Use of a smaller counterion results in an 'inverse sandwich' diindium cation

Journal of Organometallic Chemistry

Volumn 666, Issue 1-2, 2003, Pages 3-5

  Jones, Jamie N ^a   Macdonald, Charles L B ^a   Gorden, John D ^a   Cowley, Alan H ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

Cation; Indium; Pentamethylcyclopentadienyl; Tetrakis(pentafluorophenyl)borate

Indexed keywords

ANION; BORON DERIVATIVE; CATION; FLUORINE; FLUOROCARBON; INDIUM; ORGANOMETALLIC COMPOUND; TOLUENE;

ARTICLE; ATOM; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONTROLLED STUDY; X RAY ANALYSIS;

EID: 0037454819     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(02)02034-X     Document Type: Article

References (3)

1. A.H. Cowley, C.L.B. Macdonald, J.S. Silverman, J.D. Gorden, A. Voigt, Chem. Commun. (2001) 175.
2. 5) is a weakly-held hexamer in the solid state that undergoes facile dissociation to the monomer in solution and in the vapor phase: O.T. Beachley, Jr., R. Blom, M.R. Churchill, K. Faegri, Jr., J.C. Fettinger, J.C. Pazik, L. Victoriano, Organometallics 8 (1989) 346.
3. R.D. Schluter, A.H. Cowley, D.A. Atwood, R.A. Jones, M.R. Bond, C.J. Carrano, J. Am. Chem. Soc. 115 (1993) 2070.