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A template-free synthesis of macrocycles with planar coordinated phosphorus centers has been realized starting from 1,3,2-diazaphosphinines by a sequence of [4+2] cycloadditions/cycloreversions: N. Avarvari, N. Mezailles, L. Ricard, P. Le Floch, F. Mathey, Science 1998, 280, 1587-1589.
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17
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0013311590
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note
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2, 25°C): δ=386.2, 388.1 ppm (rac/meso-1a).
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18
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0013264356
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a) D. Jerchel, S. Noetzel, K. Thomas, Chem. Ber. 1960, 93, 2966-2970;
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20
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0013281234
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note
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[8] The ligand 5 retains the conformation of the ate-complex 3. S. Ekici, M. Nieger, E. Niecke, unpublished results.
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22
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0013213698
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note
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[9]
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23
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84943920736
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SHELXL-97
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2, the H-atoms were refined using a riding model (SHELXL-97). CCDC-181615 (2), CCDC-181616 (3), CCDC-190910 (6), and CCDC-190911 (7) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit @ccdc.cam.ac.uk). SHELXS-97: G. M. Sheldrick, Acta Crystallogr. Sect. A 1990, 46, 467-473 SHELXL-97: G. M. Sheldrick, Universität Göttingen, 1997.
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Sheldrick, G.M.1
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24
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0013309289
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Universität Göttingen
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2, the H-atoms were refined using a riding model (SHELXL-97). CCDC-181615 (2), CCDC-181616 (3), CCDC-190910 (6), and CCDC-190911 (7) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit @ccdc.cam.ac.uk). SHELXS-97: G. M. Sheldrick, Acta Crystallogr. Sect. A 1990, 46, 467-473 SHELXL-97: G. M. Sheldrick, Universität Göttingen, 1997.
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Sheldrick, G.M.1
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b) W. Clegg, S. Doherty, K. Izod, P. O'Shaughnessy, Chem. Commun. 1998, 1129-1130, and references therein.
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27
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Structures of lithium salts of heteroatom compounds
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F. Pauer, P. P. Power (Eds.: A.-M. Saspe, P. von Rague Schleyer), Wiley-Interscience, New York
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Melnik, M.1
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29
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0013213699
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personal communication
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1-complexes of diazapyridinophanes do not display geometries that are comparable to 6; H. J. Krüger, personal communication.
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Krüger, H.J.1
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31
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84987185025
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Läge, M.5
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32
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0013224976
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note
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6; reference electrode: calomel E=0.24 V; IR-compensation (kΩ) 3: 2.5; 5, 6: 0.2; 7: 4.5.
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