Catalytic cross-dehydrocoupling polymerization of phenylsilane with water. A new approach to poly(phenylsilsesquioxane)

Polymer Journal

Volumn 35, Issue 2, 2003, Pages 197-202

  Seino, Makoto ^a   Imae, Ichiro ^a   Kawakami, Yusuke ^a  

^a JAPAN ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY   (Japan)

Author keywords

Dehydrocoupling; Pd Catalyst; Phenylsilane; Poly(phenylsilsesquioxane); Thermal property; Water

Indexed keywords

CATALYST ACTIVITY; DEHYDRATION; HYDROLYSIS; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC SOLVENTS; POLYMERIZATION; SIZE EXCLUSION CHROMATOGRAPHY; TRANSITION METALS; WATER;

CROSS DEHYDROCOUPLING POLYMERIZATION; MOLECULAR WEIGHT POLYMER; PHENYLSILANE; POLYPHENYLSILSESQUIOXANE;

SILANES;

EID: 0037628912     PISSN: 00323896     EISSN: None     Source Type: Journal    
DOI: 10.1295/polymj.35.197     Document Type: Article

References (18)

1. R. G. Jones, W. Ando, and J. Chojnowski Ed., "Silicon-Containing Polymer", 2000, p 157.
2. a) R. H. Baney, M. Itoh, A. Sakakibara, and T. Suzuki, Chem. Rev., 95, 1409 (1995).
3. b) D. A. Loy and K. J. Shea, Chem. Rev., 95, 1431 (1995).
4. c) A. Provatas and J. G. Matisons, Trends in Polym. Sci., 5, 327 (1997).
5. a) M. M. Sprung and F. O. Guenther, J. Polym. Sci., 28, 17 (1958).
6. b) J. F. Brown, L. H. Vogt, A. Katchman, J. W. Eustance, K. M. Kiser, and K. W. Krantz, J. Am. Chem. Soc., 82, 6194 (1960).
7. c) K. A. Andrianov, G. A. Kurakov, F. F. Sushentsova, V. A. Myagkov, and V. A. Avilov, Vysokomol. Soyed., 7, 1477 (1965).
8. d) S. A. Pavlova, V. I. Pakhomov, and I. I. Tverdokhlebova., Vysokomol. Soyed., 6, 1275 (1964).
9. e) E. C. Lee and Y. Kimura, Polym. J., 29, 678 (1997).
10. f) E. C. Lee and Y. Kimura, Polym. J., 30, 234 (1998).
11. a) Y. Li and Y. Kawakami, Macromolecules., 32, 3540 (1999).
12. b) Y. Li and Y. Kawakami, Macromolecules., 32, 6871 (1999).
13. c) Y. Li and Y. Kawakami, Macromolecules., 32, 8768 (1999).
14. a) G. Engelhardt, M. Maegi, and E. Lippmaa, J. Organomet. Chem., 54, 115 (1973).
15. b) L. Guizhi, S. Lianghe, and Y. Meiling, Chin. J. Polym. Sci., 14, 41 (1996).
16. c) K. J. Shea, D. A. Loy, and O. Webster, J. Am. Chem. Soc., 114, 6700 (1992).
17. +).
18. 3 in 0.05 mL THF.