A novel pathway for the synthesis of a carboxylic acid-functionalised Ru(II) terpyridine complex

Tetrahedron Letters

Volumn 44, Issue 9, 2003, Pages 1767-1770

  Husson, Jérôme ^a   Beley, Marc ^a   Kirsch, Gilbert ^a  

^a UNIVERSITÉ DE LORRAINE   (France)

Author keywords

Carboxylic acid; Complex; Furan; Photosensitiser; Ruthenium; Terpyridine

Indexed keywords

CARBOXYLIC ACID; FURAN; LIGAND; RUTHENIUM COMPLEX;

ARTICLE; CHELATION; COMPLEX FORMATION; HYDROLYSIS; OXIDATION; PHYSICAL CHEMISTRY; POLYMERIZATION; PROTECTION; PURIFICATION; SYNTHESIS;

EID: 0037463468     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(03)00123-0     Document Type: Article

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3. (a) Fallahpour, R. Synthesis 2000, 8, 1138-1143. For other synthesis of terpyridine esters see: (b) El-ghayoury, A.; Ziessel, R. J. Org. Chem. 2000, 65, 7757-7763; (c) Ulrich, G.; Bedel, S.; Picard, C.; Tisnès, P. Tetrahedron Lett. 2001, 42, 6113-6115; (d) Heller, M.; Schubert, U. S. Synlett 2002, 5, 751-754.
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10. 2+.
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12. 2+.
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14. 2+.
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16. 2+.
17. 3CN is removed and the resulting precipitate filtered, washed with water and diethyl ether. Purification of the crude product by column chromatography afforded 1 (28 mg, 64%).