Synthesis, crystal structure, and magnetic properties of an alkoxo-hydroxo-bridged octanuclear copper(II) complex showing chemically significant hydrogen-bonding interactions involving a metallamacrocyclic core

Inorganic Chemistry

Volumn 42, Issue 2, 2003, Pages 463-468

  Mukherjee, Arindam ^a   Rudra, Indranil ^a   Nethaji, Munirathinam ^a   Ramasesha, Suryanarayanasastry ^a   Chakravarty, Akhil R ^a  

^a INDIAN INSTITUTE OF SCIENCE   (India)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER COMPLEX; COPPER ION; HYDROXIDE; LIGAND; METHANOL; N,N' (2 HYDROXYPROPANE 1,3 DIYL)BIS(SALICYLALDIMINE); PROPANE; SALICYLIC ACID DERIVATIVE; SCHIFF BASE; SODIUM HYDROXIDE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; COVALENT BOND; CRYSTAL STRUCTURE; CRYSTALLIZATION; CRYSTALLOGRAPHY; HYDROGEN BOND; MAGNETISM; SYNTHESIS; TEMPERATURE;

EID: 0037467774     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic020399n     Document Type: Article

References (48)

1. (a) Department of Inorganic & Physical Chemistry. E-mail: arc@ipc.iisc.ernet.in (for general correspondence).
2. (b) Solid State & Structural Chemistry Unit. E-mail: ramasesh@sscu.iisc.ernet.in (for correspondence related to the theoretical part of the magnetic studies).
3. Winpenny, R. E. P. Adv. Inorg. Chem. 2001, 52, 1.
4. (a) Kahn, O, Molecular Magnetism; VCH: Weinheim. Germany, 1993.
5. (b) Magneto-Structural Correlations in Exchange Coupled Systems; Willet, R. D., Gatteschi, D., Kahn, O., Eds.; Reidel Publishing Company: Dordrecht, The Netherlands, 1985.
6. (c) Magnetic Molecular Materials; Gatteschi, D., Kahn, O., Miller, J. S., Palacio, F., Eds.; NATO ASI Series E: Kluwer Academic Publishers: Dordrecht, The Netherlands, 1991; Vol. 194.
7. Lippard, S. J.; Berg, J. M. Principles of Bioinorganic Chemistry; University Science Books: Mill Valley, CA, 1995.
8. Wieghardt, K. Angew. Chem., Int. Ed. Engl. 1989, 28, 1153. Metal Clusters in Proteins: Que, L., Ed.; ACS Symposium Series 372; American Chemical Society: Washington, DC, 1988.
9. Wieghardt, K. Angew. Chem., Int. Ed. Engl. 1989, 28, 1153. Metal Clusters in Proteins: Que, L., Ed.; ACS Symposium Series 372; American Chemical Society: Washington, DC, 1988.
10. Saalfrank, R. W.; Uller, E.; Demleitner, B.; Bernt, I. Struct. Bonding (Berlin) 2000, 96, 149. Lei, X.; Wolf, E. E.; Fehlner; T. P. Eur. J. Inorg. Chem. 1998, 12, 1835. Alonso, J. A. Chem. Rev. 2000, 100, 637. Brechin, E. K.; Graham, A. M.; Paul, E. Y.; Murrie M.; Parsons, S.; Winpenny, R. E. P. Philos. Trans. R. Soc. London, Ser. A 1999, 357, 3119.
11. Saalfrank, R. W.; Uller, E.; Demleitner, B.; Bernt, I. Struct. Bonding (Berlin) 2000, 96, 149. Lei, X.; Wolf, E. E.; Fehlner; T. P. Eur. J. Inorg. Chem. 1998, 12, 1835. Alonso, J. A. Chem. Rev. 2000, 100, 637. Brechin, E. K.; Graham, A. M.; Paul, E. Y.; Murrie M.; Parsons, S.; Winpenny, R. E. P. Philos. Trans. R. Soc. London, Ser. A 1999, 357, 3119.
