Solubilization of rare earth oxides in the eutectic LiCl-KCl mixture at 450 °C and in the equimolar CaCl2-NaCl melt at 550 °C

Journal of Electroanalytical Chemistry

Volumn 545, Issue SUPPL., 2003, Pages 141-157

  Castrillejo, Y ^a   Bermejo, M R ^a   Barrado, E ^a   Martinez A M ^a,c   Diaz Arocas P ^b  

^a UNIVERSITY OF VALLADOLID   (Spain)

^b CIEMAT   (Spain)

^c Department of Materials Technology ^*  (Norway)

Author keywords

E pO2 diagrams; Lanthanides; Molten chlorides; Rare earths; Solubilization test; Yttria stabilized zirconia electrode

Indexed keywords

CHLORINATION; EUTECTICS; KINETIC THEORY; MOLTEN MATERIALS; POSITIVE IONS; RARE EARTH COMPOUNDS; REDOX REACTIONS; SOLUBILITY;

GASEOUS MIXTURES;

ELECTROCHEMISTRY;

EID: 0037468728     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-0728(03)00092-5     Document Type: Article

References (56)

1. Ferry D.M., Picard G.S., Trémilllon B.L. Trans. Instn. Min. Metall. 97:1988;C21-C30. (Section C: Mineral Process Extr. Metall.).
2. Koyama T., Iizuka M., Tanaka H., Tokiwai M., Shoji Y., Fujita R., Kobayashi T. J. Nucl. Sci. Technol. 34:1997;384.
3. T.H. Pigford, Actinide burning and waste disposal, an invited review for the MIT International Conference on the Next Generation of Nuclear Power Technology, Department of Nuclear Engineering, University of California ar Berkeley, CA, UCB-NE-4176, Rev. 1 (October 1990).
4. M. Tokiwai, T. Kobayashi, T. Koyama, M. Tsunashima, S. Horie, T. Kawaii, I. Kakehi, H. Matsuura, K. Yanagida, M. Shuto, Proceedings of International Conference on Fast Reactors and Related Fuel Cycles (FR'91), October 1991, Kyoto, Japan, Vol. II, (1991) 12.7-1.
5. M. Iizuka, K. Uozumi, T. Inoue, T. Iwai, O. Shirai, Y. Arai, NEA/OECDE 2000.
6. Inoue T., Sakamura, Y. Gaune-Escard M. Molten salts: from fundamentals to applications. NATO science series II. 52:2002;249-261 Kluwer Academic Publishers, Dordrecht.
7. Actinide and Fission Product Partitioning and Transmutation. Status and Assessment report. NEA/OCDE, 1999.
8. Laidler J.J. Trans. Am. Nucl. Soc. 68:1993;16.
9. Sakamura Y., Inoue T., Shirai O., Iwai T., Arai Y., Suzuki Y. Proceedings of Global 99. 1999;Jackson Hole, Wyoming, USA.
10. G.S. Picard, Molten Salt Forum, 1-2, 1993/94 25.
11. G.S. Picard, F.M. Seon, B.L. Tremillon, Proceedings of the Fourth International Symposium on Molten Salts. The Electrochemical Society, Washington, DC, (1984), 694-706.
12. G.S. Picard, S. Sánchez, D. Lambert́n, J. Lacquement, Proceeding of Global 2001. International Conference of the Fuel Cycle: from Research Solutions, Paris, France 2001.
13. F. Seon, Doctoral Thesis, Paris, 1981.
14. Seon F., Picard G., Tremillon B. Electrochim. Acta. 28:1983;209.
15. M.D. Lambertin, Doctoral Thesis, Paris, 2001.
16. Castrillejo Y., Bermejo M.R., Pardo R., Martínez A.M. J. Electroanal. Chem. 522:2002;124.
17. A.M. Martínez, Doctoral Thesis, Valladolid, 1999.
18. Martínez A.M., Castrillejo Y., Barrado E., Haarberg G.M., Picard G.S. J. Electroanal. Chem. 449:1998;67.
19. Castrillejo Y., Martínez A.M., Bermejo M.R., Vega M.S., Haarberg G.M., Picard G.S. Gaune-Escard M. Advances in molten salts. From structural aspects to waste processing. 1999;78-92 Begell Housse, New York.
20. Y. Castrillejo, M.R. Bermejo, In: Report CIEMAT-University of Valladolid Agreement, 2000.
