B. Rauchfuss, Inorg. Chem., 23, 3130 (1984); J. E. Hoots, T. B. Rauchfuss, and S. R. Wilson, J. Chem. Soc., Chem. Commun., 1983, 1226; A. P. Ginsberg, W. E. Lindsell, C. R. Sprinkle, K. W. West, and R. L. Cohen, Inorg. Chem., 21, 3666 (1982); G. Schmid and G. Ritter, Angew. Chem., Int. Ed. Engl., 14, 645 (1975).
10. A. Z. Rys, A.-M. Lehuis, A. Shaver, and D. N. Harpp, Organometallics, 18, 1113 (1999); M. A. Halcrow, J. C. Huffman, and G. Christou, Inorg. Chem., 33, 3639 (1994); M. Herberhold, B. Schmidkonz, M. L. Ziegler, and T. Zahn, Angew. Chem., Int. Ed. Engl., 24, 515 (1985); J. E. Hoots, D. A. Lesch, and T. B. Rauchfuss, Inorg. Chem., 23, 3130 (1984); J. E. Hoots, T. B. Rauchfuss, and S. R. Wilson, J. Chem. Soc., Chem. Commun., 1983, 1226; A. P. Ginsberg, W. E. Lindsell, C. R. Sprinkle, K. W. West, and R. L. Cohen, Inorg. Chem., 21, 3666 (1982); G. Schmid and G. Ritter, Angew. Chem., Int. Ed. Engl., 14, 645 (1975).
11. A. Z. Rys, A.-M. Lehuis, A. Shaver, and D. N. Harpp, Organometallics, 18, 1113 (1999); M. A. Halcrow, J. C. Huffman, and G. Christou, Inorg. Chem., 33, 3639 (1994); M. Herberhold, B. Schmidkonz, M. L. Ziegler, and T. Zahn, Angew. Chem., Int. Ed. Engl., 24, 515 (1985); J. E. Hoots, D. A. Lesch, and T. B. Rauchfuss, Inorg. Chem., 23, 3130 (1984); J. E. Hoots, T. B. Rauchfuss, and S. R. Wilson, J. Chem. Soc., Chem. Commun., 1983, 1226; A. P. Ginsberg, W. E. Lindsell, C. R. Sprinkle, K. W. West, and R. L. Cohen, Inorg. Chem., 21, 3666 (1982); G. Schmid and G. Ritter, Angew. Chem., Int. Ed. Engl., 14, 645 (1975).
12. K. Nagata, N. Takeda, and N. Tokitoh, Angew. Chem., Int. Ed., 41, 136 (2002).
13. 4)]; M. Murata, A. Ishii, and J. Nakayama, at the 81st Annual Meeting of the Chemical Society of Japan, March 2002, Abst., No. 4B334.
14. 14: C, 44.18; H, 8.46. Found: C, 44.27; H, 8.59.
15. I.-P. Lorenz and J. Kull, Angew. Chem., Int. Ed. Engl., 25, 261 (1986).
16. G. Schmid, G. Ritter, and T. Debaerdemaeker, Chem. Ber., 108, 3008 (1975).
17. 14: C, 47.49; H, 9.15. Found: C, 47.63; H. 9.25. The existence of the chlorine atom in 4 was confirmed by X-ray fluorescence spectroscopy.
18. 3 core are omitted to avoid confusion. All non-hydrogen atoms were refined anisotropically.
19. Examples of O,S-coordinated thiosulfate complex: A. Z. Rys, A.-M. Lebuis, A. Shaver, and D. N. Harpp, Inorg. Chem., 41, 3653 (2002); G. J. Kubas and R. R. Ryan, Inorg. Chem., 23, 3181 (1984); M. L. H. Green, A. H. Lynch, and M. G. Swanwick, J. Chem. Soc., Dalton Trans., 1972, 1445.
20. Examples of O,S-coordinated thiosulfate complex: A. Z. Rys, A.-M. Lebuis, A. Shaver, and D. N. Harpp, Inorg. Chem., 41, 3653 (2002); G. J. Kubas and R. R. Ryan, Inorg. Chem., 23, 3181 (1984); M. L. H. Green, A. H. Lynch, and M. G. Swanwick, J. Chem. Soc., Dalton Trans., 1972, 1445.
21. Examples of O,S-coordinated thiosulfate complex: A. Z. Rys, A.-M. Lebuis, A. Shaver, and D. N. Harpp, Inorg. Chem., 41, 3653 (2002); G. J. Kubas and R. R. Ryan, Inorg. Chem., 23, 3181 (1984); M. L. H. Green, A. H. Lynch, and M. G. Swanwick, J. Chem. Soc., Dalton Trans., 1972, 1445.
22. 14: C, 45.40; H. 8.69. Found: C, 45.29; H, 8.67.
23. P. S. Pregosin, Coord. Chem. Rev., 44, 247 (1982).
24. 3] has been reported: G. R. Hughes, P. C. Minshall, and D. M. P. Mingos, J. Less-Common Met., 116, 199 (1986).