On the compatibility of the IPP/PA6/EPDM blends with and without functionalized IPP I. Thermo-oxidative behaviour

Polymer Degradation and Stability

Volumn 80, Issue 3, 2003, Pages 551-566

  Darie, Raluca Nicoleta ^a   Brebu, Mihai ^a   Vasile, Cornelia ^a   Kozlowski, Marek ^b  

^a PETRU PONI INSTITUTE OF MACROMOLECULAR CHEMISTRY   (Romania)

^b WROCLAW UNIVERSITY OF TECHNOLOGY   (Poland)

Author keywords

Blends; Compatibilization; Ethylene propylene diene terpolymer; Functionalized; Isotactic polypropylene; Polyamide 6; Thermal and thermo oxidative behaviour

Indexed keywords

DECOMPOSITION; DIFFERENTIAL SCANNING CALORIMETRY; ORGANIC ACIDS; POLYAMIDES; POLYPROPYLENES; THERMOGRAVIMETRIC ANALYSIS;

COMPATIBILIZATION;

TERPOLYMERS;

EID: 0037622185     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0141-3910(03)00052-1     Document Type: Article

References (28)

1. Tomova D., Kressler J., Radush H.J. Phase behaviour in ternary polyamide 6/polyamide 66/elastomer blends. Polymer. 41:2000;7773-7783.
2. Piglowski J, Gancarz I, Gancarz R. Properties of compatibilized polyamide6/nitrile rubber and polyamide6/polypropylene blends. In: Proceedings of POLYMER 2000, 25-27 September 2000, Halle, Germany. p. 133-6.
3. Fortelny I., Krulis Z., Michalkova D. Use of additive compatibilization for recycling of municipal plastics waste. Polymery (Poland). 7/8(tom XLVII):2002;517-522.
4. Seo S.S., Lee K.Y., Kim S.H., Kim D.C., Lee S.G. A study on the PP/PS blends with nylon 6 reactive compatibilizers. Polymer (Korea). 26(1):2002;71-79.
5. Franzheim O., Rishe T., Stephan M., Macknight W.J. Blending of immiscible polymers in a mixing zone of a twin screw extruder-effects of compatibilization. Polym. Eng. Sci. 40:2000;1143-1156.
6. Manning StC., Moore R.B. Reactive compatibilization of polypropylene and polyamide-6,6 with carboxylated and maleated polypropylene. Polym. Eng. Sci. 39(10):1999;1921-1929.
7. Okada O., Keskkula H., Paul D.R. Nylon 6 as a modifier for maleated ethylene-propylene elastomers. Polymer. 40(10):1999;2699-2709.
8. Wong S.C., Mai Y.W. Effect of rubber functionality on a microstructure and fracture toughness of impact-modified nylon 6,6/polypropylene blends. 1. Structure-property relationships Polymer. 40(6):1999;1553-1566.
9. Vasile C. Reactive blending. In: Vasile C, Kulshereshtha AK, editors. Handbook of polymer blends and composites, vol. III: Polymer blends. Rapra Technology Press [in press] [Chapter 7].
10. Oshinski J., Keskkula H., Paul D.R. Rubber toughening of polyamides with functionalized block copolymers. 1. Nylon-6 Polymer. 33(2):1992;268-283.
11. Tomova D, Schmid E, Radusch H-J. Morphology and mechanical properties of ternary polyamide 6/polyamide 6,6/elastomer blends. Effect of polyamide 6 end-group configuration. In: Proceedings of 38th Macromol IUPAC Symposium, vol. 3, Warsaw (Poland), 9-14 July 2000. p. 1199.
12. Neamţu L, Eşanu M, Dascǎlu M, Vasile C. Use of functionalized polyolefins in polymer blends. III. EPDM/PA6 blends. In: Proceedings of BRAMAT'99, vol. IV, Materials and environmental protection, 3-5 February 1999, Braşov, Romania. p. 251-3.
