Investigation of the influence of H2S on hydrodesulfurization of dibenzothiophene over a bulk MoS2 catalyst

Industrial and Engineering Chemistry Research

Volumn 42, Issue 2, 2003, Pages 306-310

  Farag, Hamdy ^b   Sakanishi, Kinya ^a   Kouzu, Masatou ^a   Matsumura, Akimitsu ^a   Sugimoto, Yoshikazu ^a   Saito, Ikuo ^a  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^b Mansoura University   (Egypt)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; DESULFURIZATION; HYDROGEN SULFIDE; HYDROGENATION; MOLYBDENUM; PYROLYSIS; THERMAL EFFECTS;

MICROAUTOCLAVE REACTOR;

CATALYSTS;

DIBENZOTHIOPHENE DERIVATIVE; HYDROGEN SULFIDE; MOLYBDENUM;

AMMONIUM COMPOUND; CATALYST; DECOMPOSITION; DESULFURIZATION;

ARTICLE; AUTOCLAVE; CATALYST; CHEMICAL MODIFICATION; CHEMICAL REACTION KINETICS; DECOMPOSITION; HYDROGENATION; MAGNETISM; REACTION ANALYSIS; REACTOR; SYNTHESIS; THERMAL ANALYSIS;

EID: 0037460226     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie020404v     Document Type: Article

References (21)

1. Topsoe, H.; Clausen, B. S.; Massoth, F. E. Hydrotreating catalysis; Springer-Verlag: Berlin, 1996.
2. Yazu, K.; Yamamoto, Y.; Furuya, T.; Miki, K.; Ukegawa, K. Oxidation of dibenzothiophene in an organic biphasis system and its application to oxidative desulfurization of light oil. Energy Fuels 2001, 15, 1535.
3. Aida, T.; Yamamoto, D.; Iwata, M.; Sakata, K. Development of oxidative desulfurization process for diesel fuel. Reviews on Heteroatom Chemistry; MYUKK: Tokyo, 2000; Vol. 22, p 241.
4. Nishioka, M.; Campbell, R. M.; Lee, M. L.; Castle, R. N. Isolation of Sulfur Heterocycles from Petroleum and Coal-Derived Materials by Ligand Exchange Chromatography. Fuel 1986, 65, 270.
5. Sakanishi, K.; Ando, M.; Abe, S.; Mochida, I. Extensive Desulfurization of Diesel Fuel through Catalytic Two-Stage Hydrotreatment. Sekiyu Gakkaishi 1991, 34, 553.
6. Sakanishi, K.; Ando, M.; Mochida, I. Extensive Desulfurization of Diesel Fuel through Catalytic Two-Stage Hydrotreatment (Part 2). Sekiyu Gakkaishi 1992, 35, 403.
7. Ma, X.; Sakanishi, K.; Mochida, I. Three-Stage Deep Hydrodesulfurization of Diesel Fuel with CoMo and NiMo Catalysts at Relatively Low Pressure. Fuel 1994, 73, 1667.
8. 3 catalysts. Catal. Today 1998, 45, 347.
9. 2S on HDS of DBT and 4,6-DMDBT on alumina supported NiMo and NiW catalysts. Appl. Catal. A 2001, 209, 237.
10. Sie, S. T. Reaction order and role of hydrogen sulfide in deep HDS of gas oils: consequences for industrial reactor configuration. Fuel Process. Technol. 1999, 61, 149.
11. 2S partial pressure effect. Appl. Catal. A 1998, 170, 195.
12. Laredo, G. C.; De los Reyes, J. A.; Cano, J. L.; Castillo, J. J. Inhibiting effect of nitrogen compounds on the hydrodesulfurization of dibenzothiophene. Appl. Catal. A 2001, 207 (1-2), 103.
13. 2S and aromatic effects on HDS of dibenzothiophene over CoMo/C catalyst. Chemistry of diesel fuel; Taylor & Francis: New York, 2000; pp 123-137.
14. Farag, H.; Mochida, I.; Sakanishi, K. Fundamental comparison studies on hydrodesulfurization of dibenzothiophenes over CoMo based carbon and alumina catalysts. Appl. Catal. A 2000, 194, 147.
15. Hermann, N.; Brorson, M.; Topsoe, H. Activities of unsupported second transition series metal sulfides for hydrodesulfurization of sterically hindered 4,6-dimethyldibenzothiophene and of unsubstituted dibenzothiophene. Catal. Lett. 2000, 65, 169.
16. Schulz, H.; Bohringer, W.; Ousmanov, F.; Waller, P. Refractory sulfur compounds in gas oils. Fuel Process. Technol. 1999, 61, 5.
17. Topsoe, H.; Knudsen, K. G.; Byskov, L. S.; Norskov, J. K.; Clausen, B. S. Advances in deep desulfurization. Stud. Surf. Sci. Catal. 1999, 121, 13.
18. Vrinat, M.; Gachet, C. G.; Cavalletto, G.; De Mourgues, L. Influence of Hydrogen Sulfide on the Hydrodesulfurization of Dibenzothiophene on a Sulfided Cobalt-Molybdenum/Alumina Catalyst. Appl. Catal. 1982, 3, 57.
19. 2S in hydrodesulfurization of 4,6-dimethyldibenzothiophene over CoMo based carbon catalysts. Energy Fuels 1999, 13, 449.
20. 3. Catal. Today 1997, 35 (1-2), 59.
21. Farag, H. Effect of sulfidation temperature on the bulk structures of various molybdenum precursors. Energy Fuels 2002, 16, 944.