Reactivity of [Cp2Ti(CO)2] and B(C6F5)3: Formation of the acylborane complexes [Cp2Ti(CO)(η2-OCB(C6 F5)3)] and [Cp2Ti(THF)(η2- OCB(C6F5)3)]

Organometallics

Volumn 22, Issue 10, 2003, Pages 1995-1997

  Choukroun, Robert ^a   Lorber, Christian ^a   Lepetit, Christine ^a   Donnadieu, Bruno ^a  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYL CARBON ATOM; LEWIS ACID; TITANA ACYLBORANE;

ACIDS; CHEMICAL BONDS; CHEMICAL REACTIONS; OLEFINS; PHASE TRANSITIONS; POLYMERIZATION; X RAY DIFFRACTION ANALYSIS;

TITANIUM COMPOUNDS;

EID: 0037482011     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030185t     Document Type: Article

References (38)

1. (a) Coates, G. W.; Hustad, P. D.; Reiinartz, S. Angew. Chem., Int. Ed. 2002, 41, 2236-2257.
2. (b) You-Xian Chen, E., Marks, T. J. Chem. Rev. 2000, 100, 1391-1434.
3. (c) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 38, 428-447.
4. (a) Piers, W. E.; Chivers, T. Chem. Soc. Rev. 1997, 26, 345-354.
5. (b) Parks, D. J.; Piers, M.; Parvez, W. E.; Atencio, R.; Zaworotko, M. Organometallics 1998, 17, 1369-1377.
6. (c) Parks, D. J.; Blackwell, J. M.; Piers, W. E. J. Org. Chem. 2000, 3090-3098.
7. (d) Parks, D. J.; Spence, R. E. v. H.; Piers, W. E. Angew. Chem., Int. Ed. Engl. 1995, 34, 809-810.
8. (e) Blackwell, J. M.; Piers, W. E.; Parvez, M.; McDonald, R. Organometallics 2002, 21, 1400-1407.
9. (a) Jacobsen, H.; Berke, H.; Döring, S.; Kehr, G.; Erker, G.; Fröhlich, R.; Meyer, O. Organometallics 1999, 18, 1724-1735.
10. (b) Vagedes, D.; Kehr, G.; König, D.; Wedeking, K.; Frölich, R.; Erker, G.; Mück-Lichtenfeld, C.; Grimme, S. Eur. J. Inorg. Chem. 2002, 2015-2021.
11. Klosin, J.; Roof, G. R.; Chen, E. Y. X. Organometallics 2000, 19, 4684-4686.
12. Bradley, D. C.; Harding, I. S.; Keefe, A. D.; Motevalli, M.; Zheng, D. H. J. Chem. Soc., Dalton Trans. 1996, 3931-3936.
13. (a) Green, M. L. H.; Haggitt, J.; Mehnert, C. P. J. Chem. Soc., Chem. Commun. 1995, 1853-1854.
14. (b) Antinolo, A.; Carillo-Hermosilla, F.; del Hierro, I.; Otero, A.; Fajardo, M.; Mugnier, Y. Organometallics 1997, 16, 4161-4166.
15. (a) Choukroun, R.; Lorber, C.; Donnadieu, B. Chem. Eur. J. 2002, 8, 2700-2704.
16. (b) Wolff, F.; Choukroun, R.; Lorber, C.; Donnadieu, B. Eur. J. Inorg. Chem. 2003, 628-632.
17. Schriver, D. F. Acc. Chem. Res. 1970, 3, 231-238.
18. Braunschweig, H.; Colling, M. Coord. Chem. Rev. 2001, 223, 1-51.
19. Churchill, M. R.; Wasserman, H.; Holmes, S.J.; Schrock, R. R. Organometallics 1982, 1, 766-768.
20. Richmond, T. G.; Basolo, F.; Shriver, D. Inorg. Chem. 1982, 21, 1272-1273.
21. Fachinetti, G.; Floriani, C.; Stoeckli-Evans, H. J. Chem. Soc., Dalton Trans. 1977, 2297-2300.
22. Pankowski, M.; Cabestaing, C.; Jaouen, G. J. Organomet. Chem. 1996, 516, 11-16.
23. (a) Boyle, T. J.; Schwartz, R. W.; Doedens, R. J.; Ziller, J. W., Inorg. Chem. 1995, 34, 1110-1120 and references therein.
24. (b) Siedle, A. R.; Huffman, J. C. Inorg. Chem. 1990, 29, 3131-3133.
25. Devore, F. D. D.; Timmers, J.; Hasha, D. L.; Rosen, R. K.; Marks, T. J.; Deck, P. A.; Stern, C. L. Organometallics 1995, 14, 3132-3134 (usual Ti-C single bonds lie within the range of 2.16-2.27 Å).
26. Atwood, J. L.; Stone, K. E.; Alt, H. G.: Hrncir, D. C.; Rausch, M. D. J. Organomet. Chem. 1975, 96, C4-C6.
27. Gordy, W.; Ring, H.; Burg A. B. Phys. Rev. 1950, 78, 512-514.
28. Bochmann, M.; Jaggar, A. J.; Wilson, L. M.; Hursthouse, M.B.; Motevalli, M. Polyhedron 1989, 8, 1838-1843.
29. (a) Tatsumi, K.; Nakamura, A.; Hofmann, P.; Stauffert, P., Hoffmann, R. J. Am. Chem. Soc. 1985, 107, 4440-4451 and references therein.
30. (b) de Angelis, F.; Sgamellotti, A.; Re, N. Organometallics 2000, 19, 4904-4911.
31. (c) Lupinetti, A. J.; Strauss, S. H.; Frenking, G. Prog. Inorg. Chem. 2001, 49, 1-112.
32. Guo, Z.; Swenson, D. C.; Guram, A. S.; Jordan, R. F. Organometallics 1994, 13, 766-773.
33. Crowe, W. E.; Vu, A. T. J. Am. Chem. Soc. 1996, 118, 1557-1558.
34. Gadre, S. R. In Computational Chemistry: Reviews of Current Trends; Lesczynski, J., Ed.; World Scientific Singapore, 1999; Vol. 4, pp 1-53, and references therein.
35. A few CO-borane adducts have been isolated: Jeffery, J. C.; Norman, N. C.; Pardoe, J. A. J.; Timms, P. L. Chem. Commun. 2000, 2367-2368 and references therein.
36. (a) Kabalka, G. W.; Gotsick, J. T.; Pace, R. D.; Li, N.-S. Organometallics 1994, 13, 5163-5165 and references therein.
37. (b) Brown, H. C. Acc. Chem. Res. 1969, 2, 65-72.
38. Preliminary results show the formation of a titana(IV)azirine complex.