Perturbation of the oscillatory BZ reaction with methanol and ethylene glycol: Experiments and model calculations

Journal of Physical Chemistry A

Volumn 107, Issue 12, 2003, Pages 2039-2047

  Pelle, Krisztina ^a   Wittmann, Maria ^a   Noszticzius, Zoltan ^a   Lombardo, Renato ^b   Sbriziolo, Carmelo ^b   Turco Liveri, Maria L ^b  

^a BUDAPEST UNIVERSITY OF TECHNOLOGY AND ECONOMICS   (Hungary)

^b UNIVERSITY OF PALERMO   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; COMPUTER SIMULATION; HYDROGELS; METHANOL; MOLECULAR DYNAMICS; NUMERICAL METHODS; PERTURBATION TECHNIQUES;

ETHYLENE GLYCOL; OSCILLATORY; SPECTROPHOTOMETRIC;

POLYETHYLENE GLYCOLS;

EID: 0037468874     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp026713g     Document Type: Article

References (41)

1. Oscillations and Traveling Waves in Chemical Systems; Field, R. J., Burger, M., Eds.; Wiley: New York, 1985.
2. Gray, P.; Scott, S. K. Chemical Oscillations and Instabilities. Nonlinear Chemical Kinetics; Clarendon, Oxford, 1994.
3. Chemical Waves and Patterns; Kapral, R., Showalter, K., Eds.; Kluwer: Dordrecht, 1995.
4. Epstein, I. R.; Pojman, J. A. An Introduction to Nonlinear Chemical Dynamics; Oxford University Press: New York, 1998.
5. Nonlinear Dynamics in Polymer Science; Khoklov, A. R., Tran-Cong-Miyata, Q., Davydov, V. A., Yamaguchi, T., Kuchanov, S. I., Eds.; Wiley-VCH: Weinheim, 2000.
6. Noszticzius, Z.; Horsthemke, W.; McCormick, W. D.; Swinney, H. L.; Tam, W. Y. Nature 1987, 329, 619.
7. Castets, V.; Dulos, E.; Boissonade, J.; De Kepper, P. Phys. Rev. Lett. 1990, 64, 2953.
8. Kuhnert, L. Naturwissenschaften 1983, 70, 464.
9. Winfree, A. T. The geometry of biological time; Springer: Berlin, 1980, p 301.
10. Yamaguchi, T.; Kuhnert, I.; Nagy-Ungvárai, Zs.; Müller, S. C.; Hess, B. J. Phys. Chem. 1991, 95, 5831.
11. Lázár, A.; Försterling, H. D.; Farkas, H.; Simon, P.; Volford, A.; Noszticzius, Z. Chaos 1997, 7, 731.
12. Horváth, J.; Nagy-Ungvárai, Zs.; Müller, S. C., Phys. Chem. Chem. Phys. 2001, 3, 218.
13. Lee, K. J.; McCormick, W. D.; Noszticzius, Z.; Swinney, H. L. J. Chem. Phys. 1992, 96, 4048.
14. Noszticzius, Z.; Ouyang, Q.; McCormick, W. D.; Swinney, H. L. J. Phys. Chem. 1992, 96, 6302.
15. Yoshida, R.; Takashi, T.; Yamaguchi, T.; Ichijo, H. J. Am. Chem. Soc. 1996, 118, 5134.
16. Váradi, Z.; Beck, M. T. J. Chem. Soc., Chem. Commun. 1973, 30.
17. Pojman, J. A.; Leard, D. C.; West, W. J. Am. Chem. Soc. 1992, 114, 8298.
18. Washington, R. P.; Misra, G. P.; West, W. W.; Pojman, J. A. J. Am. Chem. Soc. 1999, 121, 7373.
