Polyoxovanadium(IV) sulfite compounds: Synthesis, structural, and physical studies

Angewandte Chemie - International Edition

Volumn 42, Issue 4, 2003, Pages 425-427

  Manos, Manolis J ^a   Miras, Haralampos N ^a   Tangoulis, Vassilis ^c   Woollins, J Derek ^b   Slawin, Alexandra M Z ^b   Kabanos, Themistoklis A ^a  

^a UNIVERSITY OF IOANNINA   (Greece)

^b UNIVERSITY OF ST ANDREWS   (United Kingdom)

^c UNIVERSITY OF PATRAS   (Greece)

Author keywords

Bridging ligands; Cluster compounds; Polyoxometalates; Sulfite ions; Vanadium

Indexed keywords

FERROMAGNETIC MATERIALS; NEGATIVE IONS; SYNTHESIS (CHEMICAL);

HETEROPOLYANIONS;

VANADIUM COMPOUNDS;

HYDROCHLORIC ACID; MAGNESIUM OXIDE; SODIUM SULFITE; TETRABUTYLAMMONIUM; VANADIUM DERIVATIVE; WATER;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; INFRARED SPECTROSCOPY; PH; ROOM TEMPERATURE; SYNTHESIS; TEMPERATURE DEPENDENCE; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

EID: 0037467929     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200390129     Document Type: Article

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31. abstract
32. a) Bond valence sum (BVS) calculations for compound 1: BVS calculations for O(5) and O(12) gave values of 1.24 and 0.47, respectively, while calculations for the crystallographically independent vanadium and sulfur ions gave values very close to 4. b) BVS calculations for compound 3: BVS calculations for O(7) and O(1) gave values of 0.23 and 1.2, respectively, while calculations for the crystallographically independent vanadium and sulfur ions gave values very close to 4 [I. D. Brown in Structure and Bonding in Crystals, Vol. II (Ed.: M. O'Keefe, A. Navrotdsky), Academic Press, New York, 1981, p. 1-30].
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