Gas-phase hydrogenolysis mediated by activated carbon: Deuterated benzenes

Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands

Volumn 115, Issue 5, 1996, Pages 271-274

  Arends, Isabel W C E ^a,b   Louw, Robert ^a   Mulder, Peter ^a  

^a LEIDEN UNIVERSITY   (Netherlands)

^b DELFT UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0037755774     PISSN: 01650513     EISSN: None     Source Type: Journal    
DOI: 10.1002/recl.19961150503     Document Type: Article

References (14)

1. a I.W.C.E. Arends, W.R. Ophorst, R. Louw, P. Mulder, Carbon, in press;
2. b I.W.C.E. Arends, Thesis, Leiden University (1993) (In English).
3. European Patent no. 0175406; U.S. Patent no. 4,851,600.
4. a J. A. Manion, Thesis, Leiden University, The Netherlands (1989);
5. b J. A. Manion, J. H. M. Dijks, P. Mulder, R. Louw, Recl. Trav. Chim. Pays-Bas 107, 434 (1988);
6. c J. A. Manion, R. Louw, J. Phys. Chem. 94, 4127 (1990).
7. Analogous observations have been made with gas-phase hydro-dechlorination around 600°C, also at the threshold; depending on conditions such as the presence of other organic compounds dechlorination of chlorobenzenes could range from 0.1-2% (in around 4 s).
8. 3 with z = total dedeuteration percentage.
9. A.C. Ruiz, I.R. Ramos, Carbon 32, 23 (1994).
10. S. E. Stein, R. L. Brown, J. Am. Chem. Soc. 113, 787 (1991).
11. a D. F. McMillen, R. Malhotra, G. P. Hum, S-J. Chang, Energy Fuels 1, 193 (1987);
12. b R. Malhotra, D. F. McMillen, Energy Fuels 4, 184 (1990);
13. c R. Malhotra, D. F. McMillen, Energy Fuels 7, 227 (1993).
14. N is the abundance of (M + 1) + (M + 2), etc. (in case N = 1), relative to M.