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Volumn 125, Issue 4, 2003, Pages 1041-1055

Role of copper ion in bacterial copper amine oxidase: Spectroscopic and crystallographic studies of metal-substituted enzymes

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; CATALYSTS; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; ELECTRON TRANSITIONS; ENZYMES; HYDROGEN BONDS; OXIDATION; POSITIVE IONS; SPECTROSCOPIC ANALYSIS; SUBSTITUTION REACTIONS; SUBSTRATES;

EID: 0037471670     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja017899k     Document Type: Article
Times cited : (101)

References (66)
  • 1
    • 0347482617 scopus 로고    scopus 로고
    • note
    • pim, product Schiff base form of TPQ.
  • 21
    • 0347482616 scopus 로고    scopus 로고
    • note
    • max at 350 nm that shifts to ∼450 nm upon deprotonation to give a spectrum essentially identical to that of the deprotonated, delocalized iminoquinone. The substitution of an alkyl group onto the imine nitrogen seems not to affect the spectroscopic properties of the iminoquinone. For details, see ref 22.
  • 24
    • 0348112701 scopus 로고    scopus 로고
    • note
    • pim prepared with propylaldehyde or phenylacetoaldehyde will be identical.
  • 32
    • 0028103275 scopus 로고
    • Collaborative Computational Project Number 4. Acta Crystallogr. 1994, D50, 760-763.
    • (1994) Acta Crystallogr. , vol.D50 , pp. 760-763
  • 35
    • 0346221499 scopus 로고    scopus 로고
    • note
    • 2+ (Table 2), suggesting that the fully copper-depleted form of enzyme is completely inactive.
  • 38
    • 0348112699 scopus 로고    scopus 로고
    • unpublished results
    • 39,40
    • Kim, M.1
  • 42
    • 0348112700 scopus 로고    scopus 로고
    • note
    • 13,23,59
  • 60
    • 0348112698 scopus 로고    scopus 로고
    • note
    • 41 should also be underestimated.
  • 61
    • 0346221498 scopus 로고    scopus 로고
    • note
    • sq forms in undetectable levels. This could also explain why the oxidative half-reaction is so much slower in these systems. Our data cannot discount this possibility.
  • 66
    • 0002950518 scopus 로고
    • Martell, A. E., Ed.; ACS Monograph 174; American Chemical Society: Washington, DC
    • Margerum, D. W.; Cayley, G. R.; Weatherburn, D. C.; Pagenkopf, G. K. In Coordination Chemistry; Martell, A. E., Ed.; ACS Monograph 174; American Chemical Society: Washington, DC, 1978; Vol. 2, pp 1-220.
    • (1978) Coordination Chemistry , vol.2 , pp. 1-220
    • Margerum, D.W.1    Cayley, G.R.2    Weatherburn, D.C.3    Pagenkopf, G.K.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.