19. Cavasino, F. P.; Sbriziolo, C.; Turco Liveri, M. L. "Effects of polymers on the cerium(IV)-catalyzed Belousov-Zhabotinsky reaction", International Conference on "Nonlinear Dynamics in Polymer Science and Related Fields" (PolyNon'99), Moscow, DESNA (Russia), 1999. Conference Proceedings (Yamaguchi, T., Ed.), printed by ISEBU Co., LTD, Tsukuba, Japan, p 10. The abstract focuses on an analogous effect of poly(propylene glycol) (PPG). In the full lecture it was pointed out that poly(ethylene glycol) (PEG) also lengthens the induction period and shortens the time period. All these and other effects are discussed in detail in our next publication.
20. Lombardo, R.; Sbriziolo, C.; Turco Liveri, M. L.; Pelle, K.; Wittmann, M.; Noszticzius, Z. "Perturbation of the oscillatory Belousov-Zhabotinsky reaction with poly(ethylene glycol)" in: Nonlinear Dynamics in Polymeric Systems; Tran-Cong-Miyata, Q.; Pojman, J. A., Eds.; American Chemical Society: Washington, DC, 2003, in press.
21. Försterling, H. D.; Lamberz, H. J.; Schreiber, H. Z. Naturforsch. 1983, 38a, 483.
22. Nagy-Ungvárai, Zs.; Zimányi, I. React. Kinet. Catal. Lett. 1986, 31, 249.
23. Field, R. J.; Kõrös, E.; Noyes, R. M. J. Am. Chem. Soc. 1972, 94, 8649.
24. Field, R. J.; Noyes, R. M. J. Chem. Phys. 1974, 60, 1877.
25. Györgyi, L.; Turányi, T.; Field, R. J. J. Phys. Chem. 1990, 94, 7162.
26. Györgyi, L.; Turányi, T.; Field, R. J. J. Phys. Chem. 1993, 97, 1931.
27. Försterling, H. D.; Noszticzius, Z. J. Phys. Chem. 1989, 93, 2740.
28. Försterling, H. D.; Murányi, Sz.; Nosztczius, Z. J. Phys. Chem. 1990, 94, 2915.
29. Gao, Y.; Försterling, H. D.; Noszticzius, Z.; Meyer, B. J. Phys. Chem. 1994, 98, 8377.
30. Sirimungkala, A.; Försterling, H. D.; Noszticzius, Z. J. Phys. Chem. 1996, 100, 3051.
31. Oslonovitch, J.; Försterling, H. D.; Wittmann, M.; Noszticzius, Z. J. Phys. Chem. 1998, 102, 922.
32. Hegedüs, L.; Försterling, H. D.; Kókai, E.; Pelle, K.; Taba, G.; Wittmann, M.; Noszticzius, Z. Phys. Chem. Chem. Phys. 2000, 2, 4023.
33. Hegedüs, L.; Wittmann, M.; Noszticzius, Z.; Yan, S.; Sirimungkala, A.; Försterling, H. D.; Field, R. J. Faraday Discuss. 2001, 120, 21.
34. (a) Noszticzius, Z.; Bódiss, J. J. Am. Chem. Soc. 1979, 101, 3177.
35. (b) Nagygyõry, Sz.; Wittmann, M.; Pintér, Sz.; Visegrády, A.; Dancsó, A.; Nguyen Bich, T.; Noszticzius, Z. J. Phys. Chem. A 1999, 103, 4885.
36. Degn, H.; Lauritsen, F. R. J. Phys. Chem. 1989, 93, 2781.
37. Schmidt, V. M.; Vielstich, W. Ber. Bunsen-Ges. Phys. Chem. Chem. Phys. 1992, 96, 534.
38. Försterling, H. D.; Idstein, H.; Pachl, R.; Schreiber, H. Z. Naturforsch. 1984, 39a, 993.
39. Hansen, E. W.; Gran, H. C.; Ruoff, P. J. Phys. Chem. 1984, 88, 4908.
40. Ruoff, P.; Hansen, E. W.; Noyes, R. M. J. Phys. Chem. 1987, 91, 3393.
41. Natarayan, R.; Venkatasubramanian, N. Tetrahedron 1974, 30, 2785.