Mixed matrix membranes using carbon molecular sieves: II. Modeling permeation behavior

Journal of Membrane Science

Volumn 211, Issue 2, 2003, Pages 335-348

  Vu, De Q ^a,b   Koros, William J ^c   Miller, Stephen J ^b  

^a The University of Texas at Austin   (United States)

^b CHEVRON ENERGY TECHNOLOGY COMPANY   (United States)

^c Georgia Institute of Technology   (United States)

Author keywords

Bruggeman Model; Carbon molecular sieve; Gas separation; Heterogeneous membrane; Maxwell Model; Mixed matrix membrane; Natural gas

Indexed keywords

CARBON; DATA ACQUISITION; MATRIX ALGEBRA; MAXWELL EQUATIONS; POLYMERS; SEPARATION;

GAS SEPARATIONS; MIXED MATRIX MEMBRANES;

PERMSELECTIVE MEMBRANES;

DISPERSION; MEMBRANE; MODELING; MOLECULAR SIEVE; PERMEABILITY;

ADAPTATION; ARTICLE; DISPERSION; GAS PERMEABILITY; MEMBRANE; MIXED MATRIX MEBRANE; MODEL; MOLECULAR BIOLOGY; PRIORITY JOURNAL; RIGIDITY; SURFACE PROPERTY;

EID: 0037473749     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0376-7388(02)00425-8     Document Type: Article

References (52)

