Metal control of the reaction site in reactions of [{(η5-C5H3)2(SiMe2) 2}M2(CO)4(μ-H)]+ (M = Fe, Ru, Os) with nucleophilic amines

Organometallics

Volumn 21, Issue 15, 2002, Pages 3292-3296

  Ovchinnikov, Maxim V ^a   Wang, Xiaoping ^b   Schultz, Arthur J ^b   Guzei, Ilia A ^a,c   Angelici, Robert J ^a  

^a IOWA STATE UNIVERSITY   (United States)

^b ARGONNE NATIONAL LABORATORY   (United States)

^c UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; CHEMICAL BONDS; COMPLEXATION; MOLECULAR STRUCTURE; NEUTRON DIFFRACTION; REACTION KINETICS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

LIGANDS;

ORGANOMETALLICS;

EID: 0037668553     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020167w     Document Type: Article

References (30)

1. (a) Kristjánsdóttir, S. S.; Norton, J. R. In Transition Metal Hydrides: Recent Advances in Theory and Experiments; Dedieu, A., Ed.; VCH: New York, 1991; Chapter 10.
2. (b) Pearson, R. G. Chem. Rev. 1985,85,41.
3. (c) Martinho-Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629.
4. (d) Bullock, R. M. Comments Inorg. Chem. 1991,12, 1.
5. (a) Angelici, R. J. Acc. Chem. Res. 1995, 28, 52.
6. (b) Edidin, R. T.; Sullivan, J. M.; Norton, J. R. J. Am. Chem. Soc. 1987,109, 3945.
7. (c) Moore, E. J.; Sullivan, J. M.; Norton, J. R. J. Am. Chem. Soc. 1986, 108, 2257.
8. (d) Jordan, R. F.; Norton, J. R. J. Am. Chem. Soc. 1982, 104, 1255.
9. (a) Darensbourg, M. Y.; Ludvig, M. M. Inorg. Chem. 1986, 25, 2894.
10. (b) Hanckel, J. M.; Darensbourg, M. Y. J. Am. Chem. Soc. 1983, 105, 6979.
11. (c) Krisjánsdóttir, S. S.; Moody, A E.; Weberg, R. T.; Norton, J. R. Organometallics 1988, 7, 1983.
12. (a) Ovchinnikov, M. V.; Angelici, R. J. J. Am. Chem. Soc. 2000, 122, 6130.
13. (b) Ovchinnikov, M. V.; Guzei, I. A.; Angelici, R. J. Organometallics 2001, 20, 691.
14. Errington, R. J. Advanced Practical Inorganic and Metalorganic Chemistry, 1st ed.; Chapman & Hall: New York, 1997.
15. Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1998, 15, 5, 1518.
16. Perrin, D. D.; Armarego, W. L. F.; Perrin, D. R. Purification of Laboratory Chemicals, 2nd ed.; Pergamon: New York, 1980.
17. Siemeling, U.; Jutzi, P.; Neumann, B.; Stammler, H. G.; Hursthouse, M. B. Organometallics 1992, 11, 1328.
18. Hiermeier, J.; Koehler, F. H.; Mueller, G. Organometallics 1991, 10, 1787.
19. All software and sources of the scattering factors are contained in the SHELXTL (version 5.1) program library (G. Sheldrick, Bruker Analytical X-Ray Systems, Madison, WI).
20. Schultz, A. J. Trans. Am. Cryst. Assoc. 1993, 29, 29.
21. Sheldrick, G. M. SHELXL-97, A program for crystal structure refinement, Release 97-2; Institüt für Anorganische Chemie der Universität: Göttingen, Germany, 1998.
22. -). Copies of the data can be obtained, free of charge, on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: +44 1223 336033 or deposit@ccdc.cam.ac.uk
23. Ovchinnikov, M. V.; Klein, D. P.; Choi, M.-G.; Guzei, I. A.; Angelici, R. J. Organometallics 2002, 21, 617.
24. 6(μ-H)]+. See: McKinley, S. G.; Angelici, R. J.; Choi, M.-G. Organometallics 2002, 21, 1235.
25. -) was used in order to simplify the refinement of the neutron diffraction data.
26. For a recent review on neutron diffraction studies of transition metal hydrides, see: Bau, R.; Drabnis, M. H. Inorg. Chim. Acta 1997, 259, 27.
27. Perrin, D. D. Dissociation Constants of Organic Bases in Aqueous Solution; Butterworth: London, 1972.
28. (a) Angelici, R. J. Acc. Chem. Res. 1972,5, 335.
29. (b) Jolly, W. L.; Avanzino, S. C.; Rietz, R. R. Inorg. Chem. 1977, 16, 964.
30. 5 decrease with the metal in the order Os > Ru > Fe, even though the v(CO) values for the Ru complex are higher than those of the Os and Fe complexes. Trautman, R. J.; Gross, D. C.; Ford, P. C. J. Am. Chem. Soc. 1985, 107, 2355.