Nonracemic 2-diazo-1-oxiranyl-ethanone, a versatile chiral epoxide educt in diazocarbonyl reactions

Organic Letters

Volumn 2, Issue 16, 2000, Pages 2393-2395

  Groarke, Michelle ^a   McKervey, M Anthony ^a   Miel, Hugues ^a   Nieuwenhuyzen, Mark ^a  

^a QUEEN'S UNIVERSITY BELFAST   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0037570113     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol000034b     Document Type: Article

References (16)

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3. Doyle, M. P.; McKervey, M. A.; Ye, T. Modern Catalytic Methods for Organic Synthesis with Diazo Compounds: Wiley-Interscience: New York, 1998.
4. Supplied by PPG-SIPSY, France.
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8. For other recent examples of condensations of chiral glyoxals with amines, see: Darkins, P.; Groarke, M.; McKervey, M. A.; Moncrieff, H.; McCarthy, N.; Nieuwenhuyzen, M. J. Chem. Soc., Perkin Trans. 1 2000, 381.
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10. Crystallographic data for the compound 8 in this paper have been deposited in the Cambridge Crystallographic Data Centre (deposition number CCDC 143897). Copies of the available material can be obtained free of charge on application to the CCDC, 12, Union Rd., Cambridge. CB2 1EZ. U.K. Fax: +44 -(0) 1223-336033. Email: deposit@ccdc.cam.ac.uk.
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16. 13C NMR, accurate MS, and/ or elemental analysis.