Torsional relaxation and friction on the nanometer length scale: Comparison of small-molecule rotation in poly(dimethylsiloxane) and poly(isobutylene)

Macromolecules

Volumn 36, Issue 8, 2003, Pages 2721-2732

  Somoza, Mark M ^a   Sluch, Mikhail I ^a   Berg, Mark A ^a  

^a UNIVERSITY OF SOUTH CAROLINA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

SMALL-MOLECULE ROTATION;

CONFORMATIONS; FRICTION; NANOSTRUCTURED MATERIALS; OLIGOMERS; TORSION TESTING; VISCOSITY;

SILICONES;

EID: 0037461417     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma021181n     Document Type: Article

References (68)

1. Fleming, G. R. Chemical Applications of Ultrafast Spectrescopy; Oxford University Press: Oxford, 1986.
2. Alms, G. R.; Bauer, D. R.; Brauman, J. I.; Pecora, R. J. Chem. Phys. 1973, 58, 5570.
3. Crank, J., Park, G. S., Eds. Diffusion in Polymers; Academic Press: London, 1968.
4. Vieth, W. R. Diffusion in and Through Polymers; Hanser Publishers: Munich, 1991.
5. Ferry, J. D.; Landel, R. F.; Williams, M. L. J. Appl. Phys. 1955, 26, 359.
6. Ferry, J. D. Viscoelastic Properties of Polymers, 3rd ed.; John Wiley & Sons: New York, 1980.
7. Sluch, M. I.; Somoza, M. M.; Berg, M. A. J. Phys. Chem. B 2002, 106, 7385.
8. Parameter values quoted in this paper are derived from the procedures defined here and may vary slightly from the parametrization in ref 7.
9. Bahar, I.; Zuniga, I.; Dodge, R.; Mattice, W. L. Macromolecules 1991, 24, 2986.
10. Vacatello, M.; Yoon, D. Y. Macromolecules 1992, 25, 2502.
11. Fetters, L. J.; Lohse, D. J.; Richter, D.; Witten, T. A.; Zirkel, A. Macromolecules 1994, 27, 4639.
12. Fox, T. G.; Flory, P. J. J. Phys. Chem. 1951, 55, 221.
13. Arbe, A.; Monkenbusch, M.; Stellbrink, J.; Richter, D.; Farago, B.; Almdal, K.; Faust, R. Macromolecules 2001, 34, 1281.
14. Boyd, R. H.; Breitling, S. M. Macromolecules 1972, 5, 1.
15. Grigoras, S.; Lane, T. H. In Silicon-Based Polymer Science; Ziegler, J. M., Feardon, F. W. G., Eds.; American Chemical Society: Washington, DC, 1990; Vol. 224, p 801.
16. Sun, H.; Rigby, D. Spectrochim. Acta A 1997, 53, 1301.
17. Somoza, M. M.; Sluch, M. I.; Berg, M. A. In Femtochemistry and Femtobiology: Ultrafast Dynamics in Molecular Science; Douhal, A., Santamaria, J., Eds.; World Scientific Publishing: Singapore, 2002; pp 289-297.
18. Ediger, M. D. Annu. Rev. Phys. Chem. 1991, 42, 225.
19. Gisser, D. J.; Johnson, B. S.; Ediger, M. D.; von Meerwell, E. D. Macromolecules 1993, 26, 512.
20. Johnson, B. S.; Ediger, M. D.; Yamaguchi, Y.; Matsushita, Y.; Noda, I. Polymer 1992, 33, 3916.
21. Sillescu, H. J. Non-Cryst. Solids 1999, 243, 81.
22. Hall, D. B.; Miller, R. D.; Torkelson, J. M. J. Polym. Sci., Part B: Polym. Phys. 1997, 35, 2795.
23. Chapter 12, section B5 of ref 6.
24. Stein, A. D.; Hoffmann, D. A.; Marcus, A. H.; Leezenberg, P. B.; Frank, C. W.; Fayer, M. D. J. Phys. Chem. 1992, 96, 5255.
25. Diachun, N. A.; Marcus, A. H.; Hussey, D. M.; Fayer, M. D. J. Am. Chem. Soc. 1994, 116, 1027.
26. Niemeyer, E. D.; Bright, F. V. Macromolecules 1998, 31, 77.
27. Richter, D.; Arbe, A.; Colmenero, J.; Monkenbusch, M.; Farago, B.; Faust, R. Macromolecules 1998, 31, 1133.
28. Richter, D.; Monkenbusch, M.; Allgeier, J.; Arbe, A.; Colmenero, J.; Farago, B.; Bae, Y. C.; Faust, R. J. Chem. Phys. 1999, 111, 6107.
