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Volumn 580, Issue 2, 1999, Pages 295-303

Electron transfer versus nucleophilic pathways in the ion-pair annihilation of organoborate anions by carbonylmanganese(I) cations

Author keywords

Carbonylmanganese cations; Electron transfer; Ion pair annihilation; Nucleophilic attack; Organoborate anions; Tetramethylborate

Indexed keywords


EID: 0037514895     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)01166-8     Document Type: Article
Times cited : (3)

References (75)
  • 9
    • 0012344337 scopus 로고
    • and references cited therein
    • (a) R.J. Angelici, L.J. Blacik, Inorg. Chem. 11 (1972) 1754 and references cited therein.
    • (1972) Inorg. Chem. , vol.11 , pp. 1754
    • Angelici, R.J.1    Blacik, L.J.2
  • 40
    • 85034555252 scopus 로고    scopus 로고
    • note
    • -1).
  • 41
    • 85034559838 scopus 로고    scopus 로고
    • note
    • -1. see Ref. [5].
  • 42
    • 85034534090 scopus 로고    scopus 로고
    • note
    • 8 is 0.2 ppm, see Ref. [10].
  • 43
    • 85034561288 scopus 로고    scopus 로고
    • note
    • -1 and compared with those of the authentic sample.
  • 45
    • 0347540369 scopus 로고
    • 5. (a) C.P. Casey, C.R. Cyr, R.L. Anderson, D.F. Marten, J. Am. Chem. Soc. 97 (1975) 3053. (b) J.D. Atwood, P. Wang, J. Am. Chem. Soc. 114 (1992) 6424.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 6424
    • Atwood, J.D.1    Wang, P.2
  • 46
    • 85034563226 scopus 로고    scopus 로고
    • For the analogous pyridine adduct of trimethylborane, see above
    • For the analogous pyridine adduct of trimethylborane, see above.
  • 53
    • 85034539646 scopus 로고    scopus 로고
    • note
    • 5 and acetonitrile, so the reverse dissociation of acetonitrile should be very fast.
  • 54
    • 85034560753 scopus 로고    scopus 로고
    • note
    • 5, respectively.
  • 55
    • 85034533966 scopus 로고    scopus 로고
    • note
    • + produces methylmanganese pentacarbonyl, and no butylmanganese pentacarbonyl is observed.
  • 60
    • 85034538961 scopus 로고    scopus 로고
    • See Ref. [1a], p. 230
    • (a) See Ref. [1a], p. 230.
  • 64
    • 85034544417 scopus 로고    scopus 로고
    • note
    • 2+ occurs when the reactant anion is more nucleophilic than the product anion, and electron transfer occurs when the reactant anion is less nucleophilic [7a,b,d,g].
  • 69
    • 0010936473 scopus 로고
    • Academic Press, New York
    • R.B. King, Organometallic Syntheses, Academic Press, New York, vol. I, 1965, p. 147.
    • (1965) Organometallic Syntheses , vol.1 , pp. 147
    • King, R.B.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.