Pore solution analysis of cement pastes and nanostructural investigations of hydrated C3S

Cement and Concrete Research

Volumn 33, Issue 7, 2003, Pages 1063-1070

  Tritthart, Josef ^a   Häußler, Frank ^b  

^a Tech Versuchs/Forsch Anst TUG   (Austria)

^b Inst Gesteinshüttenkunde M L   (Austria)

Author keywords

Binding of ethanolamine; C3S; Cement paste; Gel water; Microstructure

Indexed keywords

ADSORPTION; AMINES; HYDRATION; MICROSTRUCTURE; NEUTRON SCATTERING; PARTICLE SIZE ANALYSIS; SCATTERING;

SMALL-ANGLE NEUTRON SCATTERING (SANS);

CEMENTS;

EID: 0037799552     PISSN: 00088846     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0008-8846(03)00011-5     Document Type: Article

References (36)

1. Setzer M. Micro ice lens formation. Setzer M.J. Proceedings of the 3rd International Bolomey Workshop "Pore Solution in Hardened Cement Paste", University of Essen, June 1998. 2000;89-112 AEDIFICATIO Publishers, Freiburg.
2. Röhling S., Eifert H., Kaden R. Betonbau. Planung und Ausführung. Röhling S., Eifert H., Kaden R. 2000;Verlag Bauwesen, Berlin.
3. J. Stark, B. Wicht, Anorganische Bindemittel Zement-Kalk-Spezielle Bindemittel, Schriften der Bauhaus-Universität, Fakultät Bauingenieurwesen, FIB-F.A. Finger-Institut für Baustoffkunde Weimar, 1998.
4. Barneyback R.S. Jr., Diamond S. Expression and analysis of pore fluids from hardened cement pastes and mortars. Cement and Concrete Research. 11:1981;279-285.
5. Kostorz G. Small-angle scattering and its application to materials science. Kostorz G. Treatise on Materials Science and Technology. vol. 15:1979;227-259 Academic Press, London.
6. Guinier A., Fournet G. Small-Angle Scattering of X-rays. 1955;Wiley, New York.
7. Glatter O., Kratky O. Small-Angle X-ray Scattering. 1982;Academic Press, London.
8. Häußler F., Palzer S., Eckart A. Nondestructive microstructural investigations on hydrating cement paste and tricalcium silicate by small angle neutron scattering. Leipzig Annual Civil Engineering Report. 1999;47-64.
9. 3S und PZ mittels Neutronenkleinwinkelstreuung (Vortrag), Tagungsbericht- Band 1, 14. Internationale Baustofftagung IBAUSIL, Bauhaus-Universität Weimar, 20.-23.09.2000, pp. 1-0433-1-0442.
10. Allen A.J., Oberthur R.C., Pearson D., Schofield P., Wilding C.R. Development of the fine porosity and gel structure of hydrating cement systems. Philosophical Magazine, B. 56:1987;263-288.
11. Häußler F., Baumbach H., Kröning M. Non-destructive characterization of materials with neutron experiments at the pulsed reactor IBR-2. Nondestructive Characterization of Materials. 6:1994;435-444.
12. Röhling S., Nietner M. Anwendung eines strukturorientierten Modells zur Berechnung der Festigkeitsentwicklung von Zementbeton. Betontechnik. 9:1988;52-53.
13. Diamond S. Mercury porosimetry - an inappropriate method for the measurement of pore size distributions in cement-based materials. Cem. Concr. Res. 30(1):2000;1517-1525.
14. Brunauer E., Emmett P.H., Teller E. Adsorption of gases in mulitmolecular layers. Journal of the American Chemical Society. 60:1938;309-319.
15. F. Häußler, Neutronenkleinwinkelstreuung- Ein Beitrag zur mikrostrukturellen Aufklärung des hydratisierenden Zementsteins (invited talk), Baustoff-Kolloquium, F.A. Finger-Institut für Baustoffkunde (Prof. J. Stark) der Bauhaus-Universität Weimar, 06.04.2001.
16. Tritthart J. Chloride binding in cement: I. Investigations to determine the composition of pore water in hardened cement. Cem. Concr. Res. 19:1989;586-594.
17. 2O. Journal of Material Science Letters. 7:1988;861-863.