12. Saalfrank, R. W.; Uller, E.; Demleitner, B.; Bernt, I. Struct. Bonding (Berlin) 2000, 96, 149. Lei, X.; Wolf, E. E.; Fehlner; T. P. Eur. J. Inorg. Chem. 1998, 12, 1835. Alonso, J. A. Chem. Rev. 2000, 100, 637. Brechin, E. K.; Graham, A. M.; Paul, E. Y.; Murrie M.; Parsons, S.; Winpenny, R. E. P. Philos. Trans. R. Soc. London, Ser. A 1999, 357, 3119.
13. Saalfrank, R. W.; Uller, E.; Demleitner, B.; Bernt, I. Struct. Bonding (Berlin) 2000, 96, 149. Lei, X.; Wolf, E. E.; Fehlner; T. P. Eur. J. Inorg. Chem. 1998, 12, 1835. Alonso, J. A. Chem. Rev. 2000, 100, 637. Brechin, E. K.; Graham, A. M.; Paul, E. Y.; Murrie M.; Parsons, S.; Winpenny, R. E. P. Philos. Trans. R. Soc. London, Ser. A 1999, 357, 3119.
14. Lehn, J.-M. Supramolecular Chemistry-Concepts and Properties; VCH: Weinheim, Germany, 1995.
15. Comprehensive Supramolecular Chemistry; Atwood, J. L., Davies, J. E. D., Macnical, D. D., Vögtle, F., Eds.; Pergamon: Oxford, England, 1996; Vols. 1-3.
16. Lah, M. S.; Pecoraro, V. L. Comments Inorg. Chem. 1990, 11, 9. Gray, G. M. Comments Inorg. Chem. 1995, 17, 95. Pecoraro, V. L.; Stemmler, A. J.; Gibney, B. P.; Bodwin, J.; Kampf, J. W.; Wang, H. Prog. Inorg. Chem. 1996, 45, 83. Bodwin, J. J.; Cutland, A. D.; Malkani, R.; Pecoraro, V. L. Coord. Chem. Rev. 2001, 216, 489.
17. Lah, M. S.; Pecoraro, V. L. Comments Inorg. Chem. 1990, 11, 9. Gray, G. M. Comments Inorg. Chem. 1995, 17, 95. Pecoraro, V. L.; Stemmler, A. J.; Gibney, B. P.; Bodwin, J.; Kampf, J. W.; Wang, H. Prog. Inorg. Chem. 1996, 45, 83. Bodwin, J. J.; Cutland, A. D.; Malkani, R.; Pecoraro, V. L. Coord. Chem. Rev. 2001, 216, 489.
18. Lah, M. S.; Pecoraro, V. L. Comments Inorg. Chem. 1990, 11, 9. Gray, G. M. Comments Inorg. Chem. 1995, 17, 95. Pecoraro, V. L.; Stemmler, A. J.; Gibney, B. P.; Bodwin, J.; Kampf, J. W.; Wang, H. Prog. Inorg. Chem. 1996, 45, 83. Bodwin, J. J.; Cutland, A. D.; Malkani, R.; Pecoraro, V. L. Coord. Chem. Rev. 2001, 216, 489.
19. Lah, M. S.; Pecoraro, V. L. Comments Inorg. Chem. 1990, 11, 9. Gray, G. M. Comments Inorg. Chem. 1995, 17, 95. Pecoraro, V. L.; Stemmler, A. J.; Gibney, B. P.; Bodwin, J.; Kampf, J. W.; Wang, H. Prog. Inorg. Chem. 1996, 45, 83. Bodwin, J. J.; Cutland, A. D.; Malkani, R.; Pecoraro, V. L. Coord. Chem. Rev. 2001, 216, 489.
20. Makhankova, V. G.; Vassilyeva, O. Y.; Kokozay, V. N.; Skelton, B. W.; Reedijk, J.; Van Albado, G. A.; Sorace, L.; Gatteschi, D. New. J. Chem. 2001, 25, 685. Fredericks, J. R.; Hamilton, A. D. Compr. Supramol. Chem. 1996, 9, 565.
21. Makhankova, V. G.; Vassilyeva, O. Y.; Kokozay, V. N.; Skelton, B. W.; Reedijk, J.; Van Albado, G. A.; Sorace, L.; Gatteschi, D. New. J. Chem. 2001, 25, 685. Fredericks, J. R.; Hamilton, A. D. Compr. Supramol. Chem. 1996, 9, 565.
22. Geetha, K.; Nethaji, M.; Chakravarty, A. R. Inorg. Chem. 1997, 36, 6134.
23. Mazurek, W.; Kennedy, B. J.; Murray, K. S.; O'Connor, M. J.; Rodgers, J. R.; Snow, M. R.; Wedd, A. G.; Zwack, P. R. Inorg. Chem. 1985, 24, 3258.
