One-electron oxidation of heterodinuclear organometallic compounds having polyphosphido bridges

Organometallics

Volumn 22, Issue 9, 2003, Pages 1948-1952

  Winter, Rainer F ^a,b   Geiger, William E ^a  

^a UNIVERSITY OF VERMONT   (United States)

^b UNIVERSITY OF STUTTGART   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

FERROCENIUM ION; HETERODINUCLEAR ORGANOMETALLIC COMPOUNDS; ONE ELECTRON OXIDATION; PSEUDO SANDWICH POLYPHOSPHIDO BRIDGES;

COMPLEXATION; ELECTROCHEMISTRY; ELECTROLYSIS; ELECTRON SPIN RESONANCE SPECTROSCOPY; INFRARED SPECTROSCOPY; MOLECULAR STRUCTURE; OXIDATION; PHOSPHORUS COMPOUNDS;

ORGANOMETALLICS;

EID: 0037481710     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020778o     Document Type: Article

References (33)

1. Gates, B. C. Chem. Rev. 1995, 95, 511.
2. Ichikawa, M. Adv. Catal. 1992, 38, 283.
3. Aubart, M. A.; Bergman, R. G. J. Am. Chem. Soc. 1996, 118, 1793.
4. Nashner, M. S.; Somerville, D. M.; Lane, P. D.; Alder, D. L.; Sharpley, J. R.; Nuzzo, R. G. J. Am. Chem. Soc. 1996, 118, 12964.
5. Mukerjee, S.; Srinivasan, S.; Soriaga, M. P.; McBreen, J. J. Electrochem. Soc. 1995, 142, 1409.
6. (a) Lemoine, P. Coord. Chem. Rev. 1988, 83, 169.
7. (b) Zanello, P. Coord. Chem. Rev. 1988, 83, 169.
8. (c) Geiger, W. E.; Connelly, N. G. Adv. Organomet. Chem. 1985, 24, 87.
9. Collins, B. Y.; Koide, Y.; Schauer, C. K.; White, P. S. Inorg. Chem. 1997, 36, 6172.
10. (a) Barr, M. E.; Adams, B. R.; Weller, R. R.; Dahl, L. F. J. Am. Chem. Soc. 1991, 113, 3052.
11. (b) Barr, M. E.; Dahl, L. F. Organometallics 1991, 10, 3991.
12. (a) Scherer, O. J. Angew. Chem., Int. Ed. Engl. 1985, 24, 924.
13. (b) Scheer, M. Z. Chem. 1990, 29, 41.
14. (c) Barr, M. E.; Adams, B. R.; Weller, R. R.; Dahl, L. E. J. Am. Chem. Soc. 1991, 113, 3052.
15. (d) Scherer, O. J. Angew. Chem., Int. Ed. Engl. 1990, 29, 1004.
16. (e) Scherer, O. J. Acc. Chem. Res. 1999, 32, 751.
17. (f) Ehses, M.; Remerosa, A.; Peruzzini, M. Top. Curr. Chem. 2002, 220, 107.
18. Winter, R. F.,; Geiger, W. E. Organometallics 1999, 18, 1827 and references therein.
19. Scherer, O. J.; Schwalb, J.; Swarowsky, H.; Kaim, W.; Gross, R. Chem. Ber. 1988, 121, 443.
20. Compounds 2 and 3: Detzl, M.; Mohr, T.; Scherer, O. J.; Wolmershäuser, G. Angew. Chem., Int. Ed. Engl. 1994, 33, 1110.
21. Compound 4: Scherer, O. J.; Berg, G.; Wolmershäuser, G. Chem. Ber. 1995, 128, 635.
22. 3-1,24.
23. Gritzner, G.; Kuta, J. Pure Appl. Chem. 1984, 56, 461.
24. Atwood, C. G.; Geiger, W. E.; Bitterwolf, T. E. J. Electroanal. Chem. 1995, 397, 279.
25. Geiger, W. E. In Laboratory Techniques in Electroanalytical Chemistry, 2nd ed.; Kissinger, P. T., Heineman, W. R., Eds.; Marcel Dekker: New York, 1996; p. 683 ff.
26. Bard, A. J.; Faulkner, L. R. Electrochemical Methods, 2nd ed.; Wiley: New York, 2001; pp 207-210.
27. 181Ta, one obtains a scatter of 5-157% tantalum 5d character. For details of this treatment see: Weil, J. A.; Bolton, J. R.; Wertz, J. E. Electron Paramagnetic Resonance, Wiley: New York, 1994; Chapers 5 and 9 and Table G.4.
28. 2+. Bard, A. J.; Faulkner, L. R. Electrochemical Methods, 2nd ed.; Wiley: New York, 2001; pp 234-243.
29. Robben, M. P.; Rieger, P. H.; Geiger, W. E. J. Am. Chem. Soc. 1999, 121, 367.
30. Weil, J. A. et al. Electron Paramagnetic Resonance, Wiley: New York, 1994; Chapters 5 and 9 and Table G.4. p 536.
31. Connelly, N. G.; Emslie, D. J. H.; Klangsinsirikul, P.; Rieger, P. H. J. Phys. Chem. A 2002, 106, 51.
32. Goldberg, K. I.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 4853.
33. von Schnering, H. G.; Hönle, W. Chem. Rev. 1988, 88, 243