Mechanistic insight from activation parameters for the reaction between co-enzyme B12 and cyanide: Further evidence that heterolytic Co-C bond cleavage is solvent-assisted

Journal of the Chemical Society. Dalton Transactions

Volumn , Issue 4, 2003, Pages 596-602

  Hamza, Mohamed S A ^a,c   Cregan, Andrew G ^b   Brasch, Nicola E ^b   Van Eldik, Rudi ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

^c Ain Shams University   (Egypt)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COENZYMES; COMPOSITION EFFECTS; CYANIDES; DERIVATIVES; ELECTRON TRANSITIONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION KINETICS; SATURATION (MATERIALS COMPOSITION); SOLVENTS; ULTRAVIOLET SPECTROSCOPY;

ACTIVATION PARAMETERS; DEOXYADENOSYLCOBALAMIN; ELIMINATION PROCESS; HETEROLYTIC BOND CLEAVAGE; KINETIC SATURATION; SODIUM CYANIDE;

CHEMICAL ACTIVATION;

EID: 0037458339     PISSN: 14727773     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

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