21. M.R. Bermejo, Y. Castrillejo, A. Martínez, E. Barrado, Proceeding of Global 2001. International Conference of the Fuel Cycle: from Research Solutions, Paris, France 2001.
22. Laitinen H.A., Ferguson W.B., Osteryoung R.R. J. Electrochem. Soc. 104:1957;516.
23. Castrillejo Y., Martínez A.M., Haarberg G.M., Børresen B., Osen K.S., Tunold R. Electrochim. Acta. 42:1997;1489.
24. G.S. Picard, Doctoral Thesis, Paris, 1973.
25. Tremillon B., Picard G.S. Anal. Chim. Acta. 82:1976;273.
26. J. Schenin-King, Doctoral Tesis, Paris, 1994.
27. Combes R., Tremillon B., de Andrade F., Lopes M., Ferreira H. Anal. Lett. 15:1982;1585.
28. International Critical Tables, Vol. III, Vapour Pressure Lowering, p. 292.
29. Picard G.S., Seon F., Tremillon B. J. Electroanal. Chem. 102:1979;65.
30. B. Trémillon, G. Picard, Proceedings of the First International Symposium on Molten Salt Chemistry and Technology, 1983.
31. Trémillon B. Reactions in Solution. An Applied Analytical Approach. 1997;Wiley, Chichester.
32. Lisy R., Combes R. J. Electroanal. Chem. 83:1977;287.
33. Druding L.F., Corbett J.D. J. Am. Chem. Soc. 83:1961;2462.
34. Feng L., Guo C., Tang D. J. Alloys Compounds. 234:1996;183.
35. Keneshea F.H. Jr., Cubicciotti D. J. Chem. Eng. Data. 6:1961;507.
36. Dworkin A.S., Brostein H.R., Bredig M.A. Discuss. Faraday Soc. 32:1962;188.
37. I. Wu, H. Zhu, Y. Sato, T. Yamamura, K. Sugimoto, in: C.L. Hussey, D.S. Newman, G. Mamantov, Y. Ito, (ed.), Molten Salts. Ninth International Symposium, Pennington, 1994, 504.
38. Bard A.J., Faulkner L.R. Electrochemical Methods. Fundamentals and Applications. 1980;Wiley, New York.
39. Delahay P. New Instrumental Methods in Electrochemistry. Theory, Instrumentation, and Applications to Analytical and Physical Chemistry. 1954;Interscience, New York.
40. Barin J., Knacke O. Thermochemical Properties of Inorganic Substances. 1973;Springer, Berlin.
41. K. Igarashi, T. Nijima, J. Mochinaga, Proceedings of the First International Symposium on Molten Salt Chemistry and Technology, 1983, K-203.
42. Roewer V.G., Emons H.H. Z. Anorg. Allg. Chem. 370:1969;128.
43. Y. Mottot, Doctoral Thesis, Paris, 1986.
44. Combes R., Levelut M.N., Trémillon B. J. Electroanal. Chem. 91:1978;125.
45. Schenin-King J., Picard G.S. Molten Salt Forum. 1-2:1993/94;13.
46. Novozhilov A.L., Devyatkin V.N., Pchlina E.I. Russ. J. Phys. Chem. 48:1974;31.
47. Minh N.Q., Welch B.J. Aust. J. Chem. 28:1975;965.
48. Van Norman J.D., Tivers R.J. J. Electrochem. Soc. 118:1971;258.
49. Van Norman J.D., Tivers R.J. Mamantov G. Molten Salts. Characterization and Analysis. 1969;509 Marcel Dekker, New York.
50. J. Schenin-King, Doctoral Thesis, Paris, 1994.
51. Lantelme F., Berghoute Y. J. Electrochem. Soc. 146:1999;4137.
52. Lesourd J., Plambeck J.A. Can. J. Chem. 47:1969;3387.
53. Roy J.J., Grantham L.G., McCoy L.R., Krueger C.L., Storvick T., Inoue T., Miyashiro H., Takahashi N. Mater. Sci. Forum. 547:1991;73.
54. Fusselman S.P., Roy J.J., Grimmett D.L., Grantham L.G., Krueger C.L., Nabelek C.R., Stovick T.S., Inoue T., Hijikata T., Kinoshita K., Sakamura Y., Uozumi K., Kawai T., Takahashi T. J. Electrohem. Soc. 146:1999;2573.
55. Inman D., Hills G.J., Young L., O'M. Brockis J. Ann. N.Y. Acad. Sci. 79:1960;803.
56. Hoshino Y., Plambeck J.A. Can. J. Chem. 48:1970;685.