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As a control, reference samples were prepared by mechanical mixture of gold particles and the respective mesoporous silicate. A calculated amount of gold solution (containing nanoparticles of 2, 5, and 20 nm) was mixed with the silicate. After being stirred for 30 min, the mechanical mixture was dried and powdered. TEM pictures showed agglomerated particles definitely on the outer surface, providing further indirect evidence that the synthetic insertion of the nanoparticles leads to embedded particles.
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