Organometallic complexes containing a Co-N-C three-membered ring: Factors affecting the dynamic of the ring closure

Organometallics

Volumn 22, Issue 12, 2003, Pages 2486-2491

  Dreos, Renata ^a   Felluga, Alessandro ^a   Nardin, Giorgio ^a   Randaccio, Lucio ^a   Tauzher, Giovanni ^a  

^a UNIVERSITY OF TRIESTE   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

METALLACYCLE; NUCLEOPHILIC INTERMOLECULAR ATTACK; THREE MEMBERED RING; TRIDENTATE PYRIDYLMETHYL AMINO BUTANONE OXIME;

CARBON; CHELATION; CHEMICAL BONDS; COBALT; COMPLEXATION; ENTROPY; MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; NITROGEN; REACTION KINETICS; X RAY ANALYSIS;

ORGANOMETALLICS;

EID: 0037561447     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030024p     Document Type: Article

References (39)

1. Polson, S. M.; Hansen, L.; Marzilli, L. G. J. Am. Chem. Soc. 1966, 118, 4804.
2. Marzilli, L. G.; Polson, S. M.; Hansen, L.: Moore, S. J.; Marzilli, P. A. Inorg. Chem. 1997, 36, 3854.
3. Dreos, R.; Felluga, A.; Nardin, G.; Randaccio, L.; Siega, P.; Tauzher, G. Inorg. Chem. 2001, 40, 5541.
4. Dreos, R.; Felluga, A.; Nardin, G.; Randaccio, L.; Sandri, M.; Tauzher, G. Inorg. Chem. 2002, 41, 4548.
5. Dreos, R.; Felluga, A.; Nardin, G.; Randaccio, L.; Siega, P.; Tauzher, G. Eur. J. Inorg. Chem. 2001, 267.
6. Marzilli, L. G.; Bayo, F.; Summers, M. F. Thomas, L. B.; Zangrando, E.; Bresciani-Pahor, N.; Mari, M.; Randaccio, L. J. Am. Chem. Soc. 1987, 109, 6045.
7. Dreos Garlatti, R.; Tauzher, G.; Costa, G. Inorg. Chim. Acta 1983, 71, 9.
8. Gupta, B. D.; Roy, S. Inorg. Chim. Acta 1988, 146, 209.
9. (a) Modena, G. Acc. Chem. Res. 1771, 4, 73 and references therein.
10. (b) Hoffman, H. M. R. J. Chem. Soc. 1965, 6753.
11. (c) Bird, R.; Stirling, C. G. M. J. Chem. Soc., Perkin Trans. 2 1973, 1221.
12. (d) Bird, R.; Knipe, A. C.; Stirling, C. G. M. J. Chem. Soc., Perkin Trans. 2 1973, 1215.
13. (a) Menger, F. M. Acc. Chem. Res. 1985, 18, 128.
14. (b) Menger, F. M. In Nucleophilicity; Adv. Chem. Ser. 215; Harris, G. M., McManus, S. P., Eds.; American Chemical Society: Washington, DC, 1987; Chapter 14.
15. (a) Sisido, M. Macromolecules 1971, 4, 737.
16. (b) Storm, D. R.; Koshland, D. E., Jr. J. Am. Chem. Soc. 1972, 94, 5805.
17. (a) Dafforn, A.; Koshland, D. E., Jr. Biochem. Biophys. Res. Commun. 1973, 52, 779.
18. (b) Menger, F. M. Tetrahedron 1983, 39, 1013.
19. Perlmutter-Hayman, B. Prog. Inorg. Chem. 1973, 20, 229.
20. (a) Page, M. I.; Jencks, W. P. Proc. Natl. Acad. Sci. U.S.A. 1971, 68, 1678.
21. Jencks, W. P.; Page, M. I. Biochem. Biophys. Res. Commun. 1974, 57, 887.
22. 2 derivatives resulted unsuccessful. This is due to the tendency of these complexes to undergo intramolecular cyclization, when left for a long time in solution.
23. (a) Crumbliss, A. L.; Wilmarth, W. K. J. Am. Chem. Soc. 1970, 92, 2593.
24. (b) Brown, K. L.; Lyles, D.; Pencovici, N.; Kallen, R. G. J. Am. Chem. Soc. 1975, 97, 7338.
25. (c) Brown, K. L.; Awtrey, A. W. Inorg. Chem. 1978, 17, 111.
26. (d) Dreos Garlatti, R.; Tauzher, G.; Costa, G. Inorg. Chim. Acta 1983, 71, 9.
27. (e) Dreos Garlatti, R.; Tauzher, G.; Costa, G. Inorg. Chim. Acta 1983, 70, 83.
28. (f) Dreos Garlatti, R.; Tauzher, G.; Costa, G. Inorg. Chim. Acta 1986, 121, 27.
29. (g) Dreos Garlatti, R.; Tauzher, G.; Costa, G. Inorg. Chim. Acta 1981, 50, 95.
30. (h) Dreos Garlatti, R.; Tauzher, G.; Costa, G. Inorg. Chim. Acta 1984, 82, 197.
31. (i) Dücker-Benfer, C.; Dreos, R.; van Eldik, R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2245.
32. (j) Brasch, N.; Hamza, M. S. A.; van Eldik, R. Inorg. Chem. 1997, 36, 3216.
33. (k) Hamza, M. S. A.; Zou, X.; Brown, K. L.; van Eldik, R. Inorg. Chem. 2001, 40, 5440.
34. (l) Hamza, M. S. A.; van Eldik, R.; Pratt, J. M.; Harper, P. L. S.; Betterton, E. A. Eur. J. Inorg. Chem. 2002, 580.
35. Schierbeek, B. Nonius, Delft, The Netherlands, 1998.
36. (a) Collaborative Computational Project, Number 4. Acta Crystallogr., Sect. D 1994, D50, 760.
37. (b) Sheldrick, G. M. SHELXS-86, Program for Structure Solution. Acta Crystallogr., Sect. A 1990, A46, 467.
38. Sheldrick, G. M. SHELXL-93, Program for Structure Refinement; Universität Göttingen, Göttingen, Germany, 1993.
39. Farrugia, L. J. Appl. Crystallogr. 1999, 32, 837.