CO2 and CO utilization: Radiation-induced carboxylation of aqueous chloroacetic acid to malonic acid

Radiation Physics and Chemistry

Volumn 67, Issue 5, 2003, Pages 617-621

  Getoff, Nikola ^a  

^a UNIVERSITY OF VIENNA   (Austria)

Author keywords

Carboxylation; Chloroacetic acid; Malonic acid; Utilization of carbon dioxide

Indexed keywords

BYPRODUCTS; CARBON DIOXIDE; CARBON MONOXIDE; CARBOXYLATION; IONIZING RADIATION; PH EFFECTS;

CARBOXYLATING RADICALS;

RADIATION CHEMISTRY;

CARBON DIOXIDE; CARBON MONOXIDE; CHLORIDE ION; CHLOROACETIC ACID; MALONIC ACID; OXALIC ACID; SUCCINIC ACID;

ARTICLE; CARBOXYLATION; CHEMICAL REACTION; IONIZING RADIATION; PH; RADIATION DOSE; RADIATION RESPONSE; RADIOLYSIS; REACTION ANALYSIS;

EID: 0037867845     PISSN: 0969806X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0969-806X(03)00145-2     Document Type: Article

References (40)

1. Buxton G.V., Sellers R.M. Acid dissociation constant of the carboxyl radical, pulse radiolysis studies of aqueous formic acid and sodium formate. J. Chem. Soc. Faraday Trans. I. 69:1973;555-559.
2. Buxton G.V., Greenstock C.L., Helman W.Ph., Ross A.B. Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals in aqueous solution. J. Phys. Chem. Ref. Data. 17:1988;513-886.
3. Chmielewski A.G., Illex E., Zimek Z., Romanowski M., Koperski K. Industrial demonstration plant for electron beam flue gas treatment. Radiat. Phys. Chem. 46:1995;1063-1066.
4. 2-pressure. Radiat. Phys. Chem. 46:1983;841-848.
5. 60Co-γ-rays. Int. J. Appl. Radiat. Isot. 13:1962;205-213. (in German).
6. 2 by UV-light. Z. Naturforsch. 17b:1962;87-90. (in German).
7. 60Co-γ-radiation. Z. Naturforsch. 17b:1962;751-762. (in German).
8. 2 under UV-irradiation. Z. Naturforsch. 18b:1963;169-170. (in German).
9. Getoff N. pH-dependence of the carboxylation of formic acid to oxalic acid by gamma-irradiation. Discuss. Faraday Soc. 36:1963;314-315.
10. 60Co-γ-radiation and UV-light. Österr. Chem. Ztg. 65:1964;143-155. (in German).
11. Getoff N. Carboxylation of formic acid in aqueous solution under the influence of UV-light. Photochem. Photobiol. 4:1965;433-438.
12. Getoff, N., 1965b. Photochemical carboylation of amines to amino acids in aqueous solution. Proceedings of the II Meeting of European Biochemical Society, Vienna, Austria, pp. 55-56.
13. Getoff, N., 1967. Fundamentals, technology and applications. In: Kaindl, K., Graul, E.H. (Eds.), Radiation Chemistry. Dr. A. Hüthig Publ. Comp., Heidelberg, Germany, pp. 226-249.
14. 2 and CO into organic compounds. Int. J. Hydrogen Energy. 19:1994;667-672.
15. Getoff N. Radiation-induced degradation of water pollutants. State of the art. Radiat. Phys. Chem. 47:1996;581-593.
16. 2-utilization using ionizing radiation and UV-light. World Resour. Rev. 9:1997;86-100.
17. Getoff N. Radiation-induced carboxylation of chloroacetate ion. an avenue for making value-added products from carbon dioxide World Resour. Rev. 11:1999;551-561.
18. Getoff N. Factors influencing the efficiency of radiation-induced degradation of water pollutants. Radiat. Phys. Chem. 65:2002;437-446.
19. Getoff N., Schenck G.O. On the formation of amino acids by gamma-rays-induced carboxylation of amines in aqueous solution. Radiat. Res. 31:1967;486-506.
20. 60CO-γ-ray-induced formation of sulfur-containing amino acids in aqueous solutions. Adv. Chem. Ser. 81:1968;337-343.
21. 2 in aqueous solution under the influence of radiation. Tetrahedron Lett. 18:1960;17-23.
22. Getoff N., Gütlbauer F., Schenck G.O. Radiation-induced carboxylation of formic acid and methanol in aqueous solution. Int. J. Appl. Radiat. Isot. 17:1966;341-349. (in German).
23. Getoff N., Gütlbauer F., Schenck G.O., Wolgast R. ESR-investigations of radical reactions in γ-irradiated frozen aqueous solutions of formic acid and formiate. Tetrahedron Lett. 24:1966;2725-2731.
24. - into amines. Kerntechnik. 14:1972;75-81. (in German).
25. Gütlbauer F., Getoff N. Radiation-induced carboxylation of hydroxy-compounds. Int. J. Appl. Radiat. Isot. 16:1965;673-680. (in German).
26. Gütlbauer F., Getoff N. Kinetic studies on the radiation-induced carboxylation of methanol. Z. Phys. Chem. (N.F. ). 47:1965;299-305. (in German).
27. 2 in saturated alcohols. Atompraxis. 14:1968;500-504.
28. 2 in aromatic hydroxy-and oxocompounds as well as in carboxylic acids. Atompraxis. 15:1969;38-41.
29. 2 on p-type galium phosphate in liquid junction solar cells. Nature. 275:1979;115-116.
30. 2 Utilization. Bari, Italy, September 26-30.
31. 2 from the atmosphere. Colorado Springs, USA, March 13-16.
32. 2 using chalcogenide semiconductor microcrystals. J. Photochem. Photobiol. A. Chem. 86:1995;191-196.
33. 2 in aqueous solution. World Resour. Rev. 9:1997;421-433.
34. 2 problem. Climatic Change. 1:1977;59-68.
35. 2. Int. J. Hydrogen Energy. 19:1994;387-394.
36. Paur H.R., Baumann W., Mätzing H., Lindner W. Flue gas cleaning by multiple irradiation with electron beam. Radiat. Phys. Chem. 46:1995;1119-1122.
37. Raef Y., Swallow A.J. Action of γ-rays on aqueous solution of carbon monoxide. Trans. Faraday Soc. 59:1963;63-67.
38. 2-reduction strategies. GIT, Fachzeitschr. Lab., pp. 1209-1217.
39. 2 from fossil fuel power plants in the USA. Informal Report BNL 35666. Brookhaven National Laboratory, Long Island, NY, USA.
40. 60Co-γ-rays. Monatsh. Chem. 103:1972;1078-1090. (in German).