29. Richter, D.; Monkenbusch, M.; Pykhout-Hintzen, W.; Arbe, A.; Colmenero, J. J. Chem. Phys. 2000, 113, 11398.
30. Harnau, L. J. Chem. Phys. 2000, 113, 11396.
31. Kuhn, W.; Kuhn, H. Helv. Chim. Acta 1945, 28, 1533.
32. Allegra, G.; Ganazzoli, F. Macromolecules 1981, 14, 1110.
33. Ben-Amotz, D.; Drake, J. M. J. Chem. Phys. 1988, 89, 1019.
34. Williams, A. M.; Jiang, Y.; Ben-Amotz, D. Chem. Phys. 1994, 180, 119.
35. Zhang, Y.; Jiang, J.; Berg, M. A. J. Chem. Phys., in press.
36. Zhang, Y.; Sluch, M. I.; Somoza, M. M.; Berg, M. A. J. Chem. Phys. 2001, 115, 4212.
37. Richert, R., Blumen, A., Eds. Disorder Effects on Relaxational Processes: Glasses, Polymers, Proteins; Springer: Berlin, 1994.
38. Abramowitz, M., Stegun, I. A., Eds. Handbook of Mathematical Functions; Dover Publications: New York, 1965.
39. Benzler, J.; Luther, K. Chem. Phys. Lett. 1997, 279, 333.
40. Hyde, P. D.; Ediger, M. D. J. Chem. Phys. 1990, 92, 1036.
41. Berry, G. C.; Fox, T. G. Adv. Polym. Sci. 1968, 5, 261.
42. Silicon, Germanium, Tin and Lead Compounds Metal Alkoxides Metal Diketonates Silicones; Gelest: Tullytown, PA, 2000.
43. Alvari, D. S.; Harman, R. S.; Waldeck, D. H. J. Chem. Phys. 1990, 92, 4055.
44. Holtom, G. R. In Time-Resolved Laser Spectroscopy in Biochemistry II; Lakowicz, J. R., Ed.; SPIE: Bellingham, WA, 1990; Vol. 1204, pp 2-12.
45. Birch, D. S.; Imhof, R. E. In Topics in Fluorescence Spectroscopy; Lakowicz, J. R., Ed.; Plenum Press: New York, 1991; Vol. 1, pp 1-95.
46. Small, E. W. In Topics in Fluorescence Spectroscopy; Lakowicz, J. R., Ed.; Plenum Press: New York, 1991; Vol. 1, pp 97182.
47. Brandrup, J., Immergut, E. H., Eds. Polymer Handbook, 3rd ed.; John Wiley and Sons: New York, 1989.
48. Smith, G. D.; Jaffe, R. L. J. Phys. Chem. 1996, 100, 18718.
49. Wong, C.-P.; Schrag, J. L.; Ferry, J. D. J. Polym. Sci., Part A 1970, 8, 991.
50. Zwanzig, R.; Harrison, A. K. J. Chem. Phys. 1985, 83, 5861.
51. Doi, M.; Edwards, S. F. The Theory of Polymer Dynamics; Clarendon Press: Oxford, 1986.
52. Flory, P. J. Statistical Mechanics of Chain Molecules; Hanser Publishers: Munich, 1989.
53. Philips, L. A.; Webb, S. P.; Clark, J. H. J. Chem. Phys. 1985, 83, 5810.
54. Lee, M.; Bain, A. J.; McCarthy, P. J.; Han, C. H.; Haseltine, J. N.; Smith, A, B., III; Hochstrasser, R. M. J. Chem. Phys. 1986, 85, 4341.
55. Courtney, S. H.; Kim, S. K.; Canonica, S.; Fleming, G. R. J. Chem. Soc., Faraday Trans. 2 1986, 82, 2065.
56. Ben-Amotz, D.; Scott, T. W. J. Chem. Phys. 1987, 87, 3739.
57. Kim, S. K.; Fleming, G. R. J. Phys. Chem. 1988, 92, 2168.
58. Bowman, R. M.; Eisenthal, K. B. Chem. Phys. Lett. 1989, 155, 99.
59. Schroeder, J.; Schwarzer, D.; Troe, J. Ber. Bunsen-Ges. Phys. Chem. Chem. Phys. 1990, 94, 1249.
60. Roy, M.; Doraiswamy, S. J. Chem. Phys. 1993, 98, 3213.
61. Jiang, Y.; Blanchard, G. J. J. Phys. Chem. 1994, 98, 6436.
62. Jiang, Y.; Blanchard, G. J. J. Phys. Chem. 1995, 99, 7904.
63. De Backer, S.; Dutt, G. B.; Ameloot, M.; DeSchryver, F. C.; Müllen, K.; Holtrup, F. J. Phys. Chem. 1998, 100, 512.
64. Pauls, S. W.; Hedstrom, J. F.; Johnson, C. K. Chem. Phys. 1998, 237, 205.
65. Singh, M. K. Photochem. Photobiol. 2000, 72, 438.
66. Krushev, S.; Paul, W.; Smith, G. D. Macromolecules 2002, 35, 4198.
67. Chu, D. Y.; Thomas, J. K. J. Phys. Chem. 1989, 93, 6250.
68. Chu, D. Y.; Thomas, J. K. Macromolecules 1990, 23, 2217.