Thermodynamic solution model for trona brines

AIChE Journal

Volumn 49, Issue 7, 2003, Pages 1883-1894

  Haynes Jr , Henry W ^a  

^a UNIVERSITY OF WYOMING   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

PHASE EQUILIBRIA; REGRESSION ANALYSIS; SALTS; SOLUBILITY; SPECIFIC HEAT; THERMODYNAMICS;

THERMOCHEMISTRY;

BRINES;

SODIUM CARBONATE; SODIUM CHLORIDE;

BRINE; THERMODYNAMICS;

AQUEOUS SOLUTION; ARTICLE; CORRELATION COEFFICIENT; HIGH TEMPERATURE PROCEDURES; MODEL; TEMPERATURE DEPENDENCE; THERMODYNAMICS;

TRONA;

EID: 0037623753     PISSN: 00011541     EISSN: None     Source Type: Journal    
DOI: 10.1002/aic.690490724     Document Type: Article

References (37)

1. 2O(s)," J. Chem. Thermodyn., 10, 1113 (1978).
2. Butler, J. N., and R. Huston, "Activity Coefficients and Ion Pairs in the Systems Sodium Chloride-Sodium Bicarbonate-Water and Sodium Chloride-Sodium Carbonate-Water," J. Phys. Chem., 74, 2976 (1970).
3. Chang, Y. A., and N. Ahmad, Thermodynamic Data on Metal Carbonates and Related Oxides, Metall. Soc. AIME, Amer. Inst. Min., Metall. and Petrol. Eng., New York (1982).
4. 2O from 225 to 325°C," J. Solution Chem., 21, 825 (1992).
5. Cox, J. D., D. D. Wagman, and V. A. Medvedev, CODATA Key Values for Thermodynamics, Hemisphere, New York (1989).
6. 2O, Considered as Two Four-Component Systems," Roy. Soc. London Philos. Trans., Ser. A, A223, 35 (1922).
7. Garrels, R. M., M. E. Thompson, and R. Siever, "Control of Carbonate Solubility by Carbonate Complexes," Amer. J. Sci., 259, 24 (1961).
8. Garrett, D. E., Natural Soda Ash. Occurrences, Processing, and Use, Van Nostrand Reinhold, New York (1992).
9. 2O System to High Concentration from 0 to 250°C," Geochim. Cosmochim. Acta, 53, 2503 (1989).
10. 2O," J. Chem. Thermodyn., 15, 881 (1983).
11. 2O System to High Ionic Strengths at 25°C," Geochim. Cosmochim. Acta, 48, 723 (1984).
12. Haynes, H. W., Jr., and P. De Filippis, "An Equation of State for Trona Solutions," Proc. Int. Mineral Processing Congr., Rome, Italy (2000).
13. Helgeson, H. C., J. M. Delany, H. W. Nesbitt, and D. K. Bird, "Summary and Critique of the Thermodynamic Properties of Rock-Forming Minerals," Amer. J. Sci., 278A, 1 (1978).
14. Helgeson, H. C., D. H. Kirkham, and G. C. Flowers, "Theoretical Prediction of the Thermodynamic Behavior of Aqueous Electrolytes at High Pressures and Temperatures: IV. Calculation of Activity Coefficients, Osmotic Coefficients, and Apparent Molal and Standard and Relative Partial Molal Properties to 600°C and 5 kb," Amer. J. Sci., 281, 1249 (1981).
15. Hill, A. E., and L. R. Bacon, "Ternary Systems. VI. Sodium Carbonate, Sodium Bicarbonate and Water," J. Amer. Chem. Soc., 49, 2487 (1927).
16. Holmes, H. F., and R. E. Mesmer, "Thermodynamics of Aqueous Solutions of the Alkali Metal Sulfates," J. Solution Chem., 15, 495 (1986).
17. Keenan, J. H., and F. G. Keyes, Thermodynamic Properties of Steam Including Data for the Liquid and Solid Phases, Wiley, New York (1936).
