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1
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0036073664
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Common examples of tripod nitrogen donors include neutral tris-(pyrazolyl) methane and tris(pyridyl)methane, monoanionic tris(pyrazolyl)hydroborato, and trianionic tris[(amido)methyl]ethane. See, for example: Gade, L. H. Acc. Chem. Res. 2002, 35, 575-582.
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Gade, L.H.1
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2
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0001361495
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x] classification of ligands, see: Green, M. L. H. J. Organomet. Chem. 1995, 500, 127-148.
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J. Organomet. Chem.
, vol.500
, pp. 127-148
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Green, M.L.H.1
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3
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0033798803
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For an example of a tetradentate tripodal ligand in which B-H is the axial donor, see: Bridgewater, B. M.; Parkin, G. Inorg. Chem. Commun. 2000, 3, 534-536.
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(2000)
Inorg. Chem. Commun.
, vol.3
, pp. 534-536
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Bridgewater, B.M.1
Parkin, G.2
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6
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0037051626
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Tetradentate tetraanionic ligands are also known. See: Kobayashi, J.; Goto, K.; Kawashima, T.; Schmidt, M. W.; Nagase, S. J. Am. Chem. Soc. 2002, 124, 3703-3712.
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J. Am. Chem. Soc.
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, pp. 3703-3712
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Kobayashi, J.1
Goto, K.2
Kawashima, T.3
Schmidt, M.W.4
Nagase, S.5
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11
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0000172894
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(a) Riley, P. N.; Parker, J. R.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1999, 18, 3579-3583.
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(1999)
Organometallics
, vol.18
, pp. 3579-3583
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Riley, P.N.1
Parker, J.R.2
Fanwick, P.E.3
Rothwell, I.P.4
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12
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0035924995
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(b) Riley, P. N.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 2001, 181-186.
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J. Chem. Soc., Dalton Trans.
, pp. 181-186
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Riley, P.N.1
Fanwick, P.E.2
Rothwell, I.P.3
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13
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0035937899
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(c) Harris, S. A.; Ciszewski, J. T.; Odom, A. L. Inorg. Chem. 2001, 40, 1987-1988.
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Inorg. Chem.
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, pp. 1987-1988
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Harris, S.A.1
Ciszewski, J.T.2
Odom, A.L.3
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15
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0012767085
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(e) Zhu, G.; Tanski, J. M.; Parkin, G. J. Chem. Crystallogr. 2002, 32, 461-467.
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J. Chem. Crystallogr.
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, pp. 461-467
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Zhu, G.1
Tanski, J.M.2
Parkin, G.3
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16
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77957048095
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Catalan, J.; Abboud, J. L. M.; Elguero, J. Adv. Heterocycl. Chem. 1987, 41, 187-274.
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(1987)
Adv. Heterocycl. Chem.
, vol.41
, pp. 187-274
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Catalan, J.1
Abboud, J.L.M.2
Elguero, J.3
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19
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0029937196
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(a) Freundlich, J. S.; Schrock, R. R.; Davies, W. M. J. Am. Chem. Soc. 1996, 118, 3643-3655.
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(1996)
J. Am. Chem. Soc.
, vol.118
, pp. 3643-3655
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Freundlich, J.S.1
Schrock, R.R.2
Davies, W.M.3
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20
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0000863654
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(b) Freundlich, J. S.; Schrock, R. R.; Davies, W. M. Organometallics 1996, 15, 2777-2783.
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(1996)
Organometallics
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Freundlich, J.S.1
Schrock, R.R.2
Davies, W.M.3
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22
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84987278671
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For a related example of the synthesis of a tris [(2-pyrrolyl)methyl]amine, see: Treibs, A.; Jacob, K. Liebigs Ann. Chem. 1970, 737, 176-178.
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(1970)
Liebigs Ann. Chem.
, vol.737
, pp. 176-178
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Treibs, A.1
Jacob, K.2
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23
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0012835188
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note
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See Supporting Information.
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24
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0000927088
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(a) Thompson, L. K.; Ramaswamy, B. S.; Seymour, E. A. Can. J. Chem. 1977, 55, 878-888.
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(1977)
Can. J. Chem.
