Diastereoselective substitution of PR3 for CO in carbene(dicarbonyl)-cyclopentadienyl complexes of manganese - Synthesis of (5Mn)- and (RMn)-[Cp(CO)(PR3)Mn=C(OR*)R′] complexes

European Journal of Inorganic Chemistry

Volumn , Issue 3, 1998, Pages 339-347

  Fischer, Helmut ^a   Weißenbach, Kerstin ^a   Karl, Christoph ^a   Geyer, Armin ^a  

^a UNIVERSITY OF KONSTANZ   (Germany)

Author keywords

Asymmetric synthesis; Carbene complexes; Carbohydrates; Carbyne complexes; Chiral auxiliaries

Indexed keywords

CARBOHYDRATES; CHLORINE COMPOUNDS; COBALT; LIGANDS; MANGANESE; PHOTOLYSIS; STEREOSELECTIVITY;

ASYMMETRIC SYNTHESIS; CARBENE COMPLEXES; CARBENES; CARBYNE COMPLEXES; CHIRAL AUXILIARIES; CYCLOPENTADIENYL COMPLEXES; DIASTEREOSELECTIVE; DICARBONYLS; GALACTOPYRANOSE; ISOPROPYLIDENE;

SYNTHESIS (CHEMICAL);

EID: 0037513723     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1099-0682(199803)1998:3<339::aid-ejic339>3.0.co;2-9     Document Type: Article

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48. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road. Cambridge CB2 1EZ, UK [fax: int. code +44(1223)336-033, e-mail: deposit@ccdc.cam.ac.uk].