18. Thomas J.J., Jennings H.M., Allen A.J. The surface area of cement paste as measured by neutron scattering: evidence for two C-S-H morphologies. Cem. Concr. Res. 28(6):1998;897-905.
19. Häußler F., Palzer S., Eckart A. Nanostructural investigations on carbonation of hydrating tricalcium silicate by small angle neutron scattering. Leipzig Annual Civil Engineering Report. 2000;181-196.
20. Powers T.C., Brownyard T.L. Studies of the physical properties of hardened Portland cement paste. Proceedings of the American Concrete Institute. 43:1947;669.
21. Feldman R.F., Sereda P.J. A new model for hydrated Portland cement and its practical implications. Engineering Journal. 1970;53-59.
22. Beaudoin J.J., Brown P.W. The structure of hardened cement paste. Proceedings of the 9th Intern. Congr. Chem. Cem. vol. 1:1993;485-525 National Council for Cement and Building Materials (NCB).
23. W. Wieker, C. Hübert, D. Heidemann, Recent results of solid-state NMR investigations and their possibilities of use in cement chemistry, Xth Int. Congr. In Cement Chemistry Gothenburg 1997 (Sweden), Plen 2, 24 pp, ISBN 91-630-54-95-7.
24. Best G., Cross A., Peemoeller H., Pintar M.M., Blinc R. Distribution of pores sizes in white cement paste from proton NMR spin-lattice relaxation. Advances in Cement Research. 8:1996;163.
25. Heinemann A.et al. Fractal microstructures in hydrating cement paste. Journal of Material Science Letters. 18:1999;1413-1416.
26. FitzGerald S.A., Neumann D.A., Rush J.J., Bentz D.P., Livingston R.A. In situ quasi-elastic neutron scattering study of the hydration of tricalcium silicate. Chemistry of Materials. 10:1998;397-402.
27. Allen A.J., Livingston R.A. Relationship between differences in silica fume additives and fine-scale microstructural evolution in cement based materials. Advances in Cement-Based Materials. 8:1998;118-131.
28. Häußler F., Hempel M., Baumbach H., Tritthart J. Nanostructural investigations of hydrating cement pastes produced from cement with different fineness levels. Advances in Cement Research. 13:2001;65-73.
29. Weyerich B., Brunner-Popela J., Glatter O. Small-angle scattering of interacting particles: II. Generalized indirect Fourier transformation under consideration of the effective structure factor for polydisperse systems. Journal of Applied Crystallography. 32:1999;197-209.
30. Glatter O. A new method for the evaluation of small-angle scattering data. Journal of Applied Crystallography. 10:1977;415-421.
31. 2O exchange. Advances in Cement-Based Materials. 7(3):1998;119-122.
32. M. Langenfeld, J. Stark, Der Einfluss von Verzögerern auf die frühe Hydratation von Portlandzementklinkerphasen, dargestellt im ESEM-FEG, Thesis, Beiträge zur Baustofforschung, Wissenschaftliche Zeitschrift der Bauhaus-Universität, 44 (1998) 1/2, S. 83-90.
33. Kriechbaum M., Degovics G., Laggner P., Tritthart J. Investigations on cement pastes by small-angle X-ray scattering and BET: the relevance of fractal geometry. Advances in Cement Research. 6:1994;93-101.
34. Jennings H.M. A model for the microstructure of calcium silicate hydrate in cement paste. Cem. Concr. Res. 30(1):2000;101-116.
35. Pearson D., Allen A., Windsor C.G., Alford N.McN., Double D.D. An investigation on the nature of porosity in hardened cement pastes using small angle neutron scattering. Journal of Materials Science. 18:1983;430-438.
36. Peschel G. Disjoining forces in pore water. Setzer M.J. Proceedings of the 3rd International Bolomey Workshop Pore Solution in Hardened Cement Paste, University of Essen, June 1998. 2000;3-25 AEDIFICATIO Publishers, Freiburg.