, vol.55
, pp. 878-888
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Thompson, L.K.1
Ramaswamy, B.S.2
Seymour, E.A.3
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25
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0000646229
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(b) Oki, A. R.; Bommarreddy, P. R.; Zhang, H.; Hosmane, N. Inorg. Chim. Acta 1995, 231, 109-114.
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(1995)
Inorg. Chim. Acta
, vol.231
, pp. 109-114
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Oki, A.R.1
Bommarreddy, P.R.2
Zhang, H.3
Hosmane, N.4
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26
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0034675606
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(c) Su, C.-H.; Kang, B.-S.; Du, C.-X.; Yang, Q.-C.; Mak, T. C. W. Inorg. Chem. 2000, 39, 4843-4849.
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Inorg. Chem.
, vol.39
, pp. 4843-4849
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Su, C.-H.1
Kang, B.-S.2
Du, C.-X.3
Yang, Q.-C.4
Mak, T.C.W.5
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27
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37049094335
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Reference 17c
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3, are also known. See, for example: (a) Reference 17c. Hendriks, H. M. J.; Birker, P.; Verschoor, G. C.; Reedijk, J. J. Chem. Soc., Dalton Trans. 1982, 623-631.
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28
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37049094335
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3, are also known. See, for example: (a) Reference 17c. Hendriks, H. M. J.; Birker, P.; Verschoor, G. C.; Reedijk, J. J. Chem. Soc., Dalton Trans. 1982, 623-631.
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(1982)
J. Chem. Soc., Dalton Trans.
, pp. 623-631
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Hendriks, H.M.J.1
Birker, P.2
Verschoor, G.C.3
Reedijk, J.4
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29
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0037170849
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+; the deprotonated nitrogen atoms are, however, readily reprotonated, thereby indicating the non-innocent nature of the deprotonated ligand. See: Hammes, B. S.; Kieber-Emmons, M. T.; Sommer, R.; Rheingold, A. L. Inorg. Chem. 2002, 41, 1351-1353.
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Inorg. Chem.
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, pp. 1351-1353
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Hammes, B.S.1
Kieber-Emmons, M.T.2
Sommer, R.3
Rheingold, A.L.4
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30
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0012765120
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note
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3 derivatives of the groups 4 and 5 transition metals listed in the Cambridge Structural Database (Version 5.23).
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31
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0031571444
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Hermann, W. A.; Baratta, W.; Herdtweck, E. J. Organomet. Chem. 1997, 541, 445-460.
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J. Organomet. Chem.
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, pp. 445-460
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Hermann, W.A.1
Baratta, W.2
Herdtweck, E.3
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32
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0012775370
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note
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1H NMR spectroscopy.
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34
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0040908165
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Reference 21
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c (a) Reference 21. (b) Chesnut, R. W.; Fanwick, P. E.; Rothwell, I. P. Inorg. Chem. 1988, 27, 752-754. (c) Pugh, S. M.; Trösch, D. J. M.; Skinner, M. E. G.; Gade, L. H.; Mountford, P. Organometallics 2001, 20, 3531-3542.
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35
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0040908165
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c (a) Reference 21. (b) Chesnut, R. W.; Fanwick, P. E.; Rothwell,. I. P. Inorg. Chem. 1988, 27, 752-754. (c) Pugh, S. M.; Trösch, D. J. M.; Skinner, M. E. G.; Gade, L. H.; Mountford, P. Organometallics 2001, 20, 3531-3542.
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(1988)
Inorg. Chem.
, vol.27
, pp. 752-754
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Chesnut, R.W.1
Fanwick, P.E.2
Rothwell, I.P.3
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36
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0035817651
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c (a) Reference 21. (b) Chesnut, R. W.; Fanwick, P. E.; Rothwell, I. P. Inorg. Chem. 1988, 27, 752-754. (c) Pugh, S. M.; Trösch, D. J. M.; Skinner, M. E. G.; Gade, L. H.; Mountford, P. Organometallics 2001, 20, 3531-3542.
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Organometallics
, vol.20
, pp. 3531-3542
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Pugh, S.M.1
Trösch, D.J.M.2
Skinner, M.E.G.3
Gade, L.H.4
Mountford, P.5
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38
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0012824520
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note
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2)I has also been structurally characterized.
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