Application of multifunctional initiation system in block copolymerization of ethylene oxide and methyl methacrylate

Science in China, Series B: Chemistry

Volumn 39, Issue 6, 1996, Pages 661-669

  Huang, Junlian ^a   Huang, Xiaoyu ^a  

^a FUDAN UNIVERSITY   (China)

Author keywords

Anion; Block copolymer; Charge transfer complex; Ethylene oxide; Methyl methacrylate

Indexed keywords

EID: 0037788238     PISSN: 10069291     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (15)

1. Siegel, R. A., Firestone, B. A., pH-dependent equilibrium properties of hydrophobic polyelectrolyte copolymer gels, Macromolecules, 1988, 21: 3254.
2. Urry, D. W., Harris, R. D., Prasad, K. V., Chemical potential driven contraction and relaxation by ionic strength modulation of an inverse temperature transition, J. Am. Chem. Soc., 1988, 110: 3303.
3. Wang, J., Varshney, S. K., Jerome, R. et al., Synthesis of AB(BA), ABA and BAB block copolymers of tert-butyl methacrylate (A) and ethylene oxide (B), J. Polym. Sci., Part A: Polym. Chem., 1992, 30: 2251.
4. Reuter, H., Berlinova, I. V., Horing, S. et al., The anionic block copolymerization of ethylene oxide with tert-butyl methacrylate diblock and multiblock copolymers, Eur. Polym. J., 1991, 27(7): 673.
5. Lee, J. Y., Painter, P. C., Coleman, M. M., Hydrogen bonding in polymer blends (3): Blends involving polymers containing methacrylic acids and ether groups, Macromolecules, 1988, 21: 346.
6. Fetters, L. J., Synthesis of block copolymers by homogenous anionic polymerization, J. Polym. Sci. Part C: Polym. Symp., 1969, 26: 1.
7. Suzuki, T., Murakai, Y., Takegami, Y., Synthesis and characterization of block copolymers of polyethylene oxide and polymethyl methacrylate, Polym. J., 1980, 12: 183.
8. Tomoi, M., Shibayama, Y., Kakiuchi, H., Polymerization of methyl and ethyl methacrylates initiated with alkai-metal alkoxide derivatives of poly(ethylene oxide), Polym. J., 1976, 8: 190.
9. Muller, A. H. E., Recent Advances in Anionic Polymerization, New York: Elsevier, 1987.
10. Suzuki, T., Murakami, Y., Tsuji, Y. et al., Synethesis of poly(ethylene oxide-b-methyl methacrylate), J. Polym. Sci. Polym. Lett. Ed., 1976, 14: 675.
11. Riddle, E. H., Monomeric Acrylic Esters, New York: Reinhold, 1954.
12. Huang, J. L., Huang, X. Y., Zhang, S., Block copolymerization of ethylene oxide and styrene by sequential initiation of an anion and a photoinduced charge transfer complex, Macromolecules, 1995, 28: 4421.
13. Ghosh, P. G., Ghosh, R., Photopolymerization of methyl methacrylate using benzophenone-dimethylaniline combination as photoinitiator, Eur. Polym. J., 1980, 17: 545.
14. Kubota, H., Ogiwara, Y., Photopolymerization of acrylonitrile sensitized with a combination of aromatic ketone and amine, J. Appl. Polym. Sci., 1982, 27: 2683.
15. Davidson, R. S., Lambeth, P. F., Santhanam, M., The photoreactions of aromatic carbonyl compounds with amines, Part 2: The reaction of triplet benzophenone and other ketones with primary and secondary aromatic amines, J. Chem. Soc. Perkin., 1972, 11: 2351.