13. Vasile C., Downey M., Wong B., Macoveanu M.M., Pascu M.C., Choi J-H.et al. Polyolefins/lignosulfonates blends. II. Isotactic polypropylene/epoxi-modified lignin. Cell Chem. Technol. 32(1-2):1998;61-88.
14. Darie RN, Brebu M, Vasile C, Kozlowski M, Kozlowska A. Some aspects of reprocessing of polypropylene/polyamide 6 blends. In: Proceedings of the Symposium Recycling 2002, Velike Losiny (Czech Republik), 16-20 September 2002.
15. Neamţu L, Dascǎlu M, Darie H, Vasile C. Use of functionalized polyolefins in polymer blends. I. Synthesis and characterization. Proceedings of BRAMAT'99, vol. IV, Materials and environmental protection, 3-5 February 1999, Braşov, Romania. p. 240-5.
16. Dascǎlu M., Darie H., Tabârnǎ C.M., Darie R., Vasile C. Use of the functionalized polyolefins in polymer blends. IV. New synthesis, characterisation and applications. Bul. Inst. Politech. Iasi. XLV(IL):1999;281-287.
17. Gaylord N. Reactive extrusion in the preparation of carboxyl-containing polymers and their utilization as compatibilizing agents. Xanthos M. Reactive extrusion: principles and practice. 1992;59 Hanser Publ, New York. [Chapter 3].
18. Gaylord N.G., Mishra M.K. Nondegradative reaction of maleic anhydride and molten polypropylene in the presence of peroxides. J. Polym. Sci., Polym. Lett. Ed. 21(1):1983;23-30.
19. Vasile C., Deanin R.D., Mihaes M., Roy C., Chaala A., Ma W. Chemicals and energy from medical polymer wastes. II. Maleated pyrolysis products in IPP/LLDPE processing. Int J. Polym. Mater. 37:1997;173-199.
20. Mark H.F., Gaylord N.G. Encyclopedia of polymer science and technology, plastics, resins, rubbers, fibers. 1969;Interscience Publishers (a division of John Wiley & Sons Inc.). p. 608 (vol. 11), 544-7 and 568 (vol. 10).
21. Brandrup J, Immergut EH, Grulke EA, editors. Polymer handbook, vol. 23, 4th ed. 1999. p. 126, 127.
22. Gaylord N.G. Compatibilizing agents. structure and function J. Macromol. Sci-Chem. A26(8):1989;1211-1229.
23. Petrovan S., Ibanescu C., Murariu M., Bodron V. Composites based on PA employed for injection and extrusion processing. Materiale Plastice. 37(1):1998;62.
24. McNeill IC. Thermal decomposition behaviour of mixtures of two plastics, ISFR'99. In: Proceedings of the 1st International Symposium on Feedstock Recycling of Plastics, Sendai, Japan, 31 October-3 November 1999. p. 25-32.
25. Miranda R., Yang J., Roy C., Vasile C. Vacuum pyrolysis of PVC. Part I. Kinetic studies. Polym. Degrad. Stab. 64:1999;127-144.
26. Vasile C., Brebu M., Darie H., Deanin R.D., Dorneanu V., Pantea D.M.et al. Chemical and energy from medical polymer wastes I. pyrolysis of disposable syringes. Int J. Polym. Mater. 38:1997;219-247.
27. Vasile C, Costea E, Verbuta A. Polyolefins decomposition in various atmospheres. Memoriile Sectiilor Stiintifice ale Academiei Romane, Seria IV, tom XVIII, 1995, Bucuresti, 1997. p. 125-40.
28. Vieira I., Severgnini V.L.S., Mazera D.J., Soldi M.S., Pinheiro E.A., Pires A.T.N.et al. Effects of maleated ethylene propylene diene rubber (EPDM) on the thermal stability of pure polyamides, polyamides/EPDM and polyamides/poly(ethylene terephthalate) blends. kinetic parameters and reaction mechanism Polym. Degrad. Stab. 74:2001;151-157.