The interaction of hydrogen with alumina-supported copper catalysts: A temperature-programmed adsorption/temperature-programmed desorption/isotopic exchange reaction study

Journal of Catalysis

Volumn 215, Issue 2, 2003, Pages 188-198

  Wilmer, H ^a   Genger, T ^a,b   Hinrichsen, O ^a  

^a RUHR UNIVERSITY BOCHUM   (Germany)

^b BASF SE   (Germany)

Author keywords

Adsorption; Cu catalysts; Desorption; H2 TPA; H2 TPD; Hydrogen; IER; Methanol synthesis; Microkinetics

Indexed keywords

ALUMINUM OXIDE; COPPER; HYDROGEN; ZINC OXIDE;

ADSORPTION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION KINETICS; DESORPTION; MOLECULAR INTERACTION; SURFACE PROPERTY; TEMPERATURE; TRANSPORT KINETICS;

EID: 0037632759     PISSN: 00219517     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0021-9517(03)00003-4     Document Type: Article

References (54)

1. Christmann K. Surf. Sci. Rep. 9:1988;1.
2. Christmann K. Prog. Surf. Sci. 48:1995;15.
3. Balooch M., Cardillo M.J., Miller D.R., Stickney R.E. Surf. Sci. 46:1974;358.
4. Pritchard J., Catterick T., Gupta R.K. Surf. Sci. 53:1975;1.
5. Wachs I.E., Madix R.J. J. Catal. 53:1978;208.
6. Comsa G., David R. Surf. Sci. 117:1982;77.
7. Rieder K.H., Stocker W. Phys. Rev. Lett. 57:1986;2548.
8. Hayden B.E., Lamont C.L.A. Phys. Rev. Lett. 63:1989;1823.
9. Hayden B.E., Lamont C.L.A. Chem. Phys. Lett. 160:1989;331.
10. Anger G., Winkler A., Rendulic K.D. Surf. Sci. 220:1989;1.
11. Hayden B.E., Lackey D., Schott J. Surf. Sci. 239:1990;119.
12. Campbell J.M., Campbell C.T. Surf. Sci. 259:1991;1.
13. Campbell J.M., Domagala M.E., Campbell C.T. J. Vac. Sci. Technol. A. 9:1991;1693.
14. Rasmussen P.B., Holmblad P.M., Christoffersen H., Taylor P.A., Chorkendorff I. Surf. Sci. 287/288:1993;79.
15. Darling G.R., Holloway S. J. Chem. Phys. 101:1994;3268.
16. Chorkendorff I., Rasmussen P.B. Surf. Sci. 248:1991;35.
17. Besenbacher F., Sprunger P.T., Ruan L., Oelsen L., Stensgaard I., Lægsgaard E. Top. Catal. 1:1994;325.
18. Hansen J.B. Ertl G., Knözinger H., Weitkamp J. Handbook of Heterogeneous Catalysis, Vol. 4. 1997;1856 Wiley-VCH, Weinheim.
19. Kochloefl K. Ertl G., Knözinger H., Weitkamp J. Handbook of Heterogeneous Catalysis, Vol. 4. 1997;1831 Wiley-VCH, Weinheim.
20. Muhler M., Nielsen L.P., Törnqvist E., Clausen B.S., Topsøe H. Catal. Lett. 14:1992;241.
21. Genger T., Hinrichsen O., Muhler M. Catal. Lett. 59:1999;137.
22. Tabatabaei J., Sakakini B.H., Watson M.J., Waugh K.C. Catal. Lett. 59:1999;143.
23. Tabatabaei J., Sakakini B.H., Watson M.J., Waugh K.C. Catal. Lett. 59:1999;151.
24. Spencer M.S. Surf. Sci. 192/193:1987;323.
25. Spencer M.S. Surf. Sci. 192/193:1987;329.
26. Spencer M.S. Surf. Sci. 192/193:1987;336.
27. Frost J.C. Nature. 334:1988;577.
28. Spencer M.S. Catal. Lett. 50:1998;37.
29. Spencer M.S. Top. Catal. 8:1999;259.
30. Miller J.B., Siddiqui H.R., Gates S.M., Russell J.N. Jr., Yates J.T. Jr., Tully J.C., Cardillo M.J. J. Chem. Phys. 87:1987;6725.
31. de Jong A.M., Niemantsverdriet J.W. Surf. Sci. 233:1990;355.
32. Hinrichsen O., Rosowski F., Muhler M., Ertl G. Stud. Surf. Sci. Catal. 109:1997;389.
33. B. Bems, M. Schur, A. Dassenoy, H. Junkes, D. Herein, R. Schlögl, submitted to Chem.-Eur. J.
34. Hinrichsen O., Genger T., Muhler M. Stud. Surf. Sci. Catal. 130:2000;3825.
35. Wilmer H., Hinrichsen O. Catal. Lett. 82:2002;117.
36. Chinchen G.C., Hay C.M., Vanderwell H.D., Waugh K.C. J. Catal. 103:1987;79.
37. Sandoval M.J., Bell A.T. J. Catal. 144:1993;227.
38. Roberts D.L., Griffin G.L. Appl. Surf. Sci. 19:1984;298.
39. Roberts D.L., Griffin G.L. J. Catal. 110:1988;117.
40. Golze M., Grunze M., Hirschwald W. Vacuum. 31:1981;697.
41. Wachs I.E., Madix R.J. Surf. Sci. 84:1979;375.
42. Chinchen G.C., Waugh K.C., Whan D.A. Appl. Catal. 25:1986;101.
43. Bielawa H., Kurtz M., Genger T., Hinrichsen O. Ind. Eng. Chem. Res. 40:2001;2793.
44. Günter M.M., Ressler T., Bems B., Büscher C., Genger T., Hinrichsen O., Muhler M., Schlögl R. Catal. Lett. 71:2001;37.
45. Lee J.S., Lee K.H., Lee S.Y., Kim Y.G. J. Catal. 144:1993;414.
46. Clausen B.S., Schiøtz J., Grabaek L., Ovesen C.V., Jacobson K.W., Nørskov J.K., Topsøe H. Top. Catal. 1:1994;367.
47. Ovesen C.V., Clausen B.S., Schiøtz J., Stoltze P., Topsøe H., Nørskov J.K. J. Catal. 168:1997;133.
48. Topsøe H., Ovesen C.V., Clausen B.S., Topsøe N.-Y., Højlund Nielsen P.E., Törnqvist E., Nørskov J.K. Stud. Surf. Sci. Catal. 109:1997;121.
49. Meitzner G., Iglesia E. Catal. Today. 53:1999;433.
50. Grunwaldt J.-D., Molenbroek A.M., Topsøe N.-Y., Topsøe H., Clausen B.S. J. Catal. 194:2000;452.
51. Hansen P.L., Wagner J.B., Helveg S., Rostrup-Nielsen J.R., Clausen B.S., Topsøe H. Science. 295:2002;2053.
52. Clausen B.S., Steffensen G., Fabius B., Villadsen J., Feidenhans'l R., Topsøe H. J. Catal. 132:1991;524.
53. Clausen B.S., Grabaek L., Steffensen G., Hansen P.L., Topsøe H. Catal. Lett. 20:1993;23.
54. Hinrichsen O., Genger T., Muhler T. Chem. Eng. Technol. 11:2000;956.