1. H. Suda, K. Haraya, Carbon molecular sieve membranes: preparation, characterization, and gas permeation properties, ACS Symposium Series 744: Membrane Formation and Modification, 2000, pp. 295-313.
2. Singh A., Koros W.J. Significance of entropic selectivity for advanced gas separation membranes. Ind. Eng. Chem. Res. 35:1996;1231-1234.
3. K. Steel, Carbon membranes for challenging gas separations, Ph.D. Dissertation, The University of Texas at Austin, 2000.
4. 4 separation using carbon molecular sieve hollow fiber membranes. Ind. Eng. Chem. Res. 41:2002;367-380.
5. C.M. Zimmerman, Advanced gas separation membrane materials: hyper rigid polymers and molecular sieve-polymer mixed matrices, Ph.D. Dissertation, The University of Texas at Austin, 1998.
6. Zimmerman C.M., Singh A., Koros W.J. Tailoring mixed matrix composite membranes for gas separations. J. Membr. Sci. 137:1997;145-154.
7. R. Mahajan, C.M. Zimmerman, W.J. Koros, Fundamental and practical aspects of mixed matrix gas separation membranes, ACS Symposium Series, 1999, pp. 277-286.
8. S. Kulprathipanja, R.W. Neuzil, N.N. Li, Gas separation by means of mixed matrix membranes, US Patent 4,740,219, Allied-Signal Inc., USA (1988).
9. Jia M., Peinemann K.V., Behling R.D. Molecular sieving effect of the zeolite-filled silicone rubber membranes in gas permeation. J. Membr. Sci. 57:1991;289-296.
10. Duval J.M., Folkers B., Mulder M.H.V., Desgrandchamps G., Smolders C.A. Adsorbent-filled membranes for gas separation. Part 1. Improvement of the gas separation properties of polymeric membranes by incorporation of microporous adsorbents. J. Membr. Sci. 80:1993;189-198.
11. Gür T.M. Permselectivity of zeolite filled polysulfone gas separation membranes. J. Membr. Sci. 93:1994;283-289.
12. Mahajan R., Koros W.J. Factors controlling successful formation of mixed-matrix gas separation materials. Ind. Eng. Chem. Res. 39:2000;2692-2696.
13. Boom J.P., Punt I.G.M., Zwijnenberg H., de Boer R., Bargeman D., Smolders C.A., Strathmann H. Transport through zeolite filled polymeric membranes. J. Membr. Sci. 138:1998;237-258.
14. Duval J.M., Kemperman A.J.B., Folkers B., Mulder M.H.V., Desgrandchamps G., Smolders C.A. Preparation of zeolite filled glassy polymer membranes. J. Appl. Polym. Sci. 54:1994;409-418.
15. Vankelecom I.F.J., Merckx E., Luts M., Uytterhoeven J.B. Incorporation of zeolites in polyimide membranes. J. Phys. Chem. 99:1995;13187-13192.
16. Vankelecom I.F.J., Van den Broeck S., Merckx E., Geerts H., Grobet P., Uytterhoeven J.B. Silylation to improve incorporation of zeolites in polyimide films. J. Phys. Chem. 100:1996;3753-3758.
17. D.Q. Vu, W.J. Koros, S.J. Miller, Mixed matrix membranes using carbon molecular sieves. I. Preparation and experimental results, J. Membr. Sci., in press.
18. Petropoulos J.H. A comparative study of approaches applied to the permeability of binary composite polymeric materials. J. Polym. Sci., Polym. Phys. Ed. 23:1985;1309-1324.
19. J.C. Maxwell, Treatise on Electricity and Magnetism, Oxford University Press, London, 1873.
20. Bouma R.H.B., Checchetti A., Chidichimo G., Drioli E. Permeation through a heterogeneous membrane: the effect of the dispersed phase. J. Membr. Sci. 128:1997;141-149.
21. Robeson L.M., Noshay A., Matzner M., Merriam C.N. Physical property characteristics of polysulfone/poly(dimethylsiloxane) block copolymers. Angew. Makromol. Chem. 29-30:1973;47-62.
22. Zimmerman C.M., Singh A., Koros W.J. Tailoring mixed matrix composite membranes for gas separations. J. Membr. Sci. 137:1997;145-154.
23. Banhegyi G. Comparison of electrical mixture rules for composites. Colloid Polym. Sci. 264:1986;1030-1050.
24. Eisenberg A., Hird B., Moore R.B. A new multiplet-cluster model for the morphology of random ionomers. Macromolecules. 23:1990;4098-4107.
25. R. Mahajan, Formation, characterization, and modeling of mixed matrix membranes materials, Ph.D. Dissertation, The University of Texas at Austin, 2000.
26. Mogri Z., Paul D.R. Gas sorption and transport in side-chain crystalline and molten poly(octadecyl acrylate). Polymer. 42:2000;2531-2542.
27. J. Brandrup, E.H. Immergut, E.A. Grulke (Eds.), Polymer Handbook, 4th Ed., Wiley, New York, 1999.
28. Michaels A.S., Parker R.B. Jr. Sorption and flow of gases in polyethylene. J. Polym. Sci. 41:1959;53-71.
29. Michaels A.S., Bixler H.J. Flow of gases through polyethylene [and rubbery polymers]. J. Polym. Sci. 50:1961;413-439.
30. Michaels A.S., Bixler H.J. Solubility of gases in polyethylene [and rubbery polymers]. J. Polym. Sci. 50:1961;393-412.
31. R. Camargo, F. Mercer, T.C. Cheng, Compositions of poly(imides) having phenylindane diamines and/or dianhydride moieties in the poly(imide) backbone, US Patent 5,047,487, Raychem Corp., USA (1991).
32. P.M. Subramanian, I.G. Plotzker, Barrier materials by blending, in: Polymer Blends, Wiley, New York, 2000.
33. 4 through kapton polyimide: effects of penetrant competition and gas-phase nonideality. J. Polym. Sci., Polym. Phys. Ed. 22:1984;1061-1084.
34. Barbari T.A., Koros W.J., Paul D.R. Polymeric membranes based on bisphenol-A for gas separations. J. Membr. Sci. 42:1989;69-86.
35. R.T. Chern, W.J. Koros, E.S. Sanders, S.H. Chen, H.B. Hopfenberg, Implications of the dual-mode sorption and transport models for mixed gas permeation, ACS Symposium Series, 1982, pp. 157-169.
36. Koros W.J., Chern R.T., Stannett V., Hopfenberg H.B. Model for permeation of mixed gases and vapors in glassy polymers. J. Polym. Sci., Polym. Phys. Ed. 19:1985;1015-1022.
37. 2 in a carbon molecular sieve membrane. Ind. Eng. Chem. Res. 40:2001;2942-2946.
38. Rutherford S.W., Do D.D. Permeation time lag and heterogeneity in adsorbed phase transport. Chem. Eng. Sci. 55:2000;3543-3551.
39. Chen Y.D., Yang R.T. Concentration dependence of surface diffusion and zeolitic diffusion. AIChE J. 37:1991;1579-1582.
40. Chen Y., Yang R.T. Surface and mesoporous diffusion with multilayer adsorption. Carbon. 36:1998;1525-1537.
41. Higashi K., Ito H., Oishi J. Surface diffusion phenomena in gaseous diffusion. I. Surface diffusion of pure gases. J. At. Energy Soc. Jpn. 5:1963;846-853.
42. Kapteijn F., Moulijn J.A., Krishna R. The generalized Maxwell-Stefan model for diffusion in zeolites: sorbate molecules with different saturation loadings. Chem. Eng. Sci. 55:2000;2923-2930.
43. Krishna R., van den Broeke L.J.P. The Maxwell-Stefan description of mass transport across zeolite membranes. Chem. Eng. J. (Lausanne). 57:1995;155-162.
44. Krishna R., Wesselingh J.A. The Maxwell-Stefan approach to mass transfer. Chem. Eng. Sci. 52:1997;861-911.
45. Yang R.T., Fenn J.B., Haller G.L. Modification to the Higashi model for surface diffusion. AIChE J. 19:1973;1052-1053.
46. Chen Y.D., Yang R.T., Uawithya P. Diffusion of oxygen, nitrogen and their mixtures in carbon molecular sieve. AIChE J. 40:1994;577-585.
47. Chen Y.D., Yang R.T. Preparation of carbon molecular sieve membrane and diffusion of binary mixtures in the membrane. Ind. Eng. Chem. Res. 33:1994;3146-3153.
48. D.Q. Vu, Formation and characterization of asymmetric carbon molecular sieve and mixed matrix membranes for natural gas purification, Ph.D. Dissertation, The University of Texas at Austin, 2001.
49. Koros W.J., Chan A.H., Paul D.R. Sorption and transport of various gases in polycarbonate. J. Membr. Sci. 2:1977;165-190.
50. Chan A.H., Koros W.J., Paul D.R. Analysis of hydrocarbon gas sorption and transport in ethyl cellulose using the dual sorption/partial immobilization models. J. Membr. Sci. 3:1978;117-130.
51. J.M. Prausnitz, R.N. Lichtenthaler, E. Gomes de Azevedo, Molecular Thermodynamics of Fluid-Phase Equilibria, Prentice-Hall, Englewood Cliffs, NJ, 1986.
52. D.R. Lide (Ed.), CRC Handbook of Chemistry and Physics, CRC Press, Boca Raton, 1991.