Detection of sugar syrups in apple juice by δ2H‰ and δ13C‰ analysis of hexamethylenetetramine prepared from fructose

Journal of Agricultural and Food Chemistry

Volumn 51, Issue 7, 2003, Pages 1801-1806

  Kelly, Simon D ^a   Rhodes, Christopher ^b   Lofthouse, Janice H ^b   Anderson, Dominic ^b   Burwood, Christine E ^b   Dennis, M John ^b   Brereton, Paul ^b  

^a UNIVERSITY OF EAST ANGLIA   (United Kingdom)

^b CENTRAL SCIENCE LABORATORY   (United Kingdom)

Author keywords

Apple juice; Authenticity; GC IRMS; Hydrogen isotope; Pyrolysis

Indexed keywords

CARBON 13; DEUTERIUM; FRUCTOSE; ISOTOPE; METHENAMINE; SUGAR;

APPLE JUICE; ARTICLE; DEGRADATION; FOOD ANALYSIS; FOOD COMPOSITION; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; SYRUP;

BEVERAGES; CARBOHYDRATES; CARBON ISOTOPES; DEUTERIUM; FRUCTOSE; FRUIT; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; MALUS; METHENAMINE; SENSITIVITY AND SPECIFICITY;

ARUNDINARIA; BETA VULGARIS SUBSP. VULGARIS; MALUS X DOMESTICA;

EID: 0037467470     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf021044p     Document Type: Article

References (25)

1. Doner, L.; Krueger H.; Reesman, R. Isotopic composition of carbon in apple juice. J. Agric. Food Chem. 1980, 28, 362-364.
2. 12C determinations to detect high fructose com syrup in orange juice - Collaborative Study. J. Assoc. Off Anal. Chem. 1982, 65, 608-610.
3. 12C ratios. J. Sci. Food Agric. 1982, 33, 898-903.
4. 12C) of Scotch whisky congeners to establish brand authenticity using gas chromatography combustion-isotope ratio mass spectrometry. Food Chem. 1998, 63, 423-428.
5. White, J.; Winters, K.; Martin, P. Stable carbon isotope ratio analysis of honey: Validation of internal standard procedure for worldwide application. J. Assoc. Off. Anal. Chem. 1998, 81, 610-619.
6. Bricout, J.; Fontes, J.-C.; Merlivat, L. Detection of synthetic vanillin in vanilla extracts by isotopic analysis. J. Assoc. Off. Anal. Chem. 1974, 57, 713-715.
7. Martin, G. J.; Li Zhang, B.; Naulet, N.; Martin, M. L. Deuterium transfer in the bioconversion of glucose to ethanol studied by specific isotope labeling at the natural abundance level, J. Am. Chem. Soc. 1986, 108, 5116-5122.
8. Martin, G. J.; Martin. M. L. The site-specific natural isotope fractionation-NMR method applied to the study of wines. In Modern Methods in Plant Analysis; Linskens, H. F., Jackson J. F., Eds.; Springer-Verlag: Berlin, 1988; Vol 6, 258-266.
9. Martin, M. L.; Martin, G. J.; Guillou, C. A site-specific and multielement isotopic approach to origin inference of sugars in foods and beverages. Mikro Acta 1991, 2, 81-91.
10. Martin, G. J. SNIF-NMR, a new method to detect added beet sugar to fruit juices and characterize their authenticity. Fruit Process. 1992, 8, 123-128.
11. Remaud, R.; Denon, A. A.; Martin, Y.-L.; Martin, G. G.; Martin, G. J. 1997, Authentication of bitter almond oil and cinnamon oil: Application of the SNIF-NMR method to benzaldehyde. J. Agric Food Chem. 1997, 45, 4042-4048.
12. 1H ratios of the carbon bound hydrogen-atoms in sugars. Fressenius' J. Anal. Chem. 1984, 317, 853-857.
13. 16O analysis of sucrose. J. Agric. Food Chem. 1987, 35, 610-612.
14. Rossmann, A.; Rieth, W.; Schmidt, H.-L. Possibilities and results of the combination of hydrogen and carbon stable isotope ratio determination with results of conventional analyses (RSK-values) for the proof of sugar addition to fruit juices. Z. Lebensm. Unters. Forsch. 1990, 191, 259-264.
15. Krueger, D. Detection of added sugar to fruit juices using carbon and hydrogen stable isotope analysis. In Methods to Detect Adulteration of Fruit Juice Beverages; Nagy, S., Wade, R., Eds.; AGScience, Inc: Auburndale, Florida, 1995; pp 41-51.
16. 1H isotope ratios in organic and water samples using an elemental analyser coupled to an isotope ratio mass spectrometer. J. Mass Spectrom. 1998, 33, 735-738.
17. 18O measurement for water and volatile organic compounds by continuous flow pyrolysis isotope ratio mass spectrometry. Anal. Chem. 1997, 69, 1530-1535.
18. 2O by continuous-flow isotope ratio mass spectrometry. Anal. Chem. 1995, 67, 1992-1997.
19. Smith, G.; Duke, F. Cerate and periodate oxidimetry: perchlorato-cerate and periodate ions as oxidants in the determination of organic compounds. Ind. Eng. Chem., Anal. Ed. 1943, 15, 120-122.
20. Bigeliesen, J. Science 1965, 147, 463-471.
21. Caimi, R.; Brenna, J. Quantitative evaluation of carbon isotopic fractionation during reversed-phase high-performance liquid chromatography. J. Chromatogr. A. 1997, 757, 307-310.
22. Hilkert, A. W.; Douthitt, C. B.; Schlöter, H. J.; Brand, W. A. Isotope Ratio Monitoring Gas Chromatography Mass Spectrometry of D/H by High-Temperature Conversion Isotope Ratio Mass Spectrometry. Rapid Commun. Mass Spec. 1999, 13, 1226-1230.
23. Bricout, J.; Koziet, J. Control of the authenticity of orange juice by isotopic analysis. J. Agric. Food Chem. 1987, 35, 758-760.
24. Jackson, E. Org. React. 1944, 2, 341-375.
25. Schmidt, H.-L.: Rossmann, A.; Butzenlechner, A. M. Evidence for nonstatistical carbon isotope distribution in glucose. Plant Physiol. 1991, 96, 609-614.