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Volumn 44, Issue 18, 2003, Pages 3649-3651

Pd-SAPO-31, an efficient, heterogeneous catalyst for Heck reactions of aryl chlorides

Author keywords

[No Author keywords available]

Indexed keywords

CHLORIDE; PALLADIUM COMPLEX;

EID: 0037471449     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(03)00706-8     Document Type: Article
Times cited : (50)

References (22)
  • 2
    • 0000633011 scopus 로고
    • B.M. Trost, & I. Fleming. Oxford: Pergamon Press
    • Heck R.F. Trost B.M., Fleming I. Comprehensive Organic Synthesis. 4:1991;833 Pergamon Press, Oxford.
    • (1991) Comprehensive Organic Synthesis , vol.4 , pp. 833
    • Heck, R.F.1
  • 13
    • 0012919181 scopus 로고    scopus 로고
    • 2O (74.46 mg) and SAPO-31 (1 g). The suspension was stirred for 10 h at 90°C. The solid (Pd-SAPO-31) was calcined at 550°C for 6 h and then reduced at 400°C under hydrogen flow for 6 h. Ni-SAPO-31 and Cu-SAPO-31 were prepared in a similar manner using the nitrate salts of Ni and Cu, respectively.
    • 2O (74.46 mg) and SAPO-31 (1 g). The suspension was stirred for 10 h at 90°C. The solid (Pd-SAPO-31) was calcined at 550°C for 6 h and then reduced at 400°C under hydrogen flow for 6 h. Ni-SAPO-31 and Cu-SAPO-31 were prepared in a similar manner using the nitrate salts of Ni and Cu, respectively.
  • 15
    • 0012918308 scopus 로고    scopus 로고
    • The Heck reactions were carried out in a glass, round bottom flask (25 ml) fitted with a water-cooled condenser. In a typical reaction, the halobenzene (1 mmol), methyl acrylate (2 mmol), base (1.5 mmol) and catalyst (4 wt% with respect to halobenzene) were taken in 5 g of solvent. The reaction was conducted at 60-120°C under a nitrogen atmosphere. The progress and completion of the reaction was monitored by gas chromatography. The products were identified by GC-MS.
    • The Heck reactions were carried out in a glass, round bottom flask (25 ml) fitted with a water-cooled condenser. In a typical reaction, the halobenzene (1 mmol), methyl acrylate (2 mmol), base (1.5 mmol) and catalyst (4 wt% with respect to halobenzene) were taken in 5 g of solvent. The reaction was conducted at 60-120°C under a nitrogen atmosphere. The progress and completion of the reaction was monitored by gas chromatography. The products were identified by GC-MS.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.