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Journal of Organometallic Chemistry

Volumn 341, Issue 1-3, 1988, Pages 187-198

Generation of silanimines by photolysis of hindered azidosilanes

(3) Zigler, Steven S a Johnson, Leighta M a West, Robert a

a UNIVERSITY OF WISCONSIN MADISON (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0037852480 PISSN: 0022328X EISSN: None Source Type: Journal
DOI: 10.1016/0022-328X(88)89074-0 Document Type: Article

Times cited : (31)

References (23)

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3
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- Observation of a silanimine in an inert matrix and in solution at low temperature.
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- Zigler¹ West² Michl³

4
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- Isolation of the Stable SilaketiminetBu2Si?N?SitBu3
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- Chem. Comm.
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6
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- Diisopropyl(2,4,6-tri-tert-butylphenylimino)silane—a very Stable, Free Silaimine
- Int. Ed. Engl.
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- Hesse¹ Klingebiel²

7
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- 3, an absorption at 257 nm was the only remaining band.

8
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- 3 in argon at 20 K. See ref. 2.

9
- 84917889052
- Compound 6 could result from an intermediate nitrene or an excited state of the azide.

10
- 84917889051
- The UV spectrum of 10a does not show a discernible maximum. The yellow color is due to an increase in optical density between 300 and 500 nm.

11
- 0041937851
- Photodecomposition of alkyl azides. Absence of freedom of choice and nonnitrene mechanism
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- Abramovich¹ Kybe²

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- (1987) Ph.D. Thesis
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14
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- The reason for the preferred ground-state geometry of 2 is not known, but in the excited state, where the p orbital on N(1) is electron deficient, this orientation should be the most stable [15].

15
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- An analogy can possibly be made to siliconcarbon bonds, which stabilize electron-deficient carbenium ions by hyperconjugation., See
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- BROMOMESITYLENE
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- 37Cl with appropriate intensity were observed.

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- Silylazide, V. Darstellung, Eigenschaften und Struktur einiger Silylazide
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.