18. Linke, W. F., Solubilities. Inorganic and Metal-Organic Compounds, Vol. II, 4th ed., Amer. Chem. Soc., Washington, DC (1965).
19. 2O System, to High Temperature and Concentration," Geochim. Cosmochim. Acta, 52, 821 (1988).
20. Monnin, C., and J. Schott, "Determination of the Solubility Products of Sodium Carbonate Minerals and an Application to Trona Deposition in Lake Magadi (Kenya)," Geochim. Cosmochim. Acta, 48, 571 (1984).
21. -," J. Inorg. Nucl. Chem., 33, 1287 (1971).
22. Oelkers, E. H., H. C. Helgeson, E. L. Shock, D. A. Sverjensky, J. W. Johnson, and V. A. Pokrovskii, "Summary of the Apparent Standard Partial Molal Gibbs Free Energies of Formation of Aqueous Species, Minerals, and Gases at Pressures 1 to 5000 Bars and Temperatures 25 to 1000°C," J. Phys. Chem. Ref. Data, 24, 1401 (1995).
23. 2O," Geochim. Cosmochim. Acta, 51, 2429 (1987).
24. 2O) to 300°C," Geochim. Cosmochim. Acta, 52, 2393 (1988).
25. Peiper, J. C., and K. S. Pitzer, "Thermodynamics of Aqueous Carbonate Solutions Including Mixtures of Sodium Carbonate, Bicarbonate, and Chloride," J. Chem. Thermodyn., 14, 613 (1982).
26. Pitzer, K. S., J. C. Peiper, and R. H. Busey, "Thermodynamic Properties of Aqueous Sodium Chloride Solutions," J. Phys. Chem. Ref. Data, 13, 1 (1984).
27. Pitzer, K. S., Thermodynamics, 3rd ed., McGraw-Hill, New York (1995).
28. Riggs, J. B., An Introduction to Numerical Methods for Chemical Engineers, Texas Tech Univ. Press, Lubbock, TX (1988).
29. Rogers, P. S. Z., and K. S. Pitzer, "Volumetric Properties of Aqueous Sodium Chloride Solutions," J. Phys. Chem. Ref. Data, 11, 15 (1982).
30. Shock, E. L. and H. C. Helgeson, "Calculation of the Thermodynamic and Transport Properties of Aqueous Species at High Pressures and Temperatures: Correlation Algorithms for Ionic Species and Equation of State Predictions to 5 kb and 1000°C," Geochim. Cosmochim. Acta, 52, 2009 (1988).
31. Shock, E. L., H. C. Helgeson, and D. A. Sverjensky, "Calculation of the Thermodynamic and Transport Properties of Aqueous Species at High Pressures and Temperatures: Standard Partial Molal Properties of Inorganic Neutral Species," Geochim. Cosmochim. Acta, 53, 2157 (1989).
32. Tanger, J. C., IV, and H. C. Helgeson, "Calculation of the Thermodynamic and Transport Properties of Aqueous Species at High Pressures and Temperatures: Revised Equations of State for the Standard Partial Molal Properties of Ions and Electrolytes," Amer. J. Sci., 288, 19 (1988).
33. 2O," Stud. Soc. Sci. Torun., Sec. B, III(2), 33 (1961).
34. 3)," J. Chem. Thermodyn., 14, 219 (1982).
35. 2O from 100 to 200°," J. Amer. Chem. Soc., 56, 43 (1934).
36. Waterfield, C. G., R. G. Linford, B. B. Goalby, T. R. Bates, C. A. Elyard, and L. A. K. Staveley, "Thermodynamic Investigation of Disorder in the Hydrates of Sodium Carbonate," Trans. Faraday Soc., 64, 868 (1968).
37. 2O und das Existenzgebiet der Trona," Monatsh. Chem. Verw. Teile Wiss., 49, 283 (1928).