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Volumn 42, Issue 6, 2003, Pages 1884-1894

Kinetics of oxygen exchange between the two isomers of bisulfite ion, disulfite ion (S2O52-), and water as studied by oxygen-17 nuclear magnetic resonance spectroscopy

Author keywords

[No Author keywords available]

Indexed keywords

BISULFITE; DISULFIDE; OXYGEN 17; WATER;

EID: 0037464268     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic020692n     Document Type: Article
Times cited : (29)

References (56)
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    • (private communication) has performed additional Raman measurements that confirm the identification of the two bisulfite isomers
    • (b) D. Littlejohn (private communication) has performed additional Raman measurements that confirm the identification of the two bisulfite isomers.
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    • note
    • 2)c vs [S(IV)] data at 274 K may be found in the Supporting Information.
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    • note
    • Details may be found in the Supporting Information.
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    • note
    • See Figure 6S in the Supporting Information for (1/T1)A data.
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    • note
    • Q1 = Q2(1 + Q4).
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    • Private communication
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    • (2002)
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    • note
    • i, but it is a good approximation because the chemical shifts of the S(IV) peaks relative to water were large in comparison to changes in the position of the water peak.
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    • note
    • 17O Larmor frequency of 24.4 MHz. It accepted 20 mm (outside diameter) sample tubes.
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    • note
    • This experiment was done on the Bruker NMR spectrometer described in the Experimental Section.
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    • note
    • 2- resonance was observed at 210 ppm.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.