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Volumn 42, Issue 2, 2003, Pages 264-266

Tantalum amido and imido complexes supported by tris[(2-indolyl)methyl]amine, a tetradentate trianionic ligand with reduced π-donor character

Author keywords

[No Author keywords available]

Indexed keywords

2 BROMOMETHYL 1 INDOLECARBOXYLATE; AMIDE; CARBOXYLIC ACID DERIVATIVE; IMIDE; INDOLE DERIVATIVE; LIGAND; METHYLAMINE; NITROGEN; TANTALUM; TRIS[(2 INDOLYL)METHYL]AMINE; UNCLASSIFIED DRUG;

EID: 0037467768     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic026182a     Document Type: Article
Times cited : (28)

References (38)
  • 1
    • 0036073664 scopus 로고    scopus 로고
    • Common examples of tripod nitrogen donors include neutral tris-(pyrazolyl) methane and tris(pyridyl)methane, monoanionic tris(pyrazolyl)hydroborato, and trianionic tris[(amido)methyl]ethane. See, for example: Gade, L. H. Acc. Chem. Res. 2002, 35, 575-582.
    • (2002) Acc. Chem. Res. , vol.35 , pp. 575-582
    • Gade, L.H.1
  • 2
  • 3
    • 0033798803 scopus 로고    scopus 로고
    • For an example of a tetradentate tripodal ligand in which B-H is the axial donor, see: Bridgewater, B. M.; Parkin, G. Inorg. Chem. Commun. 2000, 3, 534-536.
    • (2000) Inorg. Chem. Commun. , vol.3 , pp. 534-536
    • Bridgewater, B.M.1    Parkin, G.2
  • 22
    • 84987278671 scopus 로고
    • For a related example of the synthesis of a tris [(2-pyrrolyl)methyl]amine, see: Treibs, A.; Jacob, K. Liebigs Ann. Chem. 1970, 737, 176-178.
    • (1970) Liebigs Ann. Chem. , vol.737 , pp. 176-178
    • Treibs, A.1    Jacob, K.2
  • 23
    • 0012835188 scopus 로고    scopus 로고
    • note
    • See Supporting Information.
  • 27
    • 37049094335 scopus 로고    scopus 로고
    • Reference 17c
    • 3, are also known. See, for example: (a) Reference 17c. Hendriks, H. M. J.; Birker, P.; Verschoor, G. C.; Reedijk, J. J. Chem. Soc., Dalton Trans. 1982, 623-631.
  • 29
    • 0037170849 scopus 로고    scopus 로고
    • +; the deprotonated nitrogen atoms are, however, readily reprotonated, thereby indicating the non-innocent nature of the deprotonated ligand. See: Hammes, B. S.; Kieber-Emmons, M. T.; Sommer, R.; Rheingold, A. L. Inorg. Chem. 2002, 41, 1351-1353.
    • (2002) Inorg. Chem. , vol.41 , pp. 1351-1353
    • Hammes, B.S.1    Kieber-Emmons, M.T.2    Sommer, R.3    Rheingold, A.L.4
  • 30
    • 0012765120 scopus 로고    scopus 로고
    • note
    • 3 derivatives of the groups 4 and 5 transition metals listed in the Cambridge Structural Database (Version 5.23).
  • 32
    • 0012775370 scopus 로고    scopus 로고
    • note
    • 1H NMR spectroscopy.
  • 34
    • 0040908165 scopus 로고    scopus 로고
    • Reference 21
    • c (a) Reference 21. (b) Chesnut, R. W.; Fanwick, P. E.; Rothwell, I. P. Inorg. Chem. 1988, 27, 752-754. (c) Pugh, S. M.; Trösch, D. J. M.; Skinner, M. E. G.; Gade, L. H.; Mountford, P. Organometallics 2001, 20, 3531-3542.
  • 35
    • 0040908165 scopus 로고    scopus 로고
    • c (a) Reference 21. (b) Chesnut, R. W.; Fanwick, P. E.; Rothwell,. I. P. Inorg. Chem. 1988, 27, 752-754. (c) Pugh, S. M.; Trösch, D. J. M.; Skinner, M. E. G.; Gade, L. H.; Mountford, P. Organometallics 2001, 20, 3531-3542.
    • (1988) Inorg. Chem. , vol.27 , pp. 752-754
    • Chesnut, R.W.1    Fanwick, P.E.2    Rothwell, I.P.3
  • 38
    • 0012824520 scopus 로고    scopus 로고
    • note
    • 2)I has also been structurally characterized.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.