24. Nishida, Y.; Kida, S. J. Chem. Soc., Dalton Trans. 1986, 2633.
25. Geetha, K.; Nethaji, M.; Vasanthacharya, N. Y.; Chakravarty, A. R. J. Coord. Chem. 1999, 47, 77. Bürger, K.-S.; Chaudhuri, P.; Wieghardt, K. J. Chem. Soc., Dalton Trans. 1996, 247.
26. Geetha, K.; Nethaji, M.; Vasanthacharya, N. Y.; Chakravarty, A. R. J. Coord. Chem. 1999, 47, 77. Bürger, K.-S.; Chaudhuri, P.; Wieghardt, K. J. Chem. Soc., Dalton Trans. 1996, 247.
27. Mazurek, W.; Berry, K. J.; Murray, K. S.; O'Connor, M. J.; Snow, M. R.; Wedd, A. G. Inorg. Chem. 1982, 21, 3071.
28. Kayatani, T.; Hayashi, Y.; Suzuki, M.; Inomata, K.; Uehera, A. Bull. Chem. Soc. Jpn. 1996, 69, 389.
29. (a) Blessing, R. Acta Crystallogr. Sect. A 1995, 51, 33.
30. (b) Sheldrick, G. M. SHELX-97. A Computer Program for Crystal Structure Solution and Refinement; Universität Göttingen: Göttingen, Germany, 1997.
31. Addison, A. W.; Rao, T. N.; Reedjik, J.; Vershcoor, G. C. J. Chem. Soc., Dalton. Trans. 1984, 1349.
32. Ardizzoia, A.; Angarconi, M. A.; LaMonica, G.; Cariati, F.; Cenini, S.; Moret, M.; Masciocchi, N. Inorg. Chem. 1991, 30, 4347.
33. Agostinelli, E.; Dell'Amico, D. B.; Calderazzo, F.; Fiorani, D.; Pelizzi, G. Gazz. Chim. Ital. 1988, 118, 729.
34. McKee, V.; Tandon, S. S. Inorg. Chem. 1989, 28, 2901.
35. Blake, A. J.; Grant, C. M.; Gregory, C. I.; Parsons, S.; Rawson, J. M.; Reed, D.; Winpenny, R. E. P. J. Chem. Soc., Dalton Trans. 1995, 163.
36. Tangoulis, V.; Passchalidou, S.; Bakalbassis, E. G.; Perlepes, S. P.; Raptopoulou, C. P.; Terzis, A. Chem. Commun. 1996, 129. Tangoulis, V.; Raptopoulou, C. P.; Terzis, A.; Passchalidou, S.; Perlepes, S. P.; Bakalbassis, E. G. Inorg. Chem. 1997, 36, 3996.
37. Tangoulis, V.; Passchalidou, S.; Bakalbassis, E. G.; Perlepes, S. P.; Raptopoulou, C. P.; Terzis, A. Chem. Commun. 1996, 129. Tangoulis, V.; Raptopoulou, C. P.; Terzis, A.; Passchalidou, S.; Perlepes, S. P.; Bakalbassis, E. G. Inorg. Chem. 1997, 36, 3996.
38. Zhang, Y.; Thompson, L. K.; Bridson, J. N.; Bubenik, M. Inorg. Chem. 1995, 34, 5870.
39. Rybak-Akimova, E. V.; Busch, D. H.; Kahol, P. K.; Pinto, N.; Aclock, N. W.; Clase, H. J. Inorg. Chem. 1997, 36, 510.
40. Zhu, F.; Schamelle, H. W.; Fischer, B.; Dubler, E. Inorg. Chem. 1998, 37, 1161.
41. Tong, M.-L.; Lee, H.-K.; Tong, Y.-X.; Cheng, X.-M.; Mak, T. C. W. Inorg. Chem. 2000, 39, 4666.
42. Xu, Z.; Thompson, L. K.; Miller, D. O. Chem. Commun. 2001, 13, 1170.
43. Wu, D.; Huang, J.; Lin, Y.; Huang, J. Sci. Sin. 1988, 31B, 800.
44. Wang, S.; Peng, Z.; Wagner, M. J. Inorg. Chem. 1992, 31, 5381.
45. Park, Y. J.; No, K.; Shin, J. M. Bull. Korean Chem. Soc. 1991, 12, 525.
46. Newkome, G. R.; Hu, Y.; Saunders, M. J. Tetrahedron Lett. 1991, 32, 1133.
47. Pati, S. K.; Ramasesha, S.; Sen, D. Magnetoscience-From Molecules to Materials; Miller, J., Drillon, M., Eds.; Wiley-VCH Verlag: Weinheim, Germany (in press).
48. Edmonds, A. R. Angular Momentum in Quantum Mechanics; Princeton University Press: Princeton, NJ, 1957.