Electrolytic conductivity and glass transition temperature as functions of salt content, solvent composition, or temperature for LiPF6 in propylene carbonate + diethyl carbonate

Journal of Chemical and Engineering Data

Volumn 48, Issue 3, 2003, Pages 519-528

  Ding, Michael S ^a  

^a U S ARMY RESEARCH LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CASTEEL AMIS EQUATION; DIETHYL CARBONATE; ELECTROLYTIC CONDUCTIVITY; MOLALITIES; PROPYLENE CARBONATE; SOLVENT COMPOSITION; VOGEL FULCHER TAMMAN EQUATION;

ACTIVATION ENERGY; CARBONATES; COMPOSITION; ELECTRIC CONDUCTIVITY; ELECTROLYSIS; GLASS TRANSITION; NUMERICAL METHODS; SALTS; SOLVENTS; TEMPERATURE; VISCOSITY;

LITHIUM COMPOUNDS;

EID: 0037684830     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je020219o     Document Type: Article

References (39)

1. Ehrlich, G. M. Lithium-ion batteries. In Handbook of Batteries, 3rd ed.; Linden, D., Reddy, T. B., Eds.; McGraw-Hill: New York, 2002.
2. Hossain, S. Rechargeable lithium batteries (ambient temperature). In Handbook of Batteries, 2nd ed.; Linden, D., Ed.; McGraw-Hill: New York, 1995.
3. Electrolyte Data Collection. Part 2a. Dielectric Properties of Nonaqueous Electrolyte Solutions; Barthel, J., Buchner, R., Munsterer, M., Eds.; Chemistry Data Series, Vol. XII; DECHEMA: Frankfurt, 1996.
4. Barthel, J.; Neueder, R.; Roch, H. Density, Relative Permittivity, and Viscosity of Propylene Carbonate + Dimethoxyethane Mixtures from 25 °C to 125 °C. J. Chem. Eng. Data 2000, 45, 1007-1011.
5. Ding, M. S. Liquid-Phase Boundaries, Dielectric Constant, and Viscosity of PC-DEC and PC-EC Binary Carbonates. J. Electrochem. Soc. 2003, 150, A455-A462.
6. 6 in EC-PC-EMC of 3:3:4 Weight Ratios. J. Electrochem. Soc. 2002, 149, A1489-1498.
7. Blomgren, G. E. Properties, Structure and Conductivity of Organic and Inorganic Electrolytes for Lithium Battery Systems. In Lithium Batteries; Gabano, J.-P., Ed.; Academic Press: London, 1983.
8. 4/Mixed Ether Electrolytes for Secondary Lithium Cells. J. Electrochem. Soc. 1984, 131, 2821-2827.
9. Matsuda, Y.; Morita, M.; Kosaka, K. Conductivity of the Mixed Organic Electrolyte Containing Propylene Carbonate and 1,2-Dimethoxyethane. J. Electrochem. Soc. 1983, 130, 101-104.
10. Matsuda, Y.; Sakate H. Mixed Electrolyte Solutions of Propylene Carbonate and Dimethoxyethane for High Energy Density Batteries. J. Electrochem. Soc. 1980, 127, 877-879.
11. Payne, R.; Theodorou, I. E. Dielectric Properties and Relaxation in Ethylene Carbonate and Propylene Carbonate. J. Phys. Chem. 1972, 76, 2892-2900.
12. 8; Barthel, J., Neueder, R., Meier, \R., Eds.; Chemistry Data Series, Vol. XII; DECHEMA: Frankfurt, 2000.
13. Cisak, A.; Werblan, L. High-Energy Nonaqueous Batteries; Ellis Horwood: New York, 1993; Chapter 7.
14. Casteel, J. F.; Angel, J. R.; McNeeley, H. B.; Sears, P. G. Conductivity-Viscosity Studies on Some Moderately Concentrated Nonaqueous Electrolyte Solutions from -50° to 125°. J. Electrochem. Soc. 1975, 122, 321-324.
15. Petrella, G.; Saaco, A. Viscosity and Conductance Studies in Ethylene Carbonate at 40 °C. J. Chem. Soc., Faraday Trans. 1 1978, 74, 2070-2076.
16. Ding, M. S.; Xu, K.; Jow, T. R. Liquid-Solid Phase Diagrams of Binary Carbonates for Lithium Batteries. J. Electrochem. Soc. 2000, 147, 1688-1694.
17. Ding, M. S.; Xu, K.; Zhang, S.-S.; Jow, T. R. Liquid/Solid Phase Diagrams of Binary Carbonates for Lithium Batteries, Part II. J. Electrochem. Soc. 2001, 148, A299-A304.
18. Ding, M. S. Thermodynamic Analysis of Phase Diagrams of Binary Carbonates Based on a Regular Solution Model. J. Electrochem. Soc. 2002, 149, A1063-1068.
19. Ding, M. S.; Xu, K.; Jow, T. R. Phase Diagram of EC-DMC Binary System and Enthalpic Determination of Its Eutectic Composition. J. Therm. Anal. Calorim. 2000, 62, 177-186.
20. Electrolyte Data Collection. Part 1d. Conductivities, Transference Numbers and Limiting Ionic Conductivities of Aprotic, Protophobic Solvents II. Carbonates; Barthel, J., Neueder, R., Eds.; Chemistry Data Series, Vol. XII; DECHEMA: Frankfurt, 2000.
21. 6 in Ethylene Carbonate-Ethyl Methyl Carbonate. J. Electrochem. Soc. 2001, 148, A1196-A1204.
22. Barthel, J.; Meier, R.; Conway, B. E. Density, Viscosity, and Specific Conductivity of Trifluoromethanesulfonic Acid Monohydrate from 309.15 K to 408.15 K. J. Chem. Eng. Data 1999, 44, 155-156.
23. Barthel, J.; Buestrich, R.; Carl E.; Gores, H. J. A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes. II. Conductivity of Lithium Organoborates in Dimethoxyethane and Propylene Carbonate. J. Electrochem. Soc. 1996, 143, 3565-3571.
24. Barthel, J.; Gores, H. J.; Schmeer, G. The Temperature Dependence of the Properties of Electrolyte Solutions. III. Conductance of Various Salts at High Concentrations in Propylene Carbonate at Temperatures from -45 °C to +25 °C. Ber. Bunsen-Ges. Phys. Chem. 1979, 83, 911-920.
25. Chen, H. P.; Fergus, J. W.; Jang, B. Z. The Effect of Ethylene Carbonate and Salt Concentration on the Conductivity of Propylene Carbonate Lithium Perchlorate Electrolytes. J. Electrochem. Soc. 2000, 147, 399-406.
26. Gu, G. Y.; Bouvier, S.; Wu, C.; Laura, R.; Rzeznik, M.; Abraham, K. M. 2-Methoxyethyl (methyl) carbonate-based electrolytes for lithium batteries. Electrochim. Acta 2000, 45, 3127-3139.
27. Gu, G. Y.; Laura, R.; Abraham, K. M. Conductivity-temperature Behavior of Organic Electrolytes. Electrochem. Solid-State Lett. 1999, 2, 486-489.
28. Ue, M.; Mori S. Mobility and Ionic Association of Lithium Salts in a Propylene Carbonate-Ethyl Methyl Carbonate Mixed Solvent. J. Electrochem. Soc. 1995, 142, 2577-2581.
29. Ue, M. Mobility and Ionic Association of Lithium and Quaternary Ammonium Salts in Propylene Carbonate and γ-Butyrolactone. J. Electrochem. Soc. 1994, 141, 3336-3342.
30. Matsuda, Y.; Nakashima, H.; Morita M.; Takasu, Y. Behavior of Some Ions in Mixed Organic Electrolytes of High Energy Density Batteries. J. Electrochem. Soc. 1981, 128, 2552-2556.
31. Casteel, J. F.; Amis, E. S. Specific Conductance of Concentrated Solutions of Magnesium Salts in Water-Ethanol System. J. Chem. Eng. Data 1972, 17, 55-59.
32. 6. J. Electrochem. Soc., in press.
33. Xu, W.; Angell, C. A. LiBoB and Its Derivatives: Weakly Coordinating Anions, and the Exceptional Conductivity of Their Nonaqueous Solutions. Electrochem. Solid-State Lett. 2001, 4, E1-E4.
34. Smedley, S. I. The Interpretation of Ionic Conductivity in Liquids; Plenum Press: New York, 1980; Chapter 3.
35. Feates, F. S.; Ives, D. J. G.; Pryor, J. H. Alternating Current Bridge for Measurement of Electrolytic Conductance. J. Electrochem. Soc. 1956, 103, 580-585.
36. Robinson, R. A.; Stokes, R. H. Electrolyte Solutions, 2nd ed.; Butterworth: London, 1959; p 93.
37. Johnson, D. Help Files for ZView 2.6b; Scribner Associates, Inc.: Southern Pines, NC, 2002.
38. Choquette, Y.; Brisard, G.; Parent, M.; Brouillette, D. Perron G.; Desnoyers, J. E.; Armand, M.; Gravel, D.; Slougui, N. Sulfamides and Glymes as Aprotic Solvents for Lithium Batteries. J. Electrochem. Soc. 1998, 145, 3500-3507.
39. McEwen, A. B.: Ngo, H. L.; LeCompte, K.; Goldman, J. L. Electrochemical Properties of Imidazolium Salt Electrolytes for Electrochemical Capacitor Applications. J. Electrochem. Soc. 1999, 